Suitability of monosaccharides as markers for particle identification in carbonate sediments*†

The identification of the remains of organisms contributing to carbonate sediments by means of scanning electron-microscopy is limited to particles of the 2–20 μm size class. Mineralogy and the content of Mg, Sr and trace elements alone are usually insufficient to solve the problem of identification, especially in the differentiation between algal and coral aragonite. The organic matrix of calcareous organisms consists of stable biopolymers such as polysaccharides and glycoproteins which are intimately associated with the carbonate skeleton. Analysis of these hydrolysed compounds gives rise to characteristic arrays of monosaccharides which provide independent criteria for producer identification. The calcareous green algae Halimeda, Penicillus and Udotea show high xylose and low fucose levels. Xylose and fucose levels are elevated in the red algae Amphiroa but only fucose is prominent in the brown algae Padina. The corals Oculina, Porites, Millipora and Montastrea are relatively rich in fucose and show little or no xylose. In the bivalves Arca, Codakia and in Argopecten mannose may be characteristic. Analysis of artificial and natural sediments demonstrates that coral and algal aragonite can be distinguished on the basis of the total sugar concentration and respective xylose and fucose levels. The applicability of the technique in comparison to geochemical and mineralogical methods has been demonstrated for surface sediments from varying water depths of Harrington Sound, Bermuda.     

Influence of water level duration on dike breach triggering,focusing on system behaviour hazard analyses in lowland rivers

ABSTRACT

Hazard analysis is a crucial step in flood risk management, and for large rivers, the effects of breaches need to be taken into account. Hazard analyses that incorporate this overall “system behaviour” have become increasingly popular in flood risk assessment. Methods to perform such analyses often focus on high water levels as a trigger for dike breaching. However, the duration of high water levels is known to be another important failure criterion. This study aims to investigate the effect of including this duration dependency in system behaviour analyses, using a computational framework in which two dike breach triggering methods are compared. The first triggers dike breaches based on water levels, and the second one based on both water-level and duration. The comparison is made for the Dutch Rhine system, where the dike failure probabilities are assumed to conform to the new Dutch standards of protection. The results show that including the duration as a breach triggering variable has an effect on the hydraulic loads and overall behaviour in the system, therefore influencing the risk. Although further work is required to fully understand the potential impact, the study suggests that including this duration dependency is important for future hazard risk analyses.     

Seismic response of a four-storey RC school building with masonry-infilled walls

This paper focuses on the evaluation of the effect of masonry-infilled walls on the seismic response of a four-storey RC school building. Numerical simulation is presented with respect to the building with and without masonry-infilled walls. The simulation employed force-based fibre elements for beams and columns, and a single equivalent diagonal strut to represent the masonry infill. The numerical model was verified through comparison with shake table test results. It was found that the presence of masonry-infilled walls has significant influence on the global response of the structure. Although the displacement of the structure with infilled wall is reduced in the in-plane direction, it was increased in both in-plane and out-of-plane directions when the infilled walls experienced loss in serviceability.     

The response of Oneirophanta mutabilis (Holothuroidea) to the seasonal deposition of phytopigments at the Porcupine Abyssal Plain in the Northeast Atlantic

The impact of seasonal pulses of phytodetritus on the grazing behaviour of Oneirophanta mutabilis was assessed on the Porcupine Abyssal Plain (PAP) in the NE Atlantic. Sediment and sediment trap samples were analysed by HPLC to estimate the quantity and quality of the organic material in terms of phytopigments and nucleic acids. Food selection by Oneirophanta was estimated by analysing these constituents in the gut contents.The study area is characterised by large interannual variations in the deposition of fresh organic material. The mass fluxes at 10 m above bottom (mab) varied from 0.25 g DW m⁻² d⁻¹ in September 1996 to <0.1 g DW m⁻² d⁻¹ in March 1997. The material caught in the sediment trap in September 1996 had a relative fresh signature with a chlorophyll-a:phaeophorbide ratio of 1.33. During the other seasons (March 1997, July 1997 and October 1997) the chlorophyll-a:phaeophorbide ratio remained low. In sediment cores this ratio showed a similar seasonal and inter-annual pattern, and again September 1996 was the period of maximum abundance of fresh organic material in the surficial sediment. The analyses of the gut contents of Oneirophanta mirrored exactly the seasonal variation of the phytopigments in both the sediment and the sediment trap material. Concentrations of pigments in the fore-gut were 5 to 15 times higher than in the sediment and the nucleic acid concentrations were up to 80 times higher. This discrepancy between pigments and nucleic acids concentrations suggests that the latter are “indigenous” to the gut of Oneirophanta, either because the gut contains high numbers of actively-dividing bacteria or as a result of cell lysis of the gut epithelium. The seasonal differences in the pigment concentration factor suggest that Oneirophanta does not actively search for hotspots where pigment concentrations are enriched. By using the degradation rate of chlorophyll-a in the PAP sediments, the minimum residence time of chlorophyll in the sediment within the gut of Oneirophanta was calculated. In combination with gut volume and density data it was estimated that each year the Oneirophanta population skims a third of the sediment surface at the PAP site.     

A comparison between the megafauna communities on the N.W. Iberian and Celtic continental margins—effects of coastal upwelling?

Megafauna biomass and feeding guilds were studied on the NW Iberian upwelling Continental Margin in order to determine the presence of enriched zones pointing to enhanced particle input. We compare these findings with similar data obtained from a transect across the Celtic Continental Margin that represents a regime without coastal upwelling. Additionally sediment concentrations of phytopigments (chlorophyll-a, phaeophorbides) representing recent inputs of algal production and of nucleic acids (DNA, RNA) are used as proxies for microbial biomass, to assess if there was a relation between these parameters and the megafauna distribution. The sediment on the upper slope (<1600 m) of the Iberian Margin was found to be inhabited by filter-feeding megafauna (26–73% of total invertebrate density, and 1–35% of biomass), and contained relatively low levels of phytopigments (3–6 ng/cm³ chlorophyll-a) and nucleic acids (12–16 μg⁻¹ DNA, 1.5–3.5 μg⁻¹ RNA). In contrast, on the upper slope of the Celtic Margin the dominant component of the megafauna were deposit-feeders (57–92% of total invertebrate density, and 23–90% of biomass) and the sediments contained higher concentrations of phytopigments and nucleic acid. These observations, supplemented by video records revealing the presence of current ripples on the Iberian upper slope, show that these upper slope regions are non-depositional, high energy environments. Conditions at the lower slope and the abyssal plain on the Iberian transect were more quiescent with large deposit-feeding holothurians dominating the megafauna (72–94% of invertebrate biomass), and with relatively high sediment concentrations of phytopigments (7–9 ng/cm³ chlorophyll-a, 157–170 ng/cm³ phaeophorbides) and nucleic acids (21–38 μg⁻¹ DNA, 2.4–5.5 μg⁻¹ RNA). On the basis of our data we argue that the benthic food for the deepest stations on the Iberian transect does not consist of shelf derived organic matter. More likely, fast sinking offshore blooms, possibly associated with filaments of upwelling water, form the major contribution to the annual food supply of the deep living megafauna.     

A pseudo-Thellier relative palaeointensity record, and rock magnetic and geochemical parameters in relation to climate during the last 276 kyr in the Azores region

In the pseudo-Thellier method for relative palaeointensity determinations (Tauxe et al. 1995) the slope of the NRM intensity left after AF demagnetization versus ARM intensity gained at the same peak field is used as a palaeointensity measure. We tested this method on a marine core from the Azores, spanning the last 276  kyr. We compared the pseudo-Thellier palaeointensity record with the conventional record obtained earlier by Lehman et al . (1996 ), who normalized NRM by SIRM. The two records show similar features: intensity lows with deviating palaeomagnetic directions at 40–45  ka and at 180–190  ka. The first interval is associated with the Laschamps excursion, while the 180–190  ka low represents the Iceland Basin excursion (Channell et al. 1997). The pseudo-Thellier method, in combination with a jackknife resampling scheme, provides error estimates on the palaeointensity.
  Spectral analysis of the rock magnetic parameters and the palaeointensity estimates shows orbitally forced periods, particularly 23  kyr for climatic precession. This suggests that palaeointensity is still slightly contaminated by climate. Fuzzy c -means cluster analysis of rock magnetic and geochemical parameters yields a seven-cluster model of predominantly calcareous clusters and detrital clusters. The clusters show a strong correlation with climate, for example samples from detrital clusters predominantly appear during rapid warming. Although both the pseudo-Thellier palaeointensity m _a and fuzzy clusters show climatic influences, we have not been able to find an unambiguous connection between the clusters and m _a .     

Potential for stratospheric Doppler windspeed measurements of Jupiter by sub-millimetre spectroscopy

The sub-millimetre/microwave range of the spectrum has been exploited in the field of Earth observation by many instruments over the years and has provided a plethora of information on atmospheric chemistry and dynamics—however, this spectral range has not been fully explored in planetary science, having been exclusively employed to carry out ground-based measurements. To this end, a sub-millimetre instrument, the Orbiter Terahertz Infrared Spectrometer (ORTIS), is studied by the University of Oxford and the Rutherford Appleton Laboratory, to meet the requirements of the European Space Agency's Cosmic Visions 2015-2025 programme—in particular, the Europa Jupiter System Mission (EJSM), which has the European Space Agency and the National Aeronautics and Space Administration as partners. ORTIS is designed to measure atmospheric temperature, the abundance of stratospheric water vapour and other jovian gases, and is intended to be capable of retrieving vertical profiles of horizontal windspeed in the stratosphere for the first time, from Doppler-shifted emission lines measured at high spectral resolution. In this work, a preliminary study and implementation of the estimation of windspeed profiles on simulated spectra representative of Jupiter is presented, detailing the development of the retrieval algorithm, showing that a sub-millimetre instrument such as ORTIS should be able to retrieve windspeed profiles to an accuracy of about 15 m/s between 70 and 200 km/0.1-10 mb using a single near-limb measurement, for expected noise amplitudes.     

Characteristics of Titan's stratospheric aerosols and condensate clouds from Cassini CIRS far-infrared spectra

Four broad spectral features were identified in far-infrared limb spectra from the Cassini Composite Infrared Spectrometer (CIRS), two of which have not been identified before. The features are broader than the spectral resolution, which suggests that they are caused by particulates in Titan's stratosphere. We derive here the spectral properties and variations with altitude for these four features for six latitudes between 65° S and 85° N. Titan's main aerosol is called Haze 0 here. It is present at all wavenumbers in the far-infrared and is found to have a fractional scale height (i.e., the aerosol density scale height divided by the atmospheric density scale height) between 1.5 and 1.7 with a small increase in opacity in the north. A second feature around 140 cm⁻¹ (Haze A) has similar spatial properties to Haze 0, but has a smaller fractional scale height of 1.2-1.3. Both Haze 0 and Haze A show an increase in retrieved abundance below 100 km. Two other features (Haze B around 220 cm⁻¹ and Haze C around 190 cm⁻¹) have a large maximum in their density profiles at 140 and 90 km, respectively. Haze B is much more abundant in the northern hemisphere compared to the southern hemisphere. Haze C also shows a large increase towards the north, but then disappears at 85° N.     

Characterising Saturn's vertical temperature structure from Cassini/CIRS

Thermal infrared spectra of Saturn from 10-1400 cm⁻¹ at 15 cm⁻¹ spectral resolution and a spatial resolution of 1°-2° latitude have been obtained by the Cassini Composite Infrared Spectrometer [Flasar, F.M., and 44 colleagues, 2004. Space Sci. Rev. 115, 169-297]. Many thousands of spectra, acquired over eighteen-months of observations, are analysed using an optimal estimation retrieval code [Irwin, P.G.J., Parrish, P., Fouchet, T., Calcutt, S.B., Taylor, F.W., Simon-Miller, A.A., Nixon, C.A., 2004. Icarus 172, 37-49] to retrieve the temperature structure and para-hydrogen distribution over Saturn's northern (winter) and southern (summer) hemispheres. The vertical temperature structure is analysed in detail to study seasonal asymmetries in the tropopause height (65-90 mbar), the location of the radiative-convective boundary (350-500 mbar), and the variation with latitude of a temperature knee (between 150 and 300 mbar) which was first observed in inversions of Voyager/IRIS spectra [Hanel, R., and 15 colleagues, 1981. Science 212, 192-200; Hanel, R., Conrath, B., Flasar, F.M., Kunde, V., Maguire, W., Pearl, J.C., Pirraglia, J., Samuelson, R., Cruikshank, D.P., Gautier, D., Gierasch, P.J., Horn, L., Ponnamperuma, C., 1982. Science 215, 544-548]. Uncertainties due to both the modelling of spectral absorptions (collision-induced absorption coefficients, tropospheric hazes, helium abundance) and the nature of our retrieval algorithm are quantified.Temperatures in the stratosphere near 1 mbar show a 25-30 K temperature difference between the north pole and south pole. This asymmetry becomes less pronounced with depth as the radiative time constant for the atmospheric response increases at deeper pressure levels. Hemispherically-symmetric small-scale temperature structures associated with zonal winds are superimposed onto the temperature asymmetry for pressures greater than 100 mbar. The para-hydrogen fraction in the 100-400 mbar range is greater than equilibrium predictions for the southern hemisphere and parts of the northern hemisphere, and less than equilibrium predictions polewards of 40° N.The temperature knee between 150-300 mbar is larger in the summer hemisphere than in the winter, smaller and higher at the equator, deeper and larger in the equatorial belts and small at the poles. Solar heating on tropospheric haze is proposed as a possible mechanism for this effect; the increased efficiency of ortho- to para-hydrogen conversion in the southern hemisphere is consistent with the presence of larger aerosols in the summer hemisphere, which we demonstrate to be qualitatively consistent with previous studies of Saturn's tropospheric aerosol distribution.