A new procedure for separating and measuring radiogenic isotopes (U, Th, Pa, Ra, Sr, Nd, Hf) in ice cores

A new method for the radiogenic isotope (U–Th–Pa–Ra, Sr, Nd, Hf) analysis of the soluble and insoluble components found within ice cores is presented. Melting experiments with rock standards in the presence of EDTA indicate that carbonates, as well as silicates, can be buffered sufficiently to preclude dissolution. The use of EDTA allows adsorbing species, such as Th and Hf, to remain in solution during melting thus fully separating the dust (insoluble) and sea salt (soluble) components of the ice after filtration. A new elemental separation scheme for low sample masses, less than 5 mg solid material, utilizes 4 primary ion exchange columns and two “clean-up” columns to fully isolate U, Th, Pa, Ra, Sr, Nd, and Hf while maintaining high yields. Elution schemes measured for USGS rock standards and a Chinese loess are presented to provide a comparison for variable matrix compositions. Mass spectrometer techniques were modified to measure small aliquots of the standards, equivalent to the amounts found in ice core samples, 10 ng and less. A MC-ICPMS was employed for the measurement of U, Th, Pa, Ra, and Hf; results of the experiments show that with ion yields up to 1%, rock standards have errors for ²³⁴U/²³⁸U of 1%, ²³⁰Th/²³²Th of 1.5%, [²²⁸Ra] of 9%, and ¹⁷⁶Hf/¹⁷⁷Hf of 100 ppm. MC-TIMS measurements of Sr and Nd show similar errors for small sample sizes: ⁸⁷Sr/⁸⁶Sr of 50 ppm and ¹⁴³Nd/¹⁴⁴Nd of 80 ppm. This new analytical method increases the number of possible tracers measured from a single sample, reducing separation times and sample consumption, as well as providing the addition of a radiometric clock, U-series, to the traditional suite of isotopic tracers, Sr, Nd, and Hf.     

The iron-nickel-phosphorus system: Effects on the distribution of trace elements during the evolution of iron meteorites

To better understand the partitioning behavior of elements during the formation and evolution of iron meteorites, two sets of experiments were conducted at 1 atm in the Fe-Ni-P system. The first set examined the effect of P on solid metal/liquid metal partitioning behavior of 22 elements, while the other set explored the effect of the crystal structures of body-centered cubic (α)- and face-centered cubic (γ)-solid Fe alloys on partitioning behavior. Overall, the effect of P on the partition coefficients for the majority of the elements was minimal. As, Au, Ga, Ge, Ir, Os, Pt, Re, and Sb showed slightly increasing partition coefficients with increasing P-content of the metallic liquid. Co, Cu, Pd, and Sn showed constant partition coefficients. Rh, Ru, W, and Mo showed phosphorophile (P-loving) tendencies. Parameterization models were applied to solid metal/liquid metal results for 12 elements. As, Au, Pt, and Re failed to match previous parameterization models, requiring the determination of separate parameters for the Fe-Ni-S and Fe-Ni-P systems.Experiments with coexisting α and γ Fe alloy solids produced partitioning ratios close to unity, indicating that an α versus γ Fe alloy crystal structure has only a minor influence on the partitioning behaviors of the trace element studied. A simple relationship between an element’s natural crystal structure and its α/γ partitioning ratio was not observed. If an iron meteorite crystallizes from a single metallic liquid that contains both S and P, the effect of P on the distribution of elements between the crystallizing solids and the residual liquid will be minor in comparison to the effect of S. This indicates that to a first order, fractional crystallization models of the Fe-Ni-S-P system that do not take into account P are appropriate for interpreting the evolution of iron meteorites if the effects of S are appropriately included in the effort.     

Desert knowledge: integrating knowledge and development in arid and semi-arid drylands

Globalisation presents particular challenges for deserts given that their sparse populations, which are amongst the world’s poorest in an absolute economic sense, tend to be remote from major markets and have only a distant, marginal voice in political and policy decision making. Here we are defining deserts as the arid and semi-arid drylands that encompass 70% of Australia and 25% of the world’s land surfaces. The value of the knowledge that local traditions and science have generated about living sustainably in deserts is being promoted and extended through the ‘desert knowledge’ movement in Australia. The Australian research reported here, together with a contribution from Niger that offers a contrast and some lessons for Australia, is largely underpinned by a neopopulist paradigm of development stressing respect for local knowledge, participatory practice and empowerment. Research in partnership with desert Aboriginal groups is contributing to their engagement with new livelihood opportunities. The local knowledge of livestock graziers is also being engaged to support sustainable management of desert water sources and landscapes for multiple values. The research reported here also addresses opportunities and challenges for local norms, identities, knowledge systems, governance and livelihoods from broader scale processes and institutions. In doing so it contributes to a ‘neo-ideographic approach’ wherein desert people might better harness their locality, knowledge and diversity in adaptations that shape their encounters with globalisation. It also points to considerable scope to mature such an approach.     

Grassroots “flexible specialisation” in Brisbane’s West End: towards a politics of economic possibility

The focus on ‘flexible specialisation’ in the 1980s and 1990s marked an important turning point in framings of economic agency and diversity within economic geography. This article deconstructs the ways in which subjects were framed as ‘flexible’ in both the flexible specialisation literature and later work on the Diverse Economy (Gibson-Graham 1996, 2002, 2006), seeking out particular examples of the ways in which different projects of subjection appear to frame different views of economic possibility. Drawing richly on a case study of residents in an inner-city neighbourhood of West End, Brisbane (Australia), this paper uses resident’s articulations of their everyday practices to reinvigorate some of the ideas of the flexible specialisation literature and challenge, defamiliarise and rework existing ideas of economic life in “First World”, urban contexts.     

The early-type galaxies NGC 1407 and NGC 1400 – I. Spatially resolved radial kinematics and surface photometry

This is the first paper of a series focused on investigating the star formation and evolutionary history of the two early-type galaxies NGC 1407 and NGC 1400. They are the two brightest galaxies of the NGC 1407 (or Eridanus-A) group, one of the 60 groups studied as part of the Group Evolution Multi-wavelength Study.
Here, we present new high signal-to-noise ratio long-slit spectroscopic data obtained at the ESO 3.6-m telescope and high-resolution multiband imaging data from the Hubble Space Telescope /Advanced Camera for Surveys and wide-field imaging from Subaru Suprime-Cam. We spatially resolved integrated spectra out to ∼0.6 (NGC 1407) and ∼1.3 (NGC 1400) effective radii. The radial profiles of the kinematic parameters v _rot, σ, h ₃ and h ₄ are measured. The surface brightness profiles are fitted to different galaxy light models and the colour distributions analysed. The multiband images are modelled to derive isophotal shape parameters and residual galaxy images. The parameters from the surface brightness profile fitting are used to estimate the mass of the possible central supermassive black hole in NGC 1407. The galaxies are found to be rotationally supported and to have a flat core in the surface brightness profiles. Elliptical isophotes are observed at all radii and no fine structures are detected in the residual galaxy images. From our results, we can also discard a possible interaction between NGC 1400, NGC 1407 and the group intergalactic medium. We estimate a mass of  ∼1.03 × 10⁹ M_⊙  for the supermassive black hole in NGC 1407 galaxy.     

Ice grain size and the rheology of the martian polar deposits

The history and dynamics of the martian polar deposits (MPD), the largest known water reservoirs on Mars, are of great interest, but estimates of ice grain size are required before detailed modeling can be performed. We clarify the microphysical processes that may control grain size in the MPD. If the MPD are ∼2% dust by mass, the maximum ice grain size is ∼1 mm due to grain boundary pinning by silicate microparticles. Relatively dusty layers in the MPD will have smaller grain sizes. If MPD ice has a very low impurity content and has experienced a significant amount of strain, grains may reach a steady state size of ∼1.5 to 3 mm due to dynamic recrystallization, wherein a steady state grain size is maintained due to the balance of grain growth and destruction during flow. If the near-bed ice in the MPD is warmed close to its melting point and has been extensively sheared, grain sizes at its base may be between 10 and 40 mm, by analogy with warm, dirty, near-bed ice in terrestrial ice sheets.     

Experimental test of a radiative transfer model of the optical effects of space weathering

We compare laboratory measurements of the optical effects of nanophase iron on near-IR reflectance spectra of transparent silica gel infused with small iron particles [Noble, S.K., Pieters, C.M., Keller, L.P., 2007. Icarus 192, 629-642] with a radiative transfer model of the process [Hapke, B., 2001. J. Geophys. Res. 106 (E5), 10039-10074]. We find that the measurements exhibit reddening and darkening effects of nanophase (<50 nm) iron particles, a darkening effect of somewhat larger particles (>50 nm) and mixing effects of silica gel particles of varying total iron abundance. The radiative transfer model reproduces the effects of nanophase iron within the experimental uncertainties.     

Effectiveness of post-fire salvage logging stream buffer management for hillslope erosion in the U.S. Inland Northwest Mountains

Active wildfire seasons in the western U.S. warrant the evaluation of post-fire forest management strategies. Ground-based salvage logging is often used to recover economic loss of burned timber. In unburned forests, ground-based logging often follows best management practices by leaving undisturbed areas near streams called stream buffers. However, the effectiveness of these buffers has not been tested in a post-wildfire setting. This experiment tested buffer width effectiveness with a novel field-simulated rill experiment using sediment-laden runoff (25 g/L) released over 40 min at evenly timed flow rates (50, 100 and 150 L/min) to measure surface runoff travel length and sediment concentration under unburned and high and low soil burn severity conditions at 2-, 10- and 22-month post-fire. High severity areas 2-month post-fire had rill lengths of up to 100 m. Rill length significantly decreased over time as vegetation regrowth provided ground cover. Sediment concentration and sediment dropout rate also varied significantly by soil burn severity. Sediment concentrations were 19 g/L for the highest flow 2-month post-fire and reduced to 6.9–14 g/L 10-month post-fire due to abundant vegetation recovery. The amount of sediment dropping out of the flow consistently increased over the study period with the low burn severity rate of 1.15 g L⁻¹ m⁻¹ approaching the unburned rate of 1.29 g L⁻¹ m⁻¹ by 2-year post-fire. These results suggest that an often-used standard, 15 m buffer, was sufficient to contain surface runoff and reduce sediment concentration on unburned sites, however buffers on high burn severity sites need to be eight times greater (120 m) immediately after wildfire and four times greater (60 m) 1-year post-fire. Low burn severity areas 1-year post-fire may need to be only twice the width of an unburned buffer (30 m), and 2-year post-fire these could return to unburned widths.     

Faecal indicator bacteria in New Zealand freshwater fish: a pilot study

Recent studies have suggested that poikilothermic animals, such as fish, may represent a previously overlooked source of the faecal indicator bacteria (FIB) used for the assessment of water quality. However, quantitative studies of FIB in poikilotherms are scarce. We investigated the presence of FIB in the faeces of five freshwater fish species. E. coli and enterococci were detected in 71 and 76% of faecal samples, respectively. Concentrations were highly variable, with maximum concentrations (2.1?×?10⁴ E. coli and 1.3?×?10⁶ enterococci per gram of faecal material) up to four orders of magnitude higher than present in the water column. FIB were not detected in faecal samples from marine fish. Our findings suggest that FIB ingested from the environment may be capable of replication within the fish gut, making fish a potential source and transport mechanism for FIB in New Zealand freshwaters. This may have implications for water quality monitoring.