Silicon negative ion chemistry in the atmosphere-in situ and laboratory measurements

The results of a rocket-borne mass spectrometer measurement indicate that large concentrations of negative ions exist above the bottom of the atmospheric atomic oxygen layer. A large majority of these ions have a mass greater than 100 amu. In addition, an ion at mass 76 was observed with concentrations too large to be CO₄^?. In order to explain these features, a number of reactions involving silicon oxide negative ions have been measured in a flowing afterglow system. The ion SiO₃^? is produced by reaction of O₃^?, and CO₃^?, with SiO. The SiO₃^? ion is extremely stable and does not react measurably with NO, NO₂, CO, CO₂, O₃ or O. Since meteoroid ablation produces a large silicon input into the atmosphere, it appears possible that the ions observed at mass 76 may be SiO₃^?. Possible production mechanisms for this ion as well as the heavy ions are discussed.     

Consequences of change and variability in sea ice on marine ecosystem and biogeochemical processes during the 2007–2008 Canadian International Polar Year program

Change and variability in the timing and magnitude of sea ice geophysical and thermodynamic state have consequences on many aspects of the arctic marine system. The changes in both the geophysical and thermodynamic state, and in particular the timing of the development of these states, have consequences throughout the marine system. In this paper we review the ??consequences?? of change in sea ice state on primary productivity, marine mammal habitats, and sea ice as a medium for storage and transport of contaminants and carbon exchange across the ocean-sea-ice-atmosphere interface based upon results from the International Polar Year. Pertinent results include: 1) conditions along ice edges can bring deep nutrient-rich ??pacific?? waters into nutrient-poor surface waters along the arctic coast, affecting local food webs; 2) both sea ice thermodynamic and dynamic processes ultimately affect ringed seal/polar bear habitats by controlling the timing, location and amount of surface deformation required for ringed seal and polar bear preferred habitat 3) the ice edges bordering open waters of flaw leads are areas of high biological production and are observed to be important beluga habitat. 4) exchange of climate-active gases, including CO₂, is extremely active in sea ice environments, and the overall question of whether the Arctic Ocean is (or will be) a source or sink for CO₂ will be dependent on the balance of competing climate-change feedbacks.     

Current state and trends in Canadian Arctic marine ecosystems: II. Heterotrophic food web, pelagic-benthic coupling, and biodiversity

As part of the Canadian contribution to the International Polar Year (IPY), several major international research programs have focused on offshore arctic marine ecosystems. The general goal of these projects was to improve our understanding of how the response of arctic marine ecosystems to climate warming will alter food web structure and ecosystem services provided to Northerners. At least four key findings from these projects relating to arctic heterotrophic food web, pelagic-benthic coupling and biodiversity have emerged: (1) Contrary to a long-standing paradigm of dormant ecosystems during the long arctic winter, major food web components showed relatively high level of winter activity, well before the spring release of ice algae and subsequent phytoplankton bloom. Such phenological plasticity among key secondary producers like zooplankton may thus narrow the risks of extreme mismatch between primary production and secondary production in an increasingly variable arctic environment. (2) Tight pelagic-benthic coupling and consequent recycling of nutrients at the seafloor characterize specific regions of the Canadian Arctic, such as the North Water polynya and Lancaster Sound. The latter constitute hot spots of benthic ecosystem functioning compared to regions where zooplankton-mediated processes weaken the pelagic-benthic coupling. (3) In contrast with another widely shared assumption of lower biodiversity, arctic marine biodiversity is comparable to that reported off Atlantic and Pacific coasts of Canada, albeit threatened by the potential colonization of subarctic species. (4) The rapid decrease of summer sea-ice cover allows increasing numbers of killer whales to use the Canadian High Arctic as a hunting ground. The stronger presence of this species, bound to become a new apex predator of arctic seas, will likely affect populations of endemic arctic marine mammals such as the narwhal, bowhead, and beluga whales.     

Limits to scale invariance in alluvial rivers

Assumptions about fluvial processes and process–form relations are made in general models and in many site-specific applications. Many standard assumptions about reach-scale flow resistance, bed-material entrainment thresholds and transport rates, and downstream hydraulic geometry involve one or other of two types of scale invariance: a parameter (e.g. critical Shields number) has the same value in all rivers, or doubling one variable causes a fixed proportional change in another variable in all circumstances (e.g. power-law hydraulic geometry). However, rivers vary greatly in size, gradient, and bed material, and many geomorphologists regard particular types of river as distinctive. This review examines the tension between universal scaling assumptions and perceived distinctions between different types of river. It identifies limits to scale invariance and departures from simple scaling, and illustrates them using large data sets spanning a wide range of conditions. Scaling considerations and data analysis support the commonly made distinction between coarse-bed and fine-bed reaches, whose different transport regimes can be traced to the different settling-velocity scalings for coarse and fine grains. They also help identify two end-member sub-types: steep shallow coarse-bed ‘torrents’ with distinctive flow-resistance scaling and increased entrainment threshold, and very large, low-gradient ‘mega rivers’ with predominantly suspended load, subdued secondary circulation, and extensive backwater conditions. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

3D MHD Coronal Oscillations about a Magnetic Null Point: Application of WKB Theory

This paper is a demonstration of how the WKB approximation can be used to help solve the linearised 3D MHD equations. Using Charpit’s method and a Runge?–?Kutta numerical scheme, we have demonstrated this technique for a potential 3D magnetic null point, B=[x,ε y,?(ε+1)z]. Under our cold-plasma assumption, we have considered two types of wave propagation: fast magnetoacoustic and Alfvén waves. We find that the fast magnetoacoustic wave experiences refraction towards the magnetic null point and that the effect of this refraction depends upon the Alfvén speed profile. The wave and thus the wave energy accumulate at the null point. We have found that current buildup is exponential and the exponent is dependent upon ε. Thus, for the fast wave there is preferential heating at the null point. For the Alfvén wave, we find that the wave propagates along the field lines. For an Alfvén wave generated along the fan plane, the wave accumulates along the spine. For an Alfvén wave generated across the spine, the value of ε determines where the wave accumulation will occur: fan plane (ε=1), along the x-axis (0<ε<1) or along the y-axis (ε>1). We have shown analytically that currents build up exponentially, leading to preferential heating in these areas. The work described here highlights the importance of understanding the magnetic topology of the coronal magnetic field for the location of wave heating.     

Flow resistance and hydraulic geometry in bedrock rivers with multiple roughness length scales

Many models of incision by bedrock rivers predict water depth and shear stress from discharge; conversely, palaeoflood discharge is sometimes reconstructed from flow depth markers in rock gorges. In both cases, assumptions are made about flow resistance. The depth–discharge relation in a bedrock river must depend on at least two roughness length scales (exposed rock and sediment cover) and possibly a third (sidewalls). A conceptually attractive way to model the depth–discharge relation in such situations is to partition the total shear stress and friction factor, but it is not obvious how to quantify the friction factor for rough walls in a way that can be used in incision process models. We show that a single flow resistance calculation using a spatially averaged roughness length scale closely approximates the partitioning of stress between sediment and rock, and between bed and walls, in idealized scenarios. Both approaches give closer fits to the measured depth–discharge relations in two small bedrock reaches than can be achieved using a fixed value of Manning's n or the Chézy friction factor. Sidewalls that are substantially rougher or smoother than the bed have a significant effect on the partitioning of shear stress between bed and sidewalls. More research is needed on how best to estimate roughness length scales from observable or measurable channel characteristics. © 2019 John Wiley & Sons, Ltd.     

Conventional Oil—The Forgotten Part of the Water-Energy Nexus

The impacts of unconventional oil and gas production via high-volume hydraulic fracturing (HVHF) on water resources, such as water use, groundwater and surface water contamination, and disposal of produced waters, have received a great deal of attention over the past decade. Conventional oil and gas production (e.g., enhanced oil recovery [EOR]), which has been occurring for more than a century in some areas of North America, shares the same environmental concerns, but has received comparatively little attention. Here, we compare the amount of produced water versus saltwater disposal (SWD) and injection for EOR in several prolific hydrocarbon producing regions in the United States and Canada. The total volume of saline and fresh to brackish water injected into depleted oil fields and nonproductive formations is greater than the total volume of produced waters in most regions. The addition of fresh to brackish “makeup” water for EOR may account for the net gain of subsurface water. The total amount of water injected and produced for conventional oil and gas production is greater than that associated with HVHF and unconventional oil and gas production by well over a factor of 10. Reservoir pressure increases from EOR and SWD wells are low compared to injection of fluids for HVHF, however, the longer duration of injections could allow for greater solute transport distances and potential for contamination. Attention should be refocused from the subsurface environmental impacts of HVHF to the oil and gas industry as a whole.     

Age verification,growth and life history of rubyfish Plagiogeneion rubiginosum

Age verification of rubyfish (Plagiogeneion rubiginosum) was sought using the bomb radiocarbon chronometer procedure. Stable isotopes were investigated for life history characteristics. Radiocarbon (¹⁴C) and stable isotope (δ¹⁸O and δ¹³C) levels were measured in micro-samples from five otoliths that had been aged using a zone count method. All the core ¹⁴C measurements were ‘pre-bomb’ indicating ages of at least 45 years, and the ¹⁴C measurements across the otolith sections suggested that the zone-count ageing method described herein is not biased. Maximum estimated age was 100 years. There was no significant between-sex difference in the von Bertalanffy growth curves. The δ¹⁸O values indicated that rubyfish are near-surface as juveniles, and move deeper with age. Adults appear to reside in 600–1000 m; this is deeper than most trawl-capture data suggest, but not implausible, and has stock assessment implications. The δ¹³C values reflect fish metabolic rates, trophic feeding levels and oceanographic conditions. The stable isotopes record the environmental life history of each fish, and have value in distinguishing stocks and/or indicating vertical and latitudinal migratory patterns.