Toward spatial understanding of environmentally-based voluntary groups

An attempt is made in this paper to complement existing analyses of voluntary groups by outlining some additional explicitly spatial dimensions which, it is argued, can be useful in examining those organizations with a land use or environmental focus. The distinction is drawn between groups which have direct spatial links and those with indirect spatial links; the hierarchical subdivision of space is considered; the role of scale and its relation to perception and desired use of areas is addressed; and the importance of considering the resolution scale of land use and environmental conflicts noted.     

Pelagic tar off Georgia and Florida in relation to physical processes

Following the Ixtoc I oil rig blowout in Campeche Bay we hypothesized that resulting tarballs should eventually appear in the Gulf Stream off Gerogia and that because of dynamic barriers in the innershelf little would reach nearshore areas. To test these hypotheses, surface tows to collect floating tar were taken off the coasts of Georgia and Florida in October and December, 1979.No tar was found within 40 km of the shore. All samples more than 40 km offshore contained some tar. The mean concentration was 0.82 mg m^?2 with a range of 0.01–5.6 mg m^?2. Closely spaced sampling showed extreme variation but trends were consistent. Perylene was the most abundant compound in the tarballs.     

Seismicity and the subduction process

There is considerable variation between subduction zones in the largest characteristic earthquake within each zone. Assuming that coupling between downgoing and upper plates is directly related to characteristic earthquake size, we have tested for correlations between variation in coupling and other physical features of subduction zones: the lateral extent and penetration depth of Benioff zones, age of subducting lithosphere, convergence rate, and back-arc spreading. Using linear multivariate regression, coupling is correlated with two variables: convergence rate and lithosphere age. Secondary correlations within the data set are penetration depth versus lithosphere age, and lateral extent versus convergence rate. An important additional correlation is that back-arc spreading is found to be associated with subduction zones where coupling is low (those characterised by small earthquakes). Taken together, the observed correlations suggest a simple qualitative model where convergence rate and lithosphere age determine the horizontal and sinking rates, respectively, of slabs: these parameters influence the seismic coupling in the subduction zone. In the limit of a fast sinking rate and slow convergence rate, back-arc spreading occurs and thereby appears to be a passive process.     

Evaluating GCM Output with Impact Models

This study uses empirical agricultural impact models to compare the U.S. climate change predictions of 16 General Circulation Models (GCMs). The impact analysis provides a policy-relevant index by which to judge complex climate predictions. National aggregate impacts vary widely across the 16 GCMs because of varying regional and seasonal patterns of predicted climate change. Examining the predicted impacts from the full set of GCMs reveals that the seasonal detail in the GCM predictions is so noisy that it is not significantly different from a constant annual change. However, a consistent regional pattern does emerge across the set of models. Nonetheless, aggregating climate change across seasons and regions within the United States, using a national-annual climate change provides a reasonable and efficient approximation to the expected impact predicted by the 16 GCM models.     

Characterization of insoluble organic matter in primitive meteorites by microRaman spectroscopy

Abstract— We have analyzed the chemically and isotopically well‐characterized insoluble organic matter (IOM) extracted from 51 unequilibrated chondrites (8 CR, 9 CM, 1 CI, 3 ungrouped C, 9 CO, 9 CV, 10 ordinary, 1 CB and 1 E chondrites) using confocal imaging Raman spectroscopy. The average Raman properties of the IOM, as parameterized by the peak characteristics of the so‐called D and G bands, which originate from aromatic C rings, show systematic trends that are correlated with meteorite (sub‐) classification and IOM chemical compositions. Processes that affect the Raman and chemical properties of the IOM, such as thermal metamorphism experienced on the parent bodies, terrestrial weathering and amorphization due to irradiation in space, have been identified. We established separate sequences of metamorphism for ordinary, CO, oxidized, and reduced CV chondrites. Several spectra from the most primitive chondrites reveal the presence of organic matter that has been amorphized. This amorphization, usually the result of sputtering processes or UV or particle irradiation, could have occurred during the formation of the organic material in interstellar or protoplanetary ices or, less likely, on the surface of the parent bodies or during the transport of the meteorites to Earth. D band widths and peak metamorphic temperatures are strongly correlated, allowing for a straightforward estimation of these temperatures.     

Mineral associations and character of isotopically anomalous organic material in the Tagish Lake carbonaceous chondrite

We report a coordinated analytical study of matrix material in the Tagish Lake carbonaceous chondrite in which the same small (?20 μm) fragments were measured by secondary ion mass spectrometry (SIMS), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDS), electron energy-loss spectroscopy (EELS), and X-ray absorption near-edge spectroscopy (XANES). SIMS analysis reveals H and N isotopic anomalies (hotspots), ranging from hundreds to thousands of nanometers in size, which are present throughout the fragments. Although the differences in spatial resolution of the SIMS techniques we have used introduce some uncertainty into the exact location of the hotspots, in general, the H and N isotopic anomalies are spatially correlated with C enrichments, suggesting an organic carrier. TEM analysis, enabled by site-specific extraction using a focused-ion-beam scanning-electron microscope, shows that the hotspots contain an amorphous component, Fe-Ni sulfides, serpentine, and mixed-cation carbonates. TEM imaging reveals that the amorphous component occurs in solid and porous forms, EDS indicates that it contains abundant C, and EELS and XANES at the C K edge reveal that it is largely aromatic. This amorphous component is probably macromolecular C, likely the carrier of the isotopic anomalies, and similar to the material extracted from bulk samples as insoluble organic matter. However, given the large sizes of some of the hotspots, the disparity in spatial resolution among the various techniques employed in our study, and the phases with which they are associated, we cannot entirely rule out that some of the isotopic anomalies are carried by inorganic material, e.g., sheet silicates. The isotopic composition of the organic matter points to an initially primitive origin, quite possibly within cold interstellar clouds or the outer reaches of the solar protoplanetary disk. The association of organic material with secondary phases, e.g., serpentine and carbonates, suggests that the organic matter was susceptible to parent-body processing, and thus, isotopic dilution.     

A system for line profile studies at the 150-foot tower on Mount Wilson

We describe enhancements to the hardware and software for the 150-foot tower system on Mt. Wilson which make possible the acquisition of high precision line profile measurements. This system utilizes the 75-foot pit spectrograph with a photomultiplier detector system to scan line profiles repeatedly in order to study variations induced by the passage of waves vertically through the solar atmosphere. Oscillations of line profile parameters with an amplitude as low as 1.7 m s^–1 have been detected with this system using integrated sunlight. Phase relations between oscillations of different parts of the line profile are appropriate to upward energy transport. Consistent with the previous conclusion by Mein and Schmieder (1981), we find that the magnitude of the energy transport is compatible with the 5-min oscillations making an important contribution to the heating of the low chromosphere.The Mount Wilson Observatory is operated by the Mount Wilson Institute under agreement with the Carnegie Institution of Washington.     

New 1982 — 1990 photometry of λ Andromedae and its 11-year cycle

We present photoelectric photometry of λ And never before published, obtained between February 1982 and December 1990 at 29 different observatories. Then we combine it with all other photometry available to us (previously published, contained in the I.A.U. Commission 27 Archives, and obtained with the Vanderbilt 16-inch automatic telescope but not yet published), to yield a 14.8-year data base. Analysis reveals a long-term cycle in mean brightness, with a full range of 0^m.15 and a period of 11.4 ± 0.4 years. Because most of our new photometry was concentrated in the 1983-84 observing season, we analyze that one well-defined light curve with a two-spot model. Spot A keeps a 0^m.04 amplitude throughout four rotation cycles whereas the amplitude of spot B diminishes from 0^m.09 down almost to 0^m.03. The spot rotation periods were 55^d.9 ± 0^d.6 and 520^d.8 ± 1^d.0, respectively.     

Spectra of extremely reduced assemblages: Implications for Mercury

Abstract— We investigate the possibility that Mercury's crust is very reduced with FeO concentrations of less than ?0.1 wt%. We believe that such a surface could have a composition of enstatite, plagioclase, diopside, and sulfide, similar to the mineral assemblages found in aubritic meteorites. To test this hypothesis, we investigated the spectra of aubrites and their constituent minerals as analogs for the surface of Mercury. We found that some sulfides have distinctive absorption features in their spectra shortwards of ?0.6 μm that may be apparent in the spectrum of such an object. Determination of the surface composition of Mercury using orbital x‐ray spectroscopy should easily distinguish between a lunar highlands and enstatite basalt composition since these materials have significant differences in concentrations of Al, Mg, S, and Fe. The strongest argument against Mercury having an enstatite basalt composition is its extreme spectral redness. Significant reddening of the surface of an object (such as Mercury) is believed to require reduction of FeO to nanophase iron, thus requiring a few percent FeO in the material prior to alteration.