朝鲜半岛冠帽地块的基底属性:来自银德洞变质侵入杂岩的锆石U-Pb年代学和岩石地球化学证据

地体基底建造的甄别和表征是联结华北克拉通与朝鲜半岛早期演化历史的基本纽带。针对朝鲜半岛前寒武纪基底建造研究方面的薄弱环节,本文表征了冠帽地块清津地区银德洞出露的变质深成侵入杂岩。3个代表性样品的SIMS锆石U-Pb定年结果显示,早期中性片麻岩记录的岩浆侵入年龄为约2.53 Ga,晚期钾长花岗质片麻岩记录的岩浆侵入年龄为约2.51 Ga,表明银德洞变质杂岩形成于新太古代晚期。参考变质杂岩的岩石地球化学特征,其原岩组成可能包括石英闪长岩和钾长花岗岩,大体上可与全球典型的岩浆型紫苏花岗岩系列相类比。结合3个样品变化较大的锆石εH f(t)值(-1.7~+10.5),我们推测银德洞变质侵入杂岩可能形成于玄武质下地壳岩石的部分熔融及其后的结晶分异作用,代表了活动大陆边缘岩浆弧环境下的典型产物。银德洞变质杂岩归属于新太古代岩浆弧根部岩浆岩建造的研究认识,不仅为判定冠帽地块与华北克拉通东部的吉南和龙地块以及辽北清原地块之间的亲缘性提供了岩石学证据,而且暗示这些地块在新太古代共同处在一个类似于安第斯活动大陆边缘的构造环境。     

朝鲜平南盆地祥原超群的沉积时代与拉伸纪早期碳同位素负漂移

朝鲜平南盆地与东华北克拉通(中朝克拉通)中新元古代盆地的对比存在争议,准确厘定相关沉积建造的沉积时限是解决这些争议的关键。朝鲜平南盆地的地层主体为祥原超群,从下往上依次为直岘群、祠堂隅群、默川群、灭恶山群和燕滩群。直岘群是祥原超群的最下部层位,大部分由陆源碎屑岩组成。从平南盆地"北部型"和"南部型"直岘群碎屑岩中分选锆石,测得LA-ICP-MS U-Pb年龄,限定祥原超群沉积时代晚于1100Ma,并且得出所谓的"北部型"和"南部型"地层没有时代和物源差异。鉴于默川群的基性岩床时代为~900Ma,祥原超群的沉积时代为新元古代早期(1000~900Ma),燕滩群的时代可能稍晚。这说明平南盆地与华北徐淮盆地和旅大盆地等同时。祥原超群碳酸盐岩样品的δ~(13)C值数据表明,默川群时期碳同位素发生了负漂移(δ~(13)C值为-6‰~-5‰)。鉴于侵入到默川群的基性岩床的时代为~900Ma,我们认为该碳同位素(δ~(13)C值)负漂移略早于~900Ma,可能与同一时期的岩浆活动有关。     

Effect of Moisture on Attraction Force in Beach Sand

Beach sands located above the sea water level exist in an unsaturated, rather than a fully saturated or dry state. Within the unsaturated zone, a steep excavated surface can be sustained for some unknown but finite time, and some slopes may remain stable for extended time periods due to capillary forces. These observations clearly indicate small but nonzero values for attraction strength (tensile strength and cohesion) in unsaturated beach sands, especially apparent but not confined to settings where there are low stress levels. Thus, experiments were carried out to quantify the magnitude of attraction strength in moist sands (D _r ?=?30%) and to examine the variation of these values as a function of moisture content and presence of a small amount of fines. Tensile strength, which is significantly different from zero, increases with increasing moisture content and fines. However, the influences of fines on the tensile strength are substantially dependent on the water content. Apparent cohesion strength is also identified in moist sands. A simple relationship between tensile strength and apparent cohesion is proposed using the obtained data. This study would help to further understand the phenomenon of stability of beach sands.     

Side-Scan Sonar Characteristics and Manganese Nodule Abundance in the Clarion—Clipperton Fracture Zones,NE Equatorial Pacific

The deep ocean floor between the Clarion and Clipperton fracture zones (NE equatorial Pacific) has the highest known manganese nodule abundance in the world oceans. A detailed analysis of MR1 (Mapping Researcher 1, 11–12?kHz) sonar images and free-fall grab data in the Korean manganese nodule field areas reveals a close relationship between side-scan sonar characteristics of the seafloor and manganese nodule abundance. Eight sonar facies are identified based on back-scattering intensity and distribution patterns. These sonar facies can be interpreted as (1) volcanic seamounts (facies I-1), (2) bounding faults of abyssal hills (facies I-2 and II-1), (3) lava flows or volcanoclastic mass-flow deposits around the volcanic seamounts (facies I-3 and II-2), (4) crests of abyssal hills (facies II-1), (5) abyssal troughs between abyssal hills (facies III-1), (6) relatively flat areas (facies II-3 and III-2). In the areas where facies II-1 (abyssal hill crests with thin sediment cover) and II-3 (relatively flat areas draped by thin sediments) are dominant, manganese nodules occur abundantly. In contrast, zones comprising facies III-1 (abyssal troughs with thick sediment cover) and III-2 (relatively flat areas covered by thick sediments) are characterized by low abundance of manganese nodules. This relationship between distribution of sonar facies and manganese nodule abundance implies that (1) the qualitative difference in acoustic reflectivity of long-range side-scan sonar with some ground truth data is useful for regional assessment of manganese nodule occurrence over wide areas in a reasonable time, and (2) seafloor topography and sediment thickness are important controlling factors for regional occurrences of manganese nodules.     

Geological and Geochemical Characteristics of the Hydrothermal Clay Alteration in South Korea

Abstract: Hydrothermally altered areas forming pyrophyllite‐kaolin‐sericite‐alunite deposits are distributed in Chonnam and Kyongsang areas, Cretaceous volcanic field of the Yuchon Group. The Chonnam alteration area is located within depression zone which is composed of volcanic and granitic rocks of late Cretaceous age. The clay deposits of this area show the genetic relationship with silicic lava domes. The Kyongsang alteration area is mainly distributed within Kyongsang Basin comprising volcanic, sedimentary and granitic rocks of Cretaceous and Tertiary age. Most of the clay deposits of this area are closely related to cauldrons. Paleozoic clay deposit occurs in the contact zone between Precambrian Hongjesa granite gneiss and Paleozoic Jangsan quartzite of Choson Supergroup. Cretaceous igneous rocks of the both alteration areas belong to high K calc‐alkaline series formed in the volcanic arc of continental margin by subduction‐related magmatism. Chonnam igneous rocks show more enrichment of crustal components such as K, La, Ce, Sm, Nd and Ba, higher (La/Yb)cn ratio, and higher initial ⁸⁷Sr/⁸⁶Sr ratio (0. 708 to 0. 712) than those of Kyongsang igneous rocks. This might be due to the difference of degree of crustal contamination during Cretaceous magmatism. The most characteristic alteration minerals of Chonnam clay deposits are alunite, kaolin, quartz, pyrophyllite and diaspore which were formed by acidic solution. Those of Kyongsang clay deposits are sericite, quartz and pyrophyllite which were formed by weak acid and neutral solution. The formation ages of the clay deposits of two alteration areas range from 70. 1 to 81. 4 Ma and 39. 7 to 79. 4 Ma, respectively. The Daehyun clay deposit in Ponghwa area of Kyongsang province shows the alteration age range from 290 to 336 Ma. This result shows the different alteration episode from the hydrothermal alteration of Cretaceous to early Tertiary in the Kyongsang and Chonnam alteration areas. These data indicate, at least, three hydrothermal activities of Tertiary (middle to late Eocene), late Cretaceous (Santonian to Maastrichtian) and Paleozoic Carboniferous Periods in South Korea.     

Hydrogeochemical Characteristics of Acid Mine Drainage around the Abandoned Youngdong Coal Mine in Korea

Abstract: To determine the geochemical characteristics of the Imgok creek impacted by acid mine drainage (AMD) generated from the abandoned Youngdong coal mine in Korea, chemical analyses of water samples and precipitates and the geochemical modelling of the precipitates were conducted. Acid mine drainage drained from the mine adit and coal refuse piles shows a low pH, high conductivity and high concentrations of Fe, Al, SO₄ and heavy metals such as Co, Cu, Ni and Zn. In the Imgok creek, the concentrations of heavy metals and major cations besides Fe are decreased by dilution, but concentrations of Fe are decreased by the formation of precipitates as well as dilution. From the results of geochemical modelling, goethite is oversaturated, and schwertmannite is the most stable solid phase in the Imgok creek. Yellowish red Fe-precipitates collected at the Imgok creek are recognized as amorphous or poorly crystallized minerals from XRD patterns and Fe_ox/Fe_totratios, and as containing chemically bonded SO₄ and OH by an IR analysis. The mole ratios of Fe/S in these precipitates, which are determined by EPMA, are 5. 1 and 6. 1.     

Protective effects of Ecklonia cava extract on the toxicity and oxidative stress induced by hair dye in in-vitro and in-vivo models

Oxidative hair dyes containingρ-phenylenediamine(PPD)are reported to induce an allergic reaction by promoting oxidative stress when absorbed through the skin.Despite the associated risk,these hair dyes remain popular owing to their convenience and sharpness of color.This makes it important to minimize the cytotoxicity and oxidative stress induced by PPD-containing hair dyes.Ecklonia cava extract has been evaluated in different studies for its protective effects against external stress in fibroblasts and keratinocytes.Our study was aimed at using in-vitro and in-vivo models to investigate the extract’s effects on cytotoxicity of and oxidative stress induced by PPD-containing hair dyes.Analysis of CIEL*a*b*Color space was first used to determine the range of E.cava extract that would not interfere with the coloring ability of the dye upon addition.Subsequently,the set ranges of E.cava extract(5% and 7%)were added to the hair dye and their toxicity assessed by evaluating the viability of fibroblasts and keratinocytes.The effects on developmental phenotypes and induction of oxidative stress by hair dye were evaluated and compared with those of hair dyes containing different contents of E.cava extract using an in-vivo zebrafish model.Our results showed that E.cava extract in hair dye could significantly decrease the cytotoxicity and levels of oxidative stress caused by hair dyes containing PPD in both in-vitro and in-vivo models.These results suggest that the addition of 7% E.cava extract to 250μg/mL hair dye does not interfere with the coloring ability of the dye while showing significant protective eff ects against the hair dye.The study proposes that the use of E.cava extract as an adduct to hair dyes containing PPD reduces the cytotoxicity and oxidative stress induced by these hair dyes.     

Meso-Cenozo ic basin evolution in northern Korean Peninsula

In the Korean Peninsula the Meso-Cenozoic basins were mainly formed due to fault block and block movement. The Mesozoic fracture structures correspond basically to modern large rivers in direction. Such faults were usually developed to rift and formed lake-type tectonic basin, such as the Amrokgang-, Taedonggang-, Ryesonggang-, Hochongang-, Jangphari-, Susongchon-, Pujon-, and Nampho basins. The Mesozoic strata are considered to be divided into the Lower Jurassic Taedong System, Upper Jurassic Jasong System, Upper Jurassic－early Lower Cretaceous Taebo System, and the Upper Cretaceous－Paleocene (Chonjaebong, Hongwon, Jaedok Series) . The Cenozoic block movement succeeded the Mesozoic fault block movement. The Kilju-Myonchon Graben and Tumangang Basin, etc, are the basins related to the fault zones developed from the Oligocene to Miocene. In addition, the Tertiary basins were formed in many areas in the Miocene ( e. g. Sinhung, Oro, Hamhung, Yonghung, Anbyon, Cholwon, etc) . The Cenozoic sedimentation occurred mainly from the late Oligocene to Miocene. The Kilju-Myongchon Graben was the fore deep connected to the sea and the basins inclined in the Chugaryong Fault Zone are intramountain basins. Therefore, coal-bearing beds and clastic rocks in the intramountain basins and rare marine strata and terrigenous clastic rocks are main sedimentary sequences in the Cenozoic.     

Numerical simulation of a short flexible pipe subject to forced motion and vortex-induced vibration

A series of numerical simulations about a small scale(aspect ratio:63.2) flexible pipe undergoing forced harmonious oscillation and vortex-induced vibration(VIV) have been taken into account.The wake hydrodynamics and pipe deformation were accomplished by ANSYS MFX solution strategy designed for fluid-structure interaction(FSI) problem with well-performed LES model.The configuration of structured mesh,multi-domain design,different mesh stiffness admeasured by User Fortran ensured that the numerical task was competent to deal with large deformation related to this case.The introduction of instantaneous amplitude definition and modeless component decomposition method(Chen and Kim,2008) was helpful to reveal much more information from modal analysis.Most results from numerical simulation are generally consistent with those from model test(Choi and Hong,2000) via the comparison between them.As supplementary to model test,visualization of the vortex wake was also provided.It has been proved that the forced oscillation doesn't only excite a complicated dumbbell-like wake pattern around the outer thimble,but also results in inner flow inside the PVC pipe.The velocity of the inner flow increases with the frequency of forced oscillation.