Fluid and silicate glass inclusions in ultramafic and mafic xenoliths from Hierro,Canary Islands: implications for mantle metasomatism

Fluid and solid inclusions have been studied in selected samples from a series of spinel-bearing Crdiopside-and Al-augite-series ultramafic (harzburgites, lherzolites, and olivine-clinopyroxene-rich rocks), and gabbroic xenoliths from Hierro, Canary Islands. In these samples several generations of fluid inclusions and ultramafic-and mafic-glass inclusions may be texturally related to different stages of crystal growth. The fluid inclusions consist of pure, or almost pure, CO₂. The solid inclusions in the ultramafic xenoliths comprise early inclusions of devitrified ultramafic glass, sulphide inclusions, as well as polyphase inclusions (spinel+clinopyroxene±glass±other silicates) believed to have formed from trapped basaltic melts. Vitreous basaltic glass±CO₂±sulphide±silicates are common as secondary inclusions in the ultramafic xenoliths, and as primary inclusions in the gabbroic xenoliths. Microthermometry gives minimum trapping temperatures of 1110° C for the early ultramafic-and mafic-glass inclusions, and a maximum of 1260–1280° C for late inclusions of host basaltic glass. In most samples the CO₂ inclusions show a wide range in homogenization temperatures (-40 to +31° C) as a result of decrepitation during ascent. The lowest homogenization temperatures of about-40° C, recorded in some of the smallest CO₂ inclusions, indicate a minimum depth of origin of 35 km (12 kbar) for both the Cr-diopside-and Al-augite-series xenoliths. The gabbroic xenoliths originate from a former magma chamber at a depth of 6–12 km.Contribution no. 100 of the Norwegian programme of the International Lithosphere Project     

Morphology and emplacement of an unusual debris-avalanche deposit at Jocotitlán volcano,Central Mexico

A pre-historic collapse of the northeastern flank of Jocotitlán Volcano (3950 m), located in the central part of the Trans Mexican Volcanic Belt, produced a debris-avalanche deposit characterized by surficial hummocks of exceptional size and conical shape. The avalanche covered an area of 80 km², had an apparent coefficient of friction (H/L)_of 0.11, a maximum runout distance of 12 km, and an estimated volume of 2.8 km³. The most remarkable features of the Jocotitlán debris avalanche deposit are: the several steep (29–32°) conical proximal hummocks (up to 165 m high), large tansverse ridges (up to 205 m high and 2.7 km long) situated at the base of the volcano, and the steep 15–50 m thick terminal scarp. Proximal conical hummocks and parallel ridges that can be visually fitted back to their pre-collapse position on the mountain resulted from a sliding mode of emplacement. Steep primary slopes developed as a result of the accumulation of coarse angular clasts at the angle of repose around core clasts that are decameters in size. Distal hummocks are commonly smaller, less conical, and clustered with more diffuse outlines. Field evidence indicates that the leading distal edge of the avalanche spilled around certain topographic barriers and that the distal moving mass had a yield strength prior to stopping. In the NE sector, the avalanche was suddenly confined by topographically higher lacustrine and volcaniclastic deposits which as a result were intensely thrust-faulted, folded, and impacted by large clasts that separated from the avalanche front. Post-emplacement loading also induced normal faulting of these soft, locally water-rich sediments. The regional tectonic pattern, N-NE direction of flank failure, and the presence of a major normal fault which intersects the volcano and is parallel to the orientation of the Acambay graben located 10 km to the N suggest a genetic relationship between the extensional tectonic stress regime and triggering of catastrophic slope failure. The presence of a 3-m-thick sequence of pumice and obsidian-rich pyroclastic surge and fall tephra directly overlying the debris-avalanche deposit indicates that magma must have been present within the edifice just prior to the catastrophic flank failure. The breached crater left by the avalanche has mostly been filled by dacitic domes and lava flows. The youngest pryroclastic surge deposits on the upper flanks of the volcano have an historical C¹⁴ age of 680±80 yearsBp (Ad 1270±80). Thus Jocotitlán volcano, formerly believed to be extinct, should be considered potentially active. Because of its close proximity to Mexico-City (60 km), the most populous city in the world, reactivation could engender severe hazards.     

Fully-implicit simulation of vertical-equilibrium models with hysteresis and capillary fringe

Geological carbon storage represents a new and substantial challenge for the subsurface geosciences. To increase understanding and make good engineering decisions, containment processes and large-scale storage operations must be simulated in a thousand year perspective. A hierarchy of models of increasing computational complexity for analysis and simulation of large-scale CO₂ storage has been implemented as a separate module of the open-source Matlab Reservoir Simulation Toolbox (MRST). This paper describes a general family of two-scale models available in this module. The models consist of two-dimensional flow equations formulated in terms of effective quantities obtained from hydrostatic reconstructions of vertical pressure and saturation distributions. The corresponding formulation is fully implicit and is the first to give a mass-conservative treatment and include general (non-linearized) CO₂ properties. In particular, the models account for compressibility, dissolution, and hysteresis effects in the fine-scale capillary and relative permeability functions and can be used to accurately and efficiently study the combined large-scale and long-term effects of structural, residual, and solubility trapping.     

Lifetimes of some excited states in the rare earths: La ii,Ce ii,Pr ii,Nd ii,Sm ii,Yb i,Yb ii,and Lu ii

Radiative lifetimes for excited states in La ii, Ce ii, Pr ii, Nd ii, Sm ii, Yb i, Yb ii, and Lu ii have been determined by means of the beam-foil technique or the zero-field level-crossing method. The lifetimes for La, Ce, Pr, Nd, Sm, and Yb are shorter than those computed by summing the transition probabilities of Corliss and Bozman by a factor of up to ~5. The large discrepancies between the abundance of La, Ce, Pr, Nd, and Sm in the solar photosphere and in meteorites are eliminated or greatly reduced if the abundance determinations of the solar photosphere are based upon the gf values of Corliss and Bozman, corrected for by the present lifetimes.     

River–aquifer interactions in a semi‐arid environment stressed by groundwater abstraction

Rivers and aquifers are, in many cases, a connected resource and as such the interactions between them need to be understood and quantified for the resource to be managed appropriately. The objective of this paper is to advance the understanding of river–aquifer interactions processes in semi‐arid environments stressed by groundwater abstraction. This is performed using data from a specific catchment where records of precipitation, evapotranspiration, river flow, groundwater levels and groundwater abstraction are analysed using basic statistics, hydrograph analysis and a simple mathematical model to determine the processes causing the spatial and temporal changes in river–aquifer interactions. This combined approach provides a novel but simple methodology to analyse river–aquifer interactions, which can be applied to catchments worldwide. The analysis revealed that the groundwater levels have declined (~ 3 m) since the onset of groundwater abstraction. The decline is predominantly due to the abstraction rather than climatic changes (r = 0.84 for the relationship between groundwater abstraction and groundwater levels; r = 0.92 for the relationship between decline in groundwater levels and magnitude of seasonal drawdown). It is then demonstrated that, since the onset of abstraction, the river has changed from being gaining to losing during low‐flow periods, defined as periods with flow less than 0.5, 1.0 or 1.5 GL/day (1 GL/day = 1 × 10⁶ m³/day). If defined as < 1.0 GL/day, low‐flow periods constitute approximately 65% of the river flows; the periods where the river is losing at low‐flow conditions are thus significant. Importantly, there was a significant delay (> 10 years) between the onset of groundwater abstraction and the changeover from gaining to losing conditions. Finally, a relationship between the groundwater gradient towards the river and the river flow at low‐flow is demonstrated. The results have important implications for water management as well as water ecology and quality. Copyright © 2012 John Wiley & Sons, Ltd.