Inputs of iron,manganese and aluminium to surface waters of the Northeast Atlantic Ocean and the European continental shelf

Dissolved Fe, Mn and Al concentrations (dFe, dMn and dAl hereafter) in surface waters and the water column of the Northeast Atlantic and the European continental shelf are reported. Following an episode of enhanced Saharan dust inputs over the Northeast Atlantic Ocean prior and during the cruise in March 1998, surface concentrations were enhanced up to 4 nmol L^− 1 dFe, 3 nmol L^− 1 dMn and 40 nmol L^− 1 dAl and returned to 0.6 nmol L^− 1 dFe, 0.5 nmol L^− 1 dMn and 10 nmol L^− 1 dAl towards the end of the cruise three weeks later. A simple steady state model (MADCOW, [Measures, C.I., Brown, E.T., 1996. Estimating dust input to the Atlantic Ocean using surface water aluminium concentrations. In: Guerzoni. S. and Chester. R. (Eds.), The impact of desert dust across the Mediterranean, Kluwer Academic Publishers, The Netherlands, pp. 301–311.]) was used which relies on surface ocean dAl as a proxy for atmospheric deposition of mineral dust. We estimated dust input at 1.8 g m^− 2 yr^− 1 (range 1.0–2.9 g m^− 2 yr^− 1) and fluxes of dFe, dMn and dAl were inferred. Mixed layer steady state residence times for dissolved metals were estimated at 1.3 yr for dFe (range 0.3–2.9 yr) and 1.9 yr for dMn (range 1.0–3.8 yr). The dFe residence time may have been overestimated and it is shown that 0.2–0.4 yr is probably more realistic. Using vertical dFe versus Apparent Oxygen Utilization (AOU) relationships as well as a biogeochemical two end member mixing model, regenerative Fe:C ratios were estimated respectively to be 20 ± 6 and 22 ± 5 μmol Fe:mol C. Combining the atmospheric flux of dFe to the upper water column with the latter Fe:C ratio, a ‘new iron’ supported primary productivity of only 15% (range 7%–56%) was deduced. This would imply that 85% (range 44–93%) of primary productivity could be supported by regenerated dFe. The open ocean surface data suggest that the continental shelf is probably not a major source of dissolved metals to the surface of the adjacent open ocean. Continental shelf concentrations of dMn, dFe, and to a lesser extent dAl, were well correlated with salinity and express mixing of a fresher continental end member with Atlantic Ocean water flowing onto the shelf. This means probably that diffusive benthic fluxes did not play a major role at the time of the cruise.     

Origin of the metamorphosed clasts in the CV3 carbonaceous chondrite breccias of Graves Nunataks 06101, Vigarano,Roberts Massif 04143, and Yamato‐86009

We observed metamorphosed clasts in the CV3 chondrite breccias Graves Nunataks 06101, Vigarano, Roberts Massif 04143, and Yamato‐86009. These clasts are coarse‐grained polymineralic rocks composed of Ca‐bearing ferroan olivine (Fa_24–40, up to 0.6 wt% CaO), diopside (Fs_7–12Wo_44–50), plagioclase (An_52–75), Cr‐spinel (Cr/[Cr + Al] = 0.4, Fe/[Fe + Mg] = 0.7), sulfide and rare grains of Fe‐Ni metal, phosphate, and Ca‐poor pyroxene (Fs₂₄Wo₄). Most clasts have triple junctions between silicate grains. The rare earth element (REE) abundances are high in diopside (REE ~3.80–13.83 × CI) and plagioclase (Eu ~12.31–14.67 × CI) but are low in olivine (REE ~0.01–1.44 × CI) and spinel (REE ~0.25–0.49 × CI). These REE abundances are different from those of metamorphosed chondrites, primitive achondrites, and achondrites, suggesting that the clasts are not fragments of these meteorites. Similar mineralogical characteristics of the clasts with those in the Mokoia and Yamato‐86009 breccias (Jogo et al. 2012 ) suggest that the clasts observed in this study would also form inside the CV3 chondrite parent body. Thermal modeling suggests that in order to reach the metamorphosed temperatures of the clasts of >800 °C, the clast parent body should have accreted by ~2.5–2.6 Ma after CAIs formation. The consistency of the accretion age of the clast parent body and the CV3 chondrule formation age suggests that the clasts and CV3 chondrites could be originated from the same parent body with a peak temperature of 800–1100 °C. If the body has a peak temperature of >1100 °C, the accretion age of the body becomes older than the CV3 chondrule formation age and multiple CV3 parent bodies are likely.     

Validation of a chrysophyte stomatocyst‐based cold‐season climate reconstruction from high‐Alpine Lake Silvaplana,Switzerland

For the reliable assessment of past climate variability, quantitative reconstructions of seasonal temperatures are required. Currently, reconstructions of cold‐season temperatures are scarce, because most biological proxies are biased towards the growing season. Here we test the potential of chrysophyte stomatocysts (or simply ‘cysts’; siliceous resting stages of the golden‐brown algae) as a proxy for cold‐season temperature. Climate reconstructions based on biological proxies are commonly constructed using transfer functions derived from calibration in space. However, the performance of these reconstructions is rarely tested by direct comparison with meteorological data due to limitations of sample resolution or chronological control. We compare a cyst‐based near‐annual reconstruction of ‘date of spring mixing’ from the varved sediments of Lake Silvaplana (Swiss Alps) spanning AD 1870–2004 with climate variables from the same period measured at the lake shore. The high correlation between cyst‐based ‘date of spring mixing’ and cold‐season temperature demonstrates the ability of chrysophyte cysts to archive cold‐season temperature variability. Lake eutrophication, which was extensive during the last 50 years, had no obvious effect on the cyst‐based reconstruction. This study underlines the high potential of chrysophyte cysts as a quantitative proxy for cold‐season climate reconstructions. Copyright © 2011 John Wiley & Sons, Ltd.     

High-resolution numerical simulation of the Pacific Ocean

The present study developed Pacific Ocean models from the Research Institute for Applied Mechanics Ocean Model (RIAMOM) with very high horizontal (1/6° and 1/12°) and vertical (70 levels) resolutions. The hydrographic features of the simulations show good agreement with observed climatological features. Solution differences between the 1/6° and 1/12° models are small for general features of various physical components, but large for eddy fields and the strengths of western boundary currents and their extensions. However, the two high-resolution models show realistic climatological features of Pacific Ocean circulation patterns. Volume transports through major straits in the northwestern Pacific Ocean were also simulated and compared with previous observational results.     

Precambrian crustal evolution in Rangrim Massif,Korean Peninsula

Petrological, chronological and geotectonic geological analysis of Precambrian metamorphic rock in Korean Peninsula shows that the remnants （ 〉3.4 Ga） of continental nuclei crust were formed in the Paleoarchean in the Rangrim Massif. In the massif, the main formation ages of continental crust range from 3.2 Ga to 2.5 Ga, its important growing period was 2.8 - 2. 5 Ga. The subsequent expansion period of the Rangrim Massif was 2. 4 - 2. 2 Ga. The division events occurred in 1.85 Ga and in the Late Paleoproterozoic-Early Mesoproterozoic, respectively. Since then the massif was relatively stable. However, the last division of the Rangrim Massif occurred at 793 Ma.     

Elasto‐plastic seepage‐induced stresses due to tunneling

When tunneling is carried out beneath the groundwater table, hydraulic boundary is altered, resulting in seepage entering into the tunnel. The development of flow into the tunnel induces seepage stresses in the ground and the lining is subjected to additional loads. This can often cause fine particles to move, which clog the filter resulting in the long‐term hydraulic deterioration of the drainage system. However, the effect of seepage force is generally not considered in the analysis of tunnel. While several elastic solutions have been proposed by assuming seepage in an elastic medium, stress solutions have not been considered for the seepage force in a porous elasto‐plastic medium. This paper documents a study that investigates the stress behavior, caused by seepage, of a tunnel in an elasto‐plastic ground and its effects on the tunnel and ground. New elasto‐plastic solutions that adopt the Mohr–Coulomb failure criterion are proposed for a circular tunnel under radial flow conditions. A simple solution based on the hydraulic gradient obtained from a numerical parametric study is also proposed for practical use. It should be noted that the simple equation is useful for acquiring additional insight into a problem on a tunnel under drainage, because only a minimal computational effort is needed and considerable economic benefits can be gained by using it in the preliminary stage of tunnel design. The proposed equations were partly validated by numerical analysis, and their applicability is illustrated and discussed using an example problem. Comments on the tunnel analysis are also provided. Copyright © 2010 John Wiley & Sons, Ltd.     

Late Holocene effective precipitation variations in the maritime regions of south-west Scandinavia

At present, the climate in south-west Scandinavia is predominantly controlled by westerlies carrying moist Atlantic air, which forms a main source of precipitation in all seasons. Past variations in the ratio between precipitation and evaporation (effective precipitation) from terrestrial sites, however, may indicate changes in the degree of maritime influence. Palaeoclimatic archives in this region are thus ideally situated to study past changes in atmospheric circulation patterns. In this study, multi-proxy comparisons of records from three peat bogs and two lakes are used to reconstruct regional-scale variations of effective precipitation in south-west Sweden during the Late Holocene. The total aeolian sediment influx into two peat bogs is used as a proxy for storm activity. The frequency of storm phases increases strongly after ca 2500 cal yrs BP. Dry conditions occur on a regional scale around 4800–4400, 2000–1700, 1300–1000, 700–500 and 300–100 cal yrs BP. In addition, a comparison to winter precipitation reconstructed from four Norwegian glaciers shows similar variations during the past ca 2000 years. This indicates that the climate in both regions was controlled by large-scale atmospheric circulation dynamics of the North Atlantic region. The strong variability of effective precipitation and storm activity after ca 2500 cal yrs BP indicates a highly variable climate.     

土壤梯度温度测定方法模拟试验研究

土壤梯度温度的测定 ,由于测定过程中造成土体结构和地面覆盖物破坏和挠动 ,都可能造成测值的偏离 ,不能反映原态土壤梯度温度的真实情况。采用插入式多温点梯级组合测温探头进行土壤梯度温度的测定 ,是一种实现土壤原态———原位测定的可行方法。