阳离子交换树脂吸附石墨炉原子吸收法测定海水中痕量铜、铅、镉

用阳离子交换树脂吸附石墨炉原子吸收法测定海水中痕量Cu,Pb,Cd。实验选定了最佳的测定条件。结果表明,在弱碱性条件下,Cu,Pb,Cd能同时被阳离子交换树脂定量吸附。方法的相对标准偏差<3﹪,样品加标回收率93﹪～102﹪,检出限分别为Cu 0.06μg/L,Pb 0.06μg/L,Cd 0.005μg/L。本法操作简便、快速、无干扰、无污染,已用于海水中铜、铅、镉的分析,取得了令人满意的结果。     

海底沉积物取样的扰动机理研究

海底沉积物取样技术对大洋诸多科学研究来说非常重要,各种研究目标的实现与沉积物样品的质量息息相关.在使用常规管状取样器对松软或轻微固结的沉积物取样时,沉积物样品的扰动总是不可避免的.以机械手持式沉积物取样器为原型机,建立了管状取样器的取样过程模型,分析了沉积物样品的扰动机理;采用球形孔扩张理论获得了沉积物土体受到取样管挤压扩张的理论解;结合太平洋具体沉积物土体物理力学参数,对管状取样器取样造成沉积物扰动的状况给出了一个定量描述,并且提出取样管壁的厚度是减小沉积物扰动的关键参数.     

一种新型电镀法制备的Ir/Ir(OH)x pH电极及其在加州纽波特港海域的应用研究

Resulting from the rising levels of atmospheric carbon, ocean acidification has become a global problem. It has significant impacts on the development, survival, growth and physiology of marine organisms. Therefore, a highprecision sensor is urgently needed to measure the pH of sea-water. Iridium wire with a diameter of 0.25 mm is used as the substrate, and an Ir/Ir(OH)_x pH electrode is prepared by a one-step electrochemical method in a Li OH solution at the room temperature. A scanning electron microscope(SEM) observation reveals that it is coated with nanoscale particles. In laboratory tests, the electrode exhibits a very promising pH response, with an ideal Nernst slope(56.14–59.52), fast response, good stability and long life-span in tested pH buffer solutions. For a sea trial,four pH electrodes and one Ag/Ag Cl reference electrode are integrated with a self-made chemical sensor, and a profile detection of nearly 70 m is implemented near Newport Harbor, California on August 3, 2015. The results reflect that the pH value measured by the sensor is very close to the data given by Sea-Bird 911 plus CTD, with a difference value ranging from 0.000 075 to 0.064 719. And the sensor shows a better data matching degree in 0–40m water depth. In addition, the high precision and accuracy of the sensor make it possible to use in the ocean observation field.     

海底沉积物取样扰动的有限元研究

应用非线性有限元分析方法,对管状取样器取样过程中的沉积物扰动状况进行了研究.建立了取样管与沉积物接触的二维轴对称有限元模型.重点分析了取样时取样管内沉积物的变形、应力和应变状况.有限元分析结果表明了取样管贯入过程中沉积物应力、应变均产生了变化,扰动显著.证实了工程实际中取样所造成的沉积物样品原始层序混杂或弯曲变形、长度缩短等扰动的后果.海底沉积物的低扰动取样样品对于诸多海洋科学研究非常重要.