Crystallization kinetics of olivine‐phyric shergottites

Crystal size distribution (CSD) and spatial distribution pattern (SDP) analyses are applied to the early crystallizing phases, olivine and pyroxene, in olivine‐phyric shergottites (Elephant moraine [EET] 79001A, Dar al Gani [DaG] 476, and dhofar [Dho] 019) from each sampling locality inferred from Mars ejection ages. Trace element zonation patterns (P and Cr) in olivine are also used to characterize the crystallization history of these Martian basalts. Previously reported 2‐D CSDs for these meteorites are re‐evaluated using a newer stereographically corrected methodology. Kinks in the olivine CSD plots suggest several populations that crystallized under different conditions. CSDs for pyroxene in DaG 476 and EET 79001A reveal single populations that grew under steady‐state conditions; pyroxenes in Dho 019 were too intergrown for CSD analysis. Magma chamber residence times of several days for small grains to several months for olivine megacrysts are calculated using the CSD slopes and growth rates inferred from previous experimental data. Phosphorus imaging in olivines in DaG 476 and Dho 019 indicate rapid growth of skeletal, sector‐zoned, or patchy cores, probably in response to delayed nucleation, followed by slow growth, and finally rapid dendritic growth with back‐filling to form oscillatory zoning in rims. SPD analyses indicate that olivine and pyroxene crystals grew or accumulated in clusters rather than as randomly distributed grains. These data reveal complex solidification histories for Martian basalts, and are generally consistent with the formation at depth of olivine megacryst cores, which were entrained in ascending magmas that crystallized pyroxenes, small olivines, and oscillatory rims on megacrysts.     

Extreme enrichment of Se,Te, PGE and Au in Cu sulfide microdroplets: evidence from LA-ICP-MS analysis of sulfides in the Skaergaard Intrusion,east Greenland

The Platinova Reef, in the Skaergaard Intrusion, east Greenland, is an example of a magmatic Cu–PGE–Au sulfide deposit formed in the latter stages of magmatic differentiation. As is characteristic with such deposits, it contains a low volume of sulfide, displays peak metal offsets and is Cu rich but Ni poor. However, even for such deposits, the Platinova Reef contains extremely low volumes of sulfide and the highest Pd and Au tenor sulfides of any magmatic ore deposit. Here, we present the first LA-ICP-MS analyses of sulfide microdroplets from the Platinova Reef, which show that they have the highest Se concentrations (up to 1200 ppm) and lowest S/Se ratios (190–700) of any known magmatic sulfide deposit and have significant Te enrichment. In addition, where sulfide volume increases, there is a change from high Pd-tenor microdroplets trapped in situ to larger, low tenor sulfides. The transition between these two sulfide regimes is marked by sharp peaks in Au, and then Te concentration, followed by a wider peak in Se, which gradually decreases with height. Mineralogical evidence implies that there is no significant post-magmatic hydrothermal S loss and that the metal profiles are essentially a function of magmatic processes. We propose that to generate these extreme precious and semimetal contents, the sulfides must have formed from an anomalously metal-rich package of magma, possibly formed via the dissolution of a previously PGE-enriched sulfide. Other processes such as kinetic diffusion may have also occurred alongside this to produce the ultra-high tenors. The characteristic metal offset pattern observed is largely controlled by partitioning effects, producing offset peaks in the order Pt+Pd>Au>Te>Se>Cu that are entirely consistent with published D values. This study confirms that extreme enrichment in sulfide droplets can occur in closed-system layered intrusions in situ, but this will characteristically form ore deposits that are so low in sulfide that they do not conform to conventional deposit models for Cu–Ni–PGE sulfides which require very high R factors, and settling of sulfide liquids.     

Correction to: Evaluation of a multi-model approach to estimate leaf wetness duration: an essential input for disease alert systems

Theoretical and Applied Climatology -     

Low-head hyperfiltration through Jurassic-Cretaceous metamorphic Darrington Phyllite discs (from the Northwest Cascades of Washington State, USA)

Membrane behavior in naturally occurring and engineering systems refers to the restriction of solute migration through a membrane relative to the migration of the solvent. Hyperfiltration is the net flux that results when two solutions of different concentration are separated by a membrane and an external force is applied in excess of the osmotic pressure. Clay membranes containing layered fabric have higher efficiencies than membranes with random fabrics. Therefore, low-permeability rocks with a foliated fabric might exhibit membrane properties. Four hyperfiltration experiments were conducted on samples of Darrington Phyllite from the Easton Metamorphic Suite of the Northwest Cascades, Washington (USA). Chloride solutions were passed through thin, intact discs at relatively low heads. At the end of the experiments, dissolved chloride concentrations had increased 110–140 % and calculated reflection coefficients ranged from 0.87 to 0.88; this was attributed to partial solute rejection by the phyllite. Natural scenarios in which phyllite might exhibit membrane properties include (1) shallow perched aquifers bounded by phyllite, (2) overpressured aquifers bounded by phyllite, (3) phyllite-bounded aquifers with significant vertical groundwater flows, and (4) ultrafiltration during metamorphic devolatilization at depth. Membrane processes exhibited by phyllite may also contribute to the formation of some low-temperature ore bodies.     

Access and Equity in Greenspace Provision: A Comparison of Methods to Assess the Impacts of Greening Vacant Land

This research explores three methods of measuring access to greenspace in Philadelphia and their implications for assessing equity in access based on race and socioeconomic status. These three methods are then used to assess the impacts of a vacant land greening program which turns vacant lots into temporary greenspaces. This research explores the differences between findings when access to greenspace is measured based on distance to any greenspace, total amount of greenspace to which residents have access, or a hybrid measure in which access is determined based on proximity to a threshold amount of greenspace. Not only do assessments of equity differ between the three approaches, but so do determinations of the impact of greening vacant land. Blacks, Hispanics and renters are more likely to live close to a public greenspace than whites or homeowners, but live in proximity to smaller overall amounts of greenspace. Greening vacant land increases the proportion of all residents who live within walking distance of a greenspace and lessens but does not eliminate differences in total greenspace access. The greatest effects of greening vacant land are seen in addressing differences in relative likelihood of having access to a threshold amount of greenspace.     

The Use of Environmental Features on Tactile Maps by Navigators Who Are Blind

Maps designed for and used by sighted audiences benefit from map symbol standardization and convention but, with very limited exception (most notably two European projects), neither standardization nor convention guides the design and use of symbols for tactile maps. In this project, we developed and field tested symbolization for and use of tactile street maps. The development process included consultation with the literature as well as with field experts (orientation and mobility teachers, Braillists, and teachers working with students who are blind or have low vision). Following development, we undertook a three-year field testing and validation phase, in which we conducted pilot testing and formal testing with travelers who are blind or have low vision. Research results reveal not only a discriminable and useful tactile symbol set but also environmental feature use by travelers who are blind or have low vision.     

Collapse of a nonductile concrete frame: Evaluation of analytical models

The current paper presents nonlinear dynamic analyses that simulate shaking table tests performed on a four‐column reinforced concrete frame described in a companion paper. The frame consists of two ductile and two nonductile columns interconnected by a stiff beam. In order to validate existing analytical models for nonductile concrete columns, a blind comparison of the test data and results of the analysis is performed. The analysis adequately captures the drift response and correctly detects collapse of the structure; however, strength degradation due to cover spalling is exaggerated in the analytical model. Refinement of the analysis by changing the concrete cover model results in an excellent agreement between the test data and analysis results at the initiation of shear failure and collapse of the frame. The experimental data are further compared with lumped‐plasticity nonlinear models used in engineering practice. The results suggest that the sudden strength degradation used in ASCE/SEI 41‐06 results in an exaggerated estimate of the displacement demands. It is also observed that ignoring the strength degradation, using an elastic‐perfectly‐plastic model, provides a good estimate of the displacement demands when strength degradation is not severe. Copyright © 2008 John Wiley & Sons, Ltd.     

Bioreduction of hematite nanoparticles by the dissimilatory iron reducing bacterium Shewanella oneidensis MR-1

We examined the reduction of different size hematite (α-Fe₂O₃) nanoparticles (average diameter of 11, 12, 30, 43, and 99 nm) by the dissimilatory iron reducing bacteria (DIRB), Shewanella oneidensis MR-1, to determine how S. oneidensis MR-1 may utilize these environmentally relevant solid-phase electron acceptors. The surface-area-normalized-bacterial Fe(III) reduction rate for the larger nanoparticles (99 nm) was one order of magnitude higher than the rate observed for the smallest nanoparticles (11 nm). The Fe(III) reduction rates for the 12, 30, and 43 nm nanoparticles fell between these two extremes. Whole-cell TEM images showed that the mode of Fe₂O₃ nanoparticle attachment to bacterial cells was different for the aggregated, pseudo-hexagonal/irregular and platey 11, 12, and 99 nm nanoparticles compared to the non-aggregated 30 and 43 nm rhombohedral nanoparticles. Due to differences in aggregation, the 11, 12, and 99 nm nanoparticles exhibited less cell contact and less cell coverage than did the 30 and 43 nm nanoparticles. We hypothesize that S. oneidensis MR-1 employs both indirect and direct mechanisms of electron transfer to Fe(III)-oxide nanoparticles and that the bioreduction mechanisms employed and Fe(III) reduction rates depend on the nanoparticles’ aggregation state, size, shape and exposed crystal faces.     

Defining Optimal Freshwater Flow for Oyster Production: Effects of Freshet Rate and Magnitude of Change and Duration on Eastern Oysters and <Emphasis Type="Italic">Perkinsus marinus</Emphasis> Infection

In coastal Louisiana, the development of large-scale freshwater diversion projects has led to controversy over their effects on oyster resources. Using controlled laboratory experiments in combination with a field study, we examined the effects of pulsed freshwater events (freshet) of different magnitude, duration, and rate of change on oyster resources. Laboratory and field evidence indicate that low salinity events (<5 psu) decreased Perkinsus marinus infection intensities. Furthermore, when salinity was low (<5 psu), parasite infection intensities continued to decrease even as temperatures exceeded 20°C. At the same time, oyster growth was positively correlated with salinity. To maximize oyster production, data indicate that both low and high salinity events will be necessary.     

Relaxational effects in radiating stellar collapse

Relaxational effects in stellar heat transport can in many cases be significant. Relativistic Fourier–Eckart theory is inherently quasi-stationary, and cannot incorporate these effects. The effects are naturally accounted for in causal relativistic thermodynamics, which provides an improved approximation to kinetic theory. Recent results, based on perturbations of a static star, show that relaxation effects can produce a significant increase in the central temperature and temperature gradient for a given luminosity. We use a simple stellar model that allows for non-perturbative deviations from staticity, and confirms qualitatively the predictions of the perturbative models.