Thermodynamic mixing properties of olivine derived from lattice vibrations

We use a lattice vibrational technique to derive thermophysical and thermochemical properties of fayalite, Fe₂SiO₄. This semi-empirical technique is based on an extension of Kieffer’s model to incorporate details of the phonon spectrum. It includes treatment of intrinsic anharmonicity and electronic effects based on crystal field theory. We extend it to predict thermodynamic mixing properties of olivine (Mg,Fe)₂SiO₄ solid solutions by using results of our previous work on the system MgO–SiO₂. Achieving this requires a relation between phonon frequency and composition and a composition relation for the energy of the static lattice. Directed by experimental Raman spectroscopic data for specific optic modes in magnesium–iron solid solutions of olivine and pyroxene we use an empirical relation for the composition dependence for phonon frequencies. We show that lattice vibrations have a large effect on the excess entropy and that the static lattice contribution and lattice vibrations have a large impact on excess enthalpy and excess Gibbs energy. Our model indicates that compositional effects in electronic and magnetic properties are negligible. The compositional variation the Néel temperature has a large impact on excess heat capacity for temperatures below 100 K.     

南堡凹陷古近纪幕式裂陷作用及其对沉积充填的控制

通过构造格架和层序地层格架的分析,结合区域不整合对比,将南堡凹陷地层与中国东部其他盆地进行对比,进行大型构造幕的确定,确认南堡凹陷古近系地层为区域可对比的裂陷Ⅲ幕和裂陷Ⅳ幕沉积。在此基础上,应用区域不整合规模的对比和火山活动期次研究,将南堡凹陷古近纪沉降划分为4个构造幕,并对各个构造幕的构造活动特征及其控制的沉积充填特征进行了分析。南堡凹陷的幕式构造活动可以分为三个阶段:在第一个阶段（即裂陷Ⅰ幕、裂陷Ⅱ幕）,完全受到边界断裂活动的控制;在第二阶段（即裂陷Ⅲ幕）,高柳断层开始活动,在南堡凹陷东部地区形成了陡坡断阶坡折带控制着沉积发育;而在第三阶段（即裂陷Ⅳ幕）,高柳断层发育为控边断裂并控制着其下降盘的沉积充填。     

Effect of different wavelengths of light on the antioxidant and immunity status of juvenile rock bream, <Emphasis Type="Italic">Oplegnathus fasciatus</Emphasis>, exposed to thermal stress

We investigated the effect of light wavelengths on antioxidant and immunity parameters in juvenile rock bream, Oplegnathus fasciatus, exposed to thermal stress (25 and 30°C). We exposed the fish to light emitting diodes (LEDs) emitting green (520 nm) and red light (630 nm) of 0.25 and 0.5 W/m² intensity, and measured the activity, and mRNA and protein expression levels of the antioxidant enzymes, superoxide dismutase, catalase, and glutathione peroxidase. We also determined the levels of plasma hydrogen peroxide (H₂O₂), melatonin, and lysozyme. Furthermore, the mRNA and protein levels of caspase-3 were measured and terminal transferase dUTP nick end labeling (TUNEL) assays were performed. We observed that mRNA expression and activities of antioxidant enzymes and plasma H₂O₂ levels were significantly higher after exposure to high temperatures. However, increases in these parameters were significantly lower after exposure to green LED light. The plasma melatonin and lysozyme levels were significantly lower in the different groups after exposure to high temperatures; however, in groups exposed to green LED light, their levels were significantly higher than those in the control group. The expression pattern of caspase-3 mRNA was similar to that of H₂O₂. The TUNEL assay showed that apoptosis was markedly higher at higher water temperatures than that at 20°C. These results indicate that high water temperatures induce oxidative stress and decrease the immunity in juvenile rock bream but green LED light inhibits the rise in oxidative stress and combats the decrease in immunity and should, thus, be useful in the culture of rock bream.     

Seismic fragility of lightly reinforced concrete frames with masonry infills

Seismic fragility of lightly reinforced concrete frames with masonry infills is assessed through numerical simulations considering uncertainty in ground motion and building materials. To achieve this aim, a numerical model of the components is developed, a rational approach to proportion and locate individual struts in the equivalent three‐strut model is proposed, and an explicit nonlinear column shear response model accounting for the infill–column interaction and soft‐story mechanism is employed. The proposed numerical model is used to (1) generate probabilistic seismic demand models accounting for a wide range of ground motion intensities with different frequency content and (2) determine limit state models obtained from nonlinear pushover analysis and incremental dynamic analysis. Using the demand and limit state model, fragility curves for the masonry‐infilled frames are developed to investigate the impact of various infill properties on the frame vulnerability. It is observed that the beneficial effect of the masonry infill diminishes at more severe limit states because of the interaction with the boundary frame. In some cases, this effect almost vanishes or switches to an adverse effect beyond a threshold of ground motion intensities. Copyright © 2015 John Wiley & Sons, Ltd.     

Framework of aftershock fragility assessment–case studies: older California reinforced concrete building frames

Current seismic design codes and damage estimation tools neglect the influence of successive events on structures. However, recent earthquakes have demonstrated that structures damaged during an initial event (mainshock) are more vulnerable to severe damage and collapse during a subsequent event (aftershock). This increased vulnerability to damage translates to increased likelihood of loss of use, property, and life. Thus, a reliable risk assessment tool is required that characterizes the risk of the undamaged structure subjected to an initial event and the risk of the damaged structure under subsequent events. In this paper, a framework for development of aftershock fragilities is presented; these aftershock fragilities define the likelihood that a building damaged during a mainshock will exhibit a given damage state following one or more aftershocks. Thus, the framework provides a method for characterizing the risk associated with damage accumulation in the structure. The framework includes the following: (i) creation of a numerical model of the structure; (ii) characterization of building damage states; (iii) generation of a suite of mainshock–aftershocks; (iv) mainshock–aftershock analyses; and (v) development of aftershock fragility curves using probabilistic aftershock demand models, defined as a linear regression of aftershock demand–intensity pairs in a logarithmic space, and damage‐state prediction models. The framework is not limited to a specific structure type but requires numerical models defining structural response and linking structural response with damage. In the current study, non‐ductile RC frames (low‐rise, mid‐rise, and high‐rise) are selected as case studies for the application of the framework. Copyright © 2015 John Wiley & Sons, Ltd.     

Evolution of calc-alkaline to alkaline magmatism through Carboniferous convergence to Permian transcurrent tectonics,western Chinese Tianshan

Continuous magmatic activity occurred in the western Chinese Tianshan, Central Asia, from the Carboniferous to the Permian, i.e. before and after the Late Carboniferous amalgamation of Junggar and the Yili Blocks. Zircon U–Pb LA-ICPMS and Ar–Ar data reveal a coincidence in time between regional wrench faulting and granitoid emplacement. Permian post-collisional granitoids crop out within or at the margins of large-scale dextral strike-slip shear zones, some of them show synkinematic fabrics. The whole rock geochemical features of the Early-Middle Permian granitoids indicate an evolution from high-K calc-alkaline towards alkaline series. In other places of the North Tianshan, alkaline magmatism occurred together with deep marine sedimentation within elongated troughs controlled by wrench faults. Therefore, in contrast with previous interpretations that forwarded continental rift or mantle plume hypotheses, the coexistence of diverse magmatic sources during the same tectonic episode suggests that post-collisional lithosphere-scale transcurrent shearing tightly controlled the magmatic activity during the transition from convergent margin to intraplate anorogenic processes.     

Spatial and Temporal Scale Variations of Sea Surface Temperature in the East Sea Using NOAA/AVHRR Data

Sea surface temperature fields in the East Sea are composed of various spatial structures such as eddies, fronts, filaments, turbulent-like features and other mesoscale variations associated with the oceanic circulations of the East Sea. These complex SST structures have many spatial scales and evole with time. Semi-monthly averaged SST distributions based on extensive satellite observations of SSTs from 1990 through 1995 were constructed to examine the characteristics of their spatial and temporal scale variations by using statistical methods of multi-dimensional autocorrelation functions and spectral analysis. Two-dimensional autocorrelation functions in the central part of the East Sea revealed that most of the spatial SST structures are anisotropic in the shape of ellipsoids with minor axes of about 90–290 km and major axes of 100–400 km. Two dimensional spatial scale analysis demonstrated a consistent pattern of seasonal variation that the scales appear small in winter and spring, increase gradually to summer, and then decrease again until the spring of the next year. These structures also show great spatial inhomogeneity and rapid temporal change on time scales as short as a semi-month in some cases. The slopes in spectral energy density spectra of SSTs show characteristics quite similar to horizontal and geostrophic turbulence. Temporal spectra at each latitude are demonstrated by predominant peaks of one and two cycles per year in all regions of the East Sea, implying that SSTs present very strong annual and semi-annual variations. This revised version was published online in August 2006 with corrections to the Cover Date.     

The distribution and preferential biological uptake of cadmium at 6°W in the Southern Ocean

The spatial and temporal distribution of cadmium (Cd) and phosphate in the Southern Ocean are related to biology and hydrography. During a period of 18 days between transects 5/6 and 11, a phytoplankton spring bloom developed in the Polar Frontal region. Upper water Cd concentrations were not depleted and ranged from 0.2 to 0.8 nM at about 10 m depth. These relatively high Cd concentrations are attributed to upwelling of Upper Circumpolar Deep Water (0.5–1.2 nM in the core) in combination with low biological productivity (0.2 to 0.3 mg m⁻³ chlorophyll-a, 0.3 g C m⁻² d⁻¹). Total particulate Cd concentrations at 40 m depth were between 0.02 and 0.14 nM with the maximum in concentration in the Polar Frontal region. Most of the particulate Cd at this depth (85–94%) was detected in the first phase of a sequential chemical leaching treatment which includes adsorbed Cd as well as Cd incorporated in algae. The Polar Frontal region was characterized by minima in Cd concentration and Cd/phosphate ratio of seawater at both transects; values were the lowest at transect 11 after development of the spring bloom which was dominated by diatoms. This decreasing Cd/phosphate ratio in seawater during spring bloom development was attributed to preferential Cd gross uptake which more than compensated the process of preferential Cd recycling. Within the Upper Circumpolar Deep Water, Cd showed a maximum in concentration similar to that of the major nutrients. Both the Cd concentration and the Cd/phosphate ratio of the deeper water increased in southern direction, from 0.4 to 0.7 nM and from 0.2 to 0.3 nM/μM, respectively. Antarctic Intermediate Water has a Cd concentration of 0.21 nM with a Cd/phosphate ratio of 0.10 nM/μM. In Antarctic Bottom Water, Cd concentrations ranged from 0.60 to 0.82 nM.     

Influence of Obstacles on the Aerodynamic Roughness of the Netherlands

The aim of this study was to analyse the influence of large- and small-scale obstacles (orography, tree lines, and dikes) on the effective aerodynamic roughness of the Netherlands, a relatively flat, small-scale landscape. The roughness averaging approach was based on drag coefficients. The effective roughness was locally dominated by small-scale obstacles such as tree lines and dikes. Even at a regional scale (40,000 km2), the small-scale obstacle drag was of the same order of magnitude as the shear stress due to landuse. The neglect of those obstacles on a regional scale would result in approximately 10% overestimated averaged windspeed at 10~m above the surface. It was concluded that small-scale obstacles need to be taken into account to calculate the aerodynamic roughness of flat landscapes. Orography was of minor importance in this lowland country.     

Evolution of the Taebaeksan Basin,Korea: I,early Paleozoic sedimentation in an epeiric sea and break‐up of the Sino‐Korean Craton from Gondwana

The Taebaeksan Basin is located in the mid‐eastern part of the southern Korean Peninsula and tectonically belonged to the Sino‐Korean Craton (SKC). It comprises largely the lower Paleozoic Joseon Supergroup and the upper Paleozoic Pyeongan Supergroup which are separated by a disconformity representing a 140 myr?long hiatus. This paper explores the early Paleozoic paleogeographical and tectonic evolution of the Taebaeksan Basin on the basis of updated stratigraphy, trilobite faunal assemblages, and detrital zircon U–Pb ages of the Joseon Supergroup. The Joseon Supergroup is a shallow marine siliciclastic‐carbonate succession ranging in age from the Cambrian Series 2 to Middle Ordovician. The Ongnyeobong Formation is the sole Upper Ordovician volcanic succession documented in the Taebaeksan Basin. It is suggested that in the early Paleozoic the Taebaeksan Basin was a part of an epeiric sea, the Joseon Sea, in east Gondwana. The Joseon Sea was the depositional site for lower Paleozoic successions of the SKC. Early Paleozoic sedimentation in the Joseon Sea commenced during the Cambrian Stage 3 (～ 520 Ma) and ceased by the end of the Darriwilian (～ 460 Ma). In the early Paleozoic, the SKC was located at the margin of east Gondwana and was separated from the South China Craton by an oceanic basin with incipient oceanic ridges, the Helan Trough. The spreading oceanic ridges and associated transform faults possibly promoted the uplift of the Joseon Sea, which resulted in cessation of sedimentation and break‐up of the SKC from core Gondwana by the end of the Ordovician.