(Na,Ca)(Ti3+,Mg)Si2O6-clinopyroxenes at high pressure: influence of cation substitution on elastic behavior and phase transition

A compressional study of (Na,Ca)(Ti³⁺,Mg)Si₂O₆-clinopyroxenes was carried out at high pressures between 10⁻⁴ and 10.2 GPa using in situ single-crystal X-ray diffraction, Raman spectroscopy and optical absorption spectroscopy. Compressional discontinuities accompanied by structural changes, in particular, the appearance of two distinct Ti³⁺–Ti³⁺ distances within the octahedral chains at 4.37 GPa, provide evidence for the occurrence of a phase transition in NaTi³⁺Si₂O₆. Equation-of-state parameters are K ₀ = 115.9(7) GPa with K′ = −0.9(3) and K ₀ = 102.7(8) GPa with K′ = 4.08(5) for the low- and high-pressure range, respectively. The transition involves a C2/c–P [`1] \overline{1} symmetry change, which can be confirmed by the occurrence of new modes in Raman spectra. Since no significant discontinuity in the evolution of the unit-cell volume with pressure has been observed, the transition appears to be second-order in character. The influence of the coupled substitution Na⁺Ti³⁺↔Ca²⁺Mg²⁺ on the static compression behavior and the structural stability has been investigated using a sample of the intermediate composition (Na_0.54Ca_0.46)(Mg_0.46Ti_0.54)Si₂O₆. No evidence for a deviation from continuous compression behavior has been found, neither in lattice parameter nor in structural data and the fit of a third-order Birch–Murnaghan equation-of-state to the pressure–volume data yields a bulk modulus of K ₀ = 109.1(5) GPa and K′ = 5.02(13). Raman and polarized absorption spectra have been compared to NaTiSi₂O₆ and reveal major similarities. The main driving force for the phase transition in NaTi³⁺Si₂O₆ is the localization of the Ti³⁺ d-electron and the accompanying distortion, which is suppressed in the (Na,Ca)(Ti³⁺,Mg)Si₂O₆-clinopyroxene.     

Influence of surface/groundwater interaction on pollution by pesticides in farmlands of the Fucino Plain,central Italy

This paper analyses flow and transport of pesticides from the unsaturated zone to groundwater so as to predict concentration of those contaminants in the Fucino Plain’s groundwater, by site investigations and numerical simulations. Pesticides were detected in surface water (peaks of 13 μg L⁻¹) and groundwater (peaks of 0.37 μg L⁻¹). Modelling tools made it possible to identify that pattern of precipitation, organic matter content, and root thickness are the key factors involved in vertical seepage of pesticides. Numerical simulations indicated that a significant fraction of contaminants is leached from the most surficial soil layers through runoff, while only a secondary fraction is mobilised towards groundwater. Likelihood of contaminating deep groundwater is fairly low, whereas surface waters show higher susceptibility. Results of the proposed conceptual hydrogeological model show that pesticides are more likely to be entrained by mixing of stream water with shallow groundwater in periods of high water exploitation from shallow wells.     

An observational study of heat fluxes and their relationships with net radiation

Experimental evidence indicates that the diurnal behaviour of the fluxes of heat into the ground and into the atmosphere versus the net flux of radiation can be modelled by closed curves, the hourly values folowing one another in either a clockwise or counter clockfashion. A general formulation to express the different heat fluxes as a function of net radiation is proposed. This relationship between the different heat fluxes and can be expressed as a sum of three terms: the first indicates a direct proportionality to , the second gives the deviation from linearity and depends on /t, and the third gives the value of the flux when = 0. The formulae are then expressed as a function of time and the ratios between the heat fluxes and are evaluated. A comparison with the approximations generally used shows that the latter may be considered as particular cases of the more general equations proposed here.     

Un réseau fluviatile d'âge Burdigalien terminal dans le Sud-Est de la France : remplissage,extension, âge,implications

An integrated study combining facies analysis, multiple group biostratigraphy, identification of depositional sequences and mapping has been conducted on the Miocene Molasse Basin of the external Alps (southeastern France). The filling of the basin is described as resulting from a succession of fluvial incisions subsequently filled during marine transgressions. The major incision is dated as Latest Burdigalian and the major transgression as Langhian. This revised interpretation of the Miocene physiographic evolution of the Molasse Basin implies a re-examination of previous stratigraphic correlations within the basin. To cite this article: D. Besson et al., C. R. Geoscience 337 (2005).     

Hydrological conditions over the western Mediterranean basin during the deposition of the cold Sapropel 6 (ca. 175 kyr BP)

A new oxygen isotope record is reported from a stalagmite collected in the Argentarola Cave located on the Tyrrhenian coast of Italy. As shown from observations and numerical modeling of δ¹⁸O in modern precipitation, the recorded δ¹⁸O variability for this zone is dominated by the amount of precipitation (so-called ‘amount effect’). The δ¹⁸O profile measured in the stalagmite is characterized by a prominent negative excursion (ca. 2-3‰) between 180 and 170 kyr BP. This paleoclimatic feature is interpreted as being due to a relatively wet period which occurred during the penultimate glacial period, more precisely, during Marine Isotope Stage 6.5. This pluvial phase is shown to correspond chronologically to the deposition of the sapropel event 6 (S6). Although this particular sapropel event occurred during a cold phase, the δ¹⁸O excursion is similar to those corresponding to other sapropels (S4, S3 and S2). The evidence for humid conditions during S6 in the western Mediterranean basin agrees with previous studies based on deep-sea sediment cores. Taken collectively, the data suggest that during sapropel events dilution of ocean surface waters was not restricted to the output of the river Nile but was rather widespread over the entire Mediterranean Sea due to increased rainfall.     

A site effect study in the Verchiano valley during the 1997 Umbria-Marche (Central Italy) earthquakes

Strong site effects were observed during the two M _W 5.7 and M _W 6.0 main shocks of the Colfiorito seismic crisis which occured on September 26, 1997 in Umbria-Marche (Central Italy).The most obvious indications of these effects are the dramatic differences in damage shown by buildings of similar construction in neighboring villages.Such observations were specifically made in the Verchiano valley in the fault area, 15 km south of Colfiorito where the Verchiano village and the Colle and Camino hamlets were heavily damaged (MCS intensity IX-X) since the first main shock of 1997/09/26,while in contrast, the Curasci village located 2 km eastwards remains almost intact.In order to study the anomalous ground motion amplifications in this area, an array of 11, 3-components seismo- and accelero-meters was set up during the 1997/10/20-24 period, extending from the western side of the valley, up to the top of Mount San Salvatore, going accross the Colle and Curasci hamlets.During the experiment, 67 aftershocks enlightened the valley from the Colfiorito (10 km north) and the Sellano (6 km south) active swarms.Seismic refraction experiments were conducted at the same time in the 500 m wide, 1500 m long Verchiano valley in order to determine the thickness and main characteristics of the alluvial infilling.The main results are: (i) compared to the valley side ground motion, and for all the events, recordings in the central part of the valley (piana di Verchiano) show relative amplification of 10 with a clear lengthening of the seismogram duration by a factor of 2 – (ii) broad band relative amplification of 6–8 is also clearly identified at the top of the Mount San Salvatore overhanging the valley – (iii) any of the site effect measurements done explains by itself the strongly contrasted damage observed at Colle and Curasci: i.e. the modification of the near-field radiation pattern by interaction with the free heterogeneous surface may have induced local shadow zones that saved Curasci.