Lagrangian sources of frontogenesis in the equatorial Atlantic front

Estimating the processes that control the north equatorial sea surface temperature (SST)-front on the northern edge of the cold tongue in the tropical Atlantic is a key issue for understanding the dynamics of the oceanic equatorial Atlantic and the West African Monsoon. Diagnosis of the frontogenetic forcings on a realistic high-resolution simulation was used to identify the processes involved in the formation and evolution of the equatorial SST-front. The turbulent forcing associated with the mixed-layer turbulent heat flux was found to be systematically frontolytic while the dynamic forcing associated with currents was found to be frontogenetic for the equatorial SST-front. Nevertheless, the low-frequency component of the turbulent forcing was frontogenetic and initiated the SST-front which was then amplified and maintained by the leading dynamic forcing. This forcing was mainly driven by the meridional convergence of the northern South Equatorial Current (nSEC) and the Guinea Current, which points out the essential role played by the circulation in the equatorial SST-front evolution. The quasi-biweekly variability of the equatorial SST-front and its forcings were found to be more strongly coupled to the wind energy flux (WEF) than to the surface wind stress. In fact the WEF controlled the convergence/divergence of the nSEC and Guinea Current and thus the meridional component of the leading dynamic forcing. The WEF explains the equatorial SST-front development better than the wind does because it is a coupled ocean-atmosphere process.     

Comparing the atmosphere to a bathtub: effectiveness of analogy for reasoning about accumulation

Understanding the process of accumulation is fundamental to recognising the magnitude and speed of emissions reduction required to stabilise atmospheric CO₂ and, hence, global temperature. This research investigated the effectiveness of analogy for building understanding of accumulation among non-experts. Two studies tested the effects of analogy and graphical information on: (1) performance on a CO₂ stabilisation task; and (2) preferred level of action on climate change. Study 1 was conducted with a sample of undergraduate students and Study 2, with a sample of the Australian public. In the student sample, analogical processing significantly improved task performance when information about emission rates was presented in text but not when it was presented in graph format. It was also associated with greater preference for strong action on climate change. When tested with the public, analogy and information format independently influenced task performance. Furthermore, there was a marginal effect of education such that the analogy especially might have helped those with at least high school attainment. Our results show that analogy can improve non-experts’ understanding of CO₂ accumulation but that using graphs to convey emissions rate information is detrimental to such improvements. The results should be of interest to climate change communicators, advocates, and policy-makers.     

1995—2015年中国人口迁移的时空变化特征

本文利用人口普查数据,估算了1995—2015年中国地（市）间人口O-D迁移流和迁移率,结合GIS空间分析和社会网络分析方法,揭示了20年间中国人口迁移的时空变化特征。研究发现：① 中国人口迁移由相对不活跃、局部地区参与的“低活性时代”,逐步走向相对活跃、绝大多数地区参与的“高活性时代”。② 人口迁移地域类型的时空演化过程呈现出各活跃型地（市）不断扩散,而非活跃型地（市）大幅缩减的特点。③ 人口迁移网络以“胡焕庸线”为界,东、西两侧迁移流“东密西疏”且差异悬殊,这一空间格局具有很强的稳定性和顽健性。④ 在人口省内迁移持续增强,以及跨省迁移中沿海三大城市群吸引力的“此消彼长”和西南地区吸引力不断增强的背景下,东中西部地区的人口迁移流场结构表现为：沿海地区主要城市群内部分化和影响范围减弱,中部地区（除湖北省）未能演化出以省为单元的独立社区,西部地区则是西北相对稳定而西南持续变动。     

Sulfur sources of sedimentary “buckshot” pyrite in the Auriferous Conglomerates of the Mesoarchean Witwatersrand and Ventersdorp Supergroups,Kaapvaal Craton,South Africa

Large rounded pyrite grains (>1 mm), commonly referred to as “buckshot” pyrite grains, are a characteristic feature of the auriferous conglomerates (reefs) in the Witwatersrand and Ventersdorp supergroups, Kaapvaal Craton, South Africa. Detailed petrographic analyses of the reefs indicated that the vast majority of the buckshot pyrite grains are of reworked sedimentary origin, i.e., that the pyrite grains originally formed in the sedimentary environment during sedimentation and diagenesis. Forty-one of these reworked sedimentary pyrite grains from the Main, Vaal, Basal, Kalkoenkrans, Beatrix, and Ventersdorp Contact reefs were analyzed for their multiple sulfur isotope compositions (δ³⁴S, Δ³³S, and Δ³⁶S) to determine the source of the pyrite sulfur. In addition, five epigenetic pyrite samples (pyrite formed after sedimentation and lithification) from the Middelvlei and the Ventersdorp Contact reefs were measured for comparison. The δ³⁴S, Δ³³S, and Δ³⁶S values of all 41 reworked sedimentary pyrite grains indicate clear signatures of mass-dependent and mass-independent fractionation and range from ?6.8 to +13.8?‰, ?1.7 to +1.7?‰, and ?3.9 to +0.9?‰, respectively. In contrast, the five epigenetic pyrite samples display a very limited range of δ³⁴S, Δ³³S, and Δ³⁶S values (+0.7 to +4.0?‰, ?0.3 to +0.0?‰. and ?0.3 to +0.1?‰, respectively). Despite the clear signatures of mass-independent sulfur isotope fractionation, very few data points plot along the primary Archean photochemical array suggesting a weak photolytic control over the data set. Instead, other factors command a greater degree of influence such as pyrite paragenesis, the prevailing depositional environment, and non-photolytic sulfur sources. In relation to pyrite paragenesis, reworked syngenetic sedimentary pyrite grains (pyrite originally precipitated along the sediment-water interface) are characterized by negative δ³⁴S and Δ³³S values, suggesting open system conditions with respect to sulfate supply and the presence of microbial sulfate reducers. On the contrary, most reworked diagenetic sedimentary pyrite grains (pyrite originally precipitated below the sediment-water interface) show positive δ³⁴S and negative Δ³³S values, suggesting closed system conditions. Negligible Δ³³S anomalies from epigenetic pyrite suggest that the sulfur was sourced from a mass-dependent or isotopically homogenous metamorphic/hydrothermal fluid. Contrasting sulfur isotope compositions were also observed from different depositional environments, namely fluvial conglomerates and marine-modified fluvial conglomerates. The bulk of the pyrite grains from fluvial conglomerates are characterized by a wide range of δ³⁴S values (?6.2 to +4.8?‰) and small Δ³³S values (±0.3?‰). This signature likely represents a crustal sulfate reservoir derived from either volcanic degassing or from weathering of sulfide minerals in the hinterland. Reworked sedimentary pyrite grains from marine-modified fluvial conglomerates share similar isotope compositions, but also produce a positive Δ³³S/δ³⁴S array that overlaps with the composition of Archean barite, suggesting the introduction of marine sulfur. These results demonstrate the presence of multiple sources of sulfur, which include atmospheric, crustal, and marine reservoirs. The prevalence of the mass-dependent crustal sulfur isotope signature in fluvial conglomerates suggests that sulfate concentrations were probably much higher in terrestrial settings in comparison to marine environments, which were sulfate-deficient. However, the optimum conditions for forming terrestrial sedimentary pyrite were probably not during fluvial progradation but rather during the early phases of flooding of low angle unconformities, i.e., during retrogradational fluvial deposition, coupled in some cases with marine transgressions, immediately following inflection points of maximum rate of relative sea level fall.     

Oxygen isotopic compositions of chondrules: Implications for evolution of oxygen isotopic reservoirs in the inner solar nebula

We review the oxygen isotopic compositions of minerals in chondrules and compound objects composed of a chondrule and a refractory inclusion, and bulk oxygen isotopic compositions of chondrules in unequilibrated ordinary, carbonaceous, enstatite, and Kakangari-like chondrites, focusing on data acquired using secondary ion mass-spectrometry and laser fluorination coupled with mass-spectrometry over the last decade. Most ferromagnesian chondrules from primitive (unmetamorphosed) chondrites are isotopically uniform (within 3–4‰ in Δ¹⁷O) and depleted in ¹⁶O (Δ¹⁷O>−7‰) relative to amoeboid olivine aggregates (AOAs) and most calcium–aluminum-rich inclusions (CAIs) (Δ¹⁷O<−20‰), suggesting that these classes of objects formed in isotopically distinct gaseous reservoirs, ¹⁶O-poor and ¹⁶O-rich, respectively. Chondrules uniformly enriched in ¹⁶O (Δ¹⁷O<−15‰) are exceptionally rare and have been reported only in CH chondrites. Oxygen isotopic heterogeneity in chondrules is mainly due to the presence of relict grains. These appear to consist of chondrules of earlier generations and rare refractory inclusions; with rare exceptions, the relict grains are ¹⁶O-enriched relative to chondrule phenocrysts and mesostasis. Within a chondrite group, the magnesium-rich (Type I) chondrules tend to be ¹⁶O-enriched relative to the ferrous (Type II) chondrules. Aluminum-rich chondrules in ordinary, enstatite, CR, and CV chondrites are generally ¹⁶O-enriched relative to ferromagnesian chondrules. No systematic differences in oxygen isotopic compositions have been found among these chondrule types in CB chondrites. Aluminum-rich chondrules in carbonaceous chondrites often contain relict refractory inclusions. Aluminum-rich chondrules with relict CAIs have heterogeneous oxygen isotopic compositions (Δ¹⁷O ranges from −20‰ to 0‰). Aluminum-rich chondrules without relict CAIs are isotopically uniform and have oxygen isotopic compositions similar to, or approaching, those of ferromagnesian chondrules. Phenocrysts and mesostases of the CAI-bearing chondrules show no clear evidence for ¹⁶O-enrichment compared to the CAI-free chondrules. Spinel, hibonite, and forsterite of the relict refractory inclusions largely retained their original oxygen isotopic compositions. In contrast, plagioclase and melilite of the relict CAIs experienced melting and ¹⁶O-depletion to various degrees, probably due to isotopic exchange with an ¹⁶O-poor nebular gas. Several igneous CAIs experienced isotopic exchange with an ¹⁶O-poor nebular gas during late-stage remelting in the chondrule-forming region. On a three-isotope diagram, bulk oxygen isotopic compositions of most chondrules in ordinary, enstatite, and carbonaceous chondrites plot above, along, and below the terrestrial fractionation line, respectively. Bulk oxygen isotopic compositions of chondrules in altered and/or metamorphosed chondrites show evidence for mass-dependent fractionation, reflecting either interaction with a gaseous/fluid reservoir on parent asteroids or open-system thermal metamorphism. Bulk oxygen isotopic compositions of chondrules and oxygen isotopic compositions of individual minerals in chondrules and refractory inclusions from primitive chondrites plot along a common line of slope of 1, suggesting that only two major reservoirs (gas and solids) are needed to explain the observed variations. However, there is no requirement that each had a permanently fixed isotopic composition. The absolute (²⁰⁷Pb–²⁰⁶Pb) and relative (²⁷Al–²⁶Mg) chronologies of CAIs and chondrules and the differences in oxygen isotopic compositions of most chondrules (¹⁶O-poor) and most refractory inclusions (¹⁶O-rich) can be interpreted in terms of isotopic self-shielding during UV photolysis of CO in the initially ¹⁶O-rich (Δ¹⁷O−25‰) parent molecular cloud or protoplanetary disk. According to these models, the UV photolysis preferentially dissociates C¹⁷O and C¹⁸O in the parent molecular cloud and in the peripheral zones of the protoplanetary disk. If this process occurs in the stability field of water ice, the released atomic ¹⁷O and ¹⁸O are incorporated into water ice, while the residual CO gas becomes enriched in ¹⁶O. During the earliest stages of evolution of the protoplanetary disk, the inner solar nebula had a solar H₂O/CO ratio and was ¹⁶O-rich. During this time, AOAs and the ¹⁶O-rich CAIs and chondrules formed. Subsequently, the inner solar nebula became H₂O- and ¹⁶O-depleted, because ice-rich dust particles, which were depleted in ¹⁶O, agglomerated outside the snowline (5 AU), drifted rapidly towards the Sun and evaporated. During this time, which may have lasted for 3 Myr, most chondrules and the ¹⁶O-depleted igneous CAIs formed. We infer that most chondrules formed from isotopically heterogeneous, but ¹⁶O-depleted precursors, and experienced isotopic exchange with an ¹⁶O-poor nebular gas during melting. Although the relative roles of the chondrule precursor materials and gas–melt isotopic exchange in establishing oxygen isotopic compositions of chondrules have not been quantified yet, mineralogical, chemical, and isotopic evidence indicate that Type I chondrules may have formed in chemical and isotopic equilibrium with nebular gas of variable isotopic composition. Whether these variations were spatial or temporal are not known yet.     

Evolution of an ancient coastal plain: palaeosols, interfluves and alluvial architecture in a sequence stratigraphic framework, Cenomanian Dunvegan Formation, NE British Columbia, Canada

To date, discussion of changes in alluvial style and in the character of palaeosols in relation to changes in accommodation and sediment supply on floodplains has primarily been from a conceptual standpoint: few case studies are available against which to test ideas. One hundred and thirty metres of non-marine strata of the Dunvegan Formation were examined in 14 closely spaced sections in the canyon of the Kiskatinaw River, NE British Columbia, Canada. This site was located about 120 km inland from the transgressive limit of the contemporary marine shoreline and represents almost exclusively freshwater environments. Fluvial channels in the Kiskatinaw River section are of two types. Small, single-storey, very fine- to fine-grained sandstone ribbons with W/T ratios <30, encased in fine-grained floodplain sediments are interpreted as anastomosed channels. Fine- to medium-grained, laterally accreted point-bar deposits forming multistorey sand bodies with individual W/T ratios >30 are interpreted as the deposits of meandering rivers filling incised valleys. Interchannel facies include the deposits of crevasse channels and splays, lakes, floodplains and palaeosols. Floodplain palaeosols consist of laterally heterogeneous, simple palaeosol profiles and pedocomplexes similar to modern Entisols, Inceptisols and hydromorphic soils. Interfluve, sequence-bounding palaeosols adjacent to incised valleys are laterally continuous, up to 3 m thick and can be reliably identified using a combination of (1) stratigraphic position; (2) field observations, such as thickness, structure, colour, degree of rooting; and (3) micromorphological features, such as evidence of bioturbation, clay coatings, ferruginous features and sphaerosiderite. Interfluve palaeosols are similar to modern Alfisols and Ultisols. Correlation of the local stratigraphic succession with the regional sequence stratigraphic framework, based on 2340 well logs and 60 outcrop sections, shows that the vertical changes in coastal plain character (more coals and lakes vs. more pedogenesis) can be related to relatively high-frequency base level cycles (eustatic?) that are expressed as transgressive–regressive marine cycles in downdip areas. Regional isopach maps show that these cycles were progressively overprinted and modified by an increasing rate of tectonic subsidence in the north and west. The character of palaeosols developed on aggrading floodplains primarily reflects local sediment supply and drainage. In contrast, well-developed interfluve palaeosols record pedogenesis during periods of reduced or negative accommodation (base level fall). Vertical changes in floodplain palaeoenvironments and palaeosol types reflect changes in accommodation rate. The detailed micromorphological analysis of interfluve palaeosols represents a powerful application of an under-used technique for the recognition of key surfaces in the geological record. This has broad implications for non-marine sequence stratigraphy.     

Effect of macrofaunal bioturbation on bacterial distribution in marine sandy sediments, with special reference to sulphur-oxidising bacteria

We have studied the impact of the bioturbating macrofauna, in particular the lugworm Arenicola marina and the bivalve Cerastoderma edule, on abundances and distribution patterns of total bacteria and of bacteria of selected functional groups in sandy intertidal sediments. The selected groups comprised the colourless sulphur-oxidising bacteria and the anoxygenic phototrophic bacteria, which are expected to occupy small zones at the oxygen–sulphide interface in stable (non-bioturbated) sediments. The presence of a wooden wreck buried in the sediment at 10 cm depth within a large area of intertidal sand flat colonised by lugworms provided a unique opportunity to confront field observations with laboratory simulations. The site with the wooden wreck, which was used as control site, was devoid of both A. marina and C. edule, while the composition of the rest of the zoobenthic community was rather similar to that of the surrounding area. In the field, the density of total bacteria was approximately one order of magnitude higher in the control site than in the natural (bioturbated) site. This can be explained by the higher contents of silt and clay particles (higher surface-area/volume ratio) and higher total organic-carbon contents found at the control site. It appears that the presence of macrofauna affects sedimentation processes, which indirectly influence bacterial dynamics. Samples from the control site have been incubated in the laboratory with A. marina and C. edule added (bioturbated core), while an unamended core served as a control. The laboratory experiments contrasted with the field observations, because it was found that total bacteria were actually higher in the deeper layers of the bioturbated core. Moreover, the populations were more homogeneous (less stratified) and colourless sulphur bacteria were on average less numerous in the bioturbated core. In general, laboratory incubations resulted in a decrease of total bacteria with a concomitant increase of colourless and phototrophic sulphur-oxidising bacteria and thus in modifications of the bacterial community structure. Hence, our results demonstrate that care must be taken in extrapolating results from laboratory experiments (e.g. mesocosm research) to field situations.     

Aragonite depositional facies in a Late Ordovician calcite sea,Eastern Laurentia

The Black River (Upper Ordovician – Sandbian) and Trenton (Upper Ordovician – Katian) groups are traditionally interpreted as a deepening-upward succession deposited in a progressively subsiding Appalachian Basin margin that contained warm-water, marine, photozoan deposits that pass upward into cool-water, marine, heterozoan carbonates. This succession is customarily interpreted to reflect an incursion of cold, high-latitude ocean waters into the area. This view is herein confirmed for coeval carbonates in the northern part of the basin, particularly the St. Lawrence Platform. They are now well explained in this study on the basis of recent studies of cool-water carbonates and calcite–aragonite seas. Overall the succession is one of Sandbian photozoan ramp deposits succeeded by Katian heterozoan ramp carbonates that changed back to photozoan ramp deposits prior to the Hirnantian glaciation. The current interpretation, that deposition took place throughout a calcite sea time, seems at odds with this series of strata. Instead it is herein proposed that deposition took place during an aragonite sea time wherein calcite sea-like sediments accumulated under cold ocean-water temperatures. Such an interpretation is supported by recent experimental data that supports the importance of seawater temperature on CaCO₃ polymorph precipitation. If correct, this means that some of the evidence for calcite sea deposition through time brought about by global tectonics, should be re-evaluated to make sure it was not simply cool-water carbonate production.     

Scientific detector workshop 2022 on-sky performance verification of near-infrared e−APD technology for wavefront sensing and demonstration of e−APD pixel performance to improve the sensitivity of large science focal planes

Near-infrared adaptive optics as well as fringe tracking for coherent beam combination in optical interferometry require the development of high-speed sensors. Because of the high speed, a large analog bandwidth is required. The short exposure times result in small signal levels which require noiseless detection. Both requirements cannot be met by state-of-the-art conventional CMOS technology of near-infrared arrays as has been attempted previously. A total of five near-infrared SAPHIRA 320 × 256 pixel HgCdTe e⁻APD arrays have been deployed in the wavefront sensors and in the fringe tracker of the VLTI instrument GRAVITY. The current limiting magnitude for coherent exposures with GRAVITY is m_k = 19, which is made possible with ADP technology. New avalanche photo-diode array (APD) developments since GRAVITY include the extension of the spectral sensitivity to the wavelength range from 0.8 to 2.5 μm. After GRAVITY a larger format array with 512 × 512 pixels has been developed for both AO applications at the ELT and for long integration times. Since dark currents of <10⁻³ e⁻/s have been demonstrated with 1Kx1K e⁻APD arrays and 2Kx2K e⁻APD arrays have already been developed, the possibilities and adaptations of e⁻APD technology to provide noiseless large-format science-grade arrays for long integration times are also discussed.