Calibration of the New Certified Reference Materials ERM‐AE633 and ERM‐AE647 for Copper and IRMM‐3702 for Zinc Isotope Amount Ratio Determinations

The commonly used, but no longer available, reference materials NIST SRM 976 (Cu) and ‘JMC Lyon’ (Zn) were calibrated against the new reference materials ERM^®‐AE633, ERM^®‐AE647 (Cu) and IRMM‐3702 (Zn), certified for isotope amount ratios. This cross‐calibration of new with old reference materials provides a continuous and reliable comparability of already published with future Cu and Zn isotope data. The Cu isotope amount ratio of NIST SRM 976 yielded δ^65/63Cu values of ?0.01 ± 0.05‰ and ?0.21 ± 0.05‰ relative to ERM^®‐AE633 and ERM^®‐AE647, respectively, and a δ^66/64Zn_IRMM‐3702 value of ?0.29 ± 0.05‰ was determined for ‘JMC Lyon’. Furthermore, we separated Cu and Zn from five geological reference materials (BCR‐2, BHVO‐2, BIR‐1, AGV‐1 and G‐2) using a two‐step ion‐exchange chromatographic procedure. Possible isotope fractionation of Cu during chromatographic purification and introduction of resin‐ and/or matrix‐induced interferences were assessed by enriched ⁶⁵Cu isotope addition. Instrumental mass bias correction for the isotope ratio determinations by MC‐ICP‐MS was performed using calibrator‐sample bracketing with internal Ni doping for Cu and a double spike approach for Zn. Our results for the five geological reference materials were in very good agreement with literature data, confirming the accuracy and applicability of our analytical protocol.     

Transient creep of the lithosphere and its role in geodynamics

Laboratory experiments with samples of rocks show that at small strains there is transient creep, at which the strain grows with time, and the strain rate decreases. Plate tectonics allows only small strains in the lithospheric plates, so that the lithosphere creep is transient. In geodynamics, the lithosphere is regarded as a cold boundary layer formed by mantle convection. If we assume that the lithosphere has a steady-state creep, which is described by power-law non-Newtonian rheological model, the low effective viscosity of the lower layers of the lithosphere, obtained by data on small-scale postglacial flows, is possible only at high strain rates in these layers. However, the high strain rates in the lithosphere induce large strains that contradict plate tectonics. Transient creep of the lithosphere leads to its mobility at small strains, removing the discrepancy between thermal convection in the mantle and plate tectonics, which holds in the case of power-law rheological model of the lithosphere.     

Zirconolite and xenotime U–Pb age constraints on the emplacement of the Golden Mile Dolerite sill and gold mineralization at the Mt Charlotte mine,Eastern Goldfields Province,Yilgarn Craton,Western Australia

In situ SHRIMP U–Pb dating of magmatic zirconolite (CaZrTi₂O₇) in the Golden Mile Dolerite from the Mt Charlotte gold deposit (Yilgarn Craton, Australia) has yielded the first robust emplacement age (2,680 ± 9 Ma) for the principle host-rock of gold mineralization in the Kalgoorlie district. In contrast, co-magmatic zircon gave ages from ~2.68 Ga to ~2.17 Ga, reflecting isotopic resetting of high-U and -Th crystals. In situ SHRIMP analysis of hydrothermal xenotime (YPO₄), which co-exists with gold in alteration pyrite, provided a Pb/Pb isochron age of 2,655 ± 13 Ma. This date indicates that the youngest deposit in the Kalgoorlie district (Mt Charlotte) formed at ~2.65 Ga, and provides a new minimum age for the structurally older Golden Mile deposit. Our results indicate that gold mineralization at Mt Charlotte is ~50 million years older than indicated by recent ⁴⁰Ar/³⁹Ar dating and places new constraints on the timing of late-stage regional faulting (D₄) in the province.     

Making the EU Emissions Trading System: The European Commission as an entrepreneurial epistemic leader

The EU has developed the first and largest international emissions trading system in the world. This development is puzzling due to the EU's scepticism to international emissions trading in greenhouse gases (GHGs) in the run-up to the 1997 Kyoto Protocol. This article analyses how the EU ETS was initiated in the first place mainly from the perspectives of Liberal intergovernmentalism (LI) and multi-level governance (MLG). LI emphasises change in the positions of the EU member states as the key to understand what happened and why, whereas MLG opens up for change in the position of supranational entrepreneurial leaders as the key explanation. The main conclusion is that entrepreneurial epistemic leadership exercised by the European Commission was crucial for making the EU ETS. The principal means of leadership involved building up independent expertise on how an EU ETS could be designed, and mobilizing support from state and non-state actors at various levels of decision-making. This type of leadership may be needed more generally to deal with challenges characterized by high scientific uncertainty and social complexity in which learning is pertinent, such as climate change.     

MgAl2O4 spinels from Allende and NWA 763 carbonaceous chondrites: Structural refinement,cooling history,and trace element contents

MgAl₂O₄ spinels from Allende and NWA 763 carbonaceous chondrites were studied by X‐ray single crystal diffraction, SEM, electron microprobe, LA‐ICP‐MS, and Raman spectroscopy. Those from Allende are almost pure, but, in one case, we found a strong FeO_tot zonation. Spinels from NWA 763 show Mg‐Fe²⁺ substitutions. Almost pure MgAl₂O₄ spinels from both meteorites underwent slow cooling and reached their intracrystalline closure temperature (T_c) in the range 460–520 °C. The NWA 763 spinel with higher FeO content shows a T_c of about 720 °C. X‐ray single crystal diffraction and Raman spectroscopy suggest a slow cooling and an ordered structure with trivalent cations in M site and divalent in T site. Among the trace elements, Ti and Co are enriched with respect to the terrestrial analogs, while Mn, Ni, and Sn show intermediate values between different terrestrial occurrences. Vanadium cannot be used as a tracer of extraterrestrial origin as for Cr‐spinels, because its content is similar in extraterrestrial and terrestrial spinels. In the zoned crystal from Allende, Co show a strong zonation similar to that of FeO.     

Flow through nets and trawls of low porosity

In trawls intended for harvesting marine zooplankton the mesh size and twine thickness may be as small as O(10⁻⁴ m), the porosity less than 0.5 and the appropriate Reynolds number O(10⁰−10²). The flow locally through the meshes varies strongly with the Reynolds number in this range, and the entire flow field, filtered volume and drag of such nets therefore depend strongly on the net parameters and towing velocity.This paper presents a simplified model for the flow through and forces on inclined permeable screens based on pressure drop considerations. For conical nets the model provides simple expressions for the filtration efficiency and drag as functions of twine diameter, mesh opening, porosity, taper angle and flow (towing) velocity. Comparisons with test tank measurements of typical plankton nets show good agreement.     

Barium, SiO2 (excess), and P2O5 as proxies of biological productivity in the Middle East during the Palaeocene and the latest Palaeocene benthic extinction event

The distribution of barium and other elements related to biological productivity has been studied in two Palaeocene sections from the Middle East. In the bathyal Ben Gurion section, Israel, Ba* (= Ba/Al₂O₃× 15%) concentrations are low, in the range 0.04% to 0.3% in the lower Palaeocene, and very high, 1% to 2%, throughout most of the upper Palaeocene. In the neritic Gebel Aweina section in Egypt Ba* values are low, < 0.1%, throughout the entire Palaeocene. The Ba* enrichments at Ben Gurion and their correlations with increases in P₂O₅ and opaline silica, and local and global δ¹³C maxima, indicate that upwelling and high productivity were important in this region during the late Palaeocene. The absence of Ba* enrichments in the shallower Gebel Aweina section probably reflects the strong depth dependence of biobarium deposition. In the uppermost Palaeocene, at the level where the global benthic extinction event is registered, Ba* concentrations in the Ben Gurion section increase to anomalous 6%. which suggests that upwelling and possibly wind strengths intensified during this event. The results speak against deep-water formation in this region since downwelling and not upwelling is required.     

Application of the Lorenz equations for studying thermal convection in the lithosphere

Stationary solutions including wave solutions with constant amplitudes are found for nonlinear equations of thermal convection in a layer with nonlinear rheology. The solution is based on the Fourier expansion of unknown velocities and temperatures with only the first and first two terms retained in the velocity and temperature series, respectively. This method, which can be regarded as the Lorenz method, yields the Lorenz equations that fairly well describe the thermal convection in a layer with Newtonian rheology if the Rayleigh number is not very large. The obtained generalization of the Lorenz equations to the case of an integral (having a memory) nonlinear rheology implies that only the first term is retained in the Fourier series for the stress components, i.e., the nonlinear rheological equation is harmonically linearized. However, in the Fourier series of temperature, it is essential to keep the second term: this term, which is independent of the horizontal coordinate, models the thermal boundary layer that characterizes the developed convection. We constructed the bifurcation curves that describe the stationary convection in the nonlinear integral medium simulating the rheology of the mantle, and analyzed the stability of stationary convective flows. The Lorenz method is applied to study small-scale thermal convection in the lithosphere of the Earth.