极谱法测定海水介质的铜络合容量

采用新极谱技术(1.5次微分)的阳极溶出伏安滴定方法测定天然海水的铜络合容量和条件稳定常数。对测试条件、EDTA回收率和有关问题进行了探讨。青岛近岸水样的九次平行测定表明,铜的表现络合容量为3.01×10~(-7)mol/dm~3,条件稳定常数为7.34×10~7,相对标准偏差分别为9.2％和13.8％。     

波群作用于垂直桩柱的峰力统计性质

研究具有窄谱和Ｗｅｉｂｕｌｌ波高分布的波群对非线性桩柱系统作用力的统计性质。求得了桩桩的波浪峰力的各种特征值及其比值。指出这些数值不仅是阻力一惯性力参数ｂＨ的函数，也随着波群因子而变化。本文模式更具广泛性。文中给出了一系列计算图表，可从理论计算波群作用于桩柱的波浪峰力。     

A Study on Hydroelastic Response of Box-Type Very Large Floating Structures

The application of very large floating structure (VLFS) to the utilization of ocean space and exploitation of ocean resources has become one of the issues of great interest in international ocean engineering field. Owing to the advantage of simplicity in structure and low cost of construction and maintenance, box-type VLFS can be used in the calm water area near the coast as the structure configuration of floating airport. In this paper, a 3D linear hydroelastic theory is used to study the dynamic response of box-type VLFS in sinusoidal regular waves. A beam model and a 3D FEM model are respectively employed to describe the dynamic characteristics of the box-type structure in vacuum. A hydrodynamic model (3D potential theory of flexible body) is applied to investigate the effect of different dry models on the hydroelastic response of box-type structure. Based on the calculation of hydroelastic response in regular waves, the rigid body motion displacement, flexible deflection, and the short term and long     

遥感和GIS支持下的分布式融雪径流过程模拟研究

基于遥感(RS)和地理信息系统(GIS)技术,设计和构建了一个分布式融雪径流模型,整个分布式融雪径流过程的模拟计算基于能量平衡和水量平衡,由分布式栅格融雪过程、分布式栅格产流过程以及分布式栅格汇流过程组成,融雪以及产汇流过程全部基于栅格尺度,全面实现了融雪过程的分布式模拟.分布式栅格融雪过程中对"度日法"加以改进,引入了"单元时段"的概念,从而得到了"度分融雪模型";针对融雪过程中颇为复杂的冻融反复性难题,提出了旨在解释积雪冻融反复性物理机制的"冻融系数"的重要概念,对于准确把握融雪过程的物理机制具有重要意义.同时基于GIS开发了分布式融雪径流模拟系统,为分布式融雪径流模型的运行提供了平台和技术支持,二者均为融雪洪水预警决策支持系统的核心模块部分.基于由MODlS等遥感数据得到的积雪信息、地表温度等下垫面信息,基础地理信息数据如DEM及其空间分析数据和大量野外同步观测数据(积雪信息、气象数据),对典型研究区新疆军塘湖流域2006年春季典型融雪期(2006-03-06,11:00-2006-03-10,11:00)内的洪水过程进行了模拟,模拟结果精度较高,平均精度0.82,达到了融雪洪水预警预报的业务需求标准.     

The distribution and geological significance of carbazole compounds in Silurian paleo-pools of the Tarim Basin,Northwest China

The results presented in this paper indicated that the carbazole-type compounds have high thermal stability and also show stability in oxidation and bio-degradation. This kind of compounds still has high concentrations and a complete distribution in the analyzed dry asphalt samples, showing that they are particularly useful in the study of hydrocarbon migration of the paleo-pools. The difference in the contents of nitrogen compounds in the Silurian dry asphalts from the Awati, Tabei and Tazhong areas is attributed to the difference in the extent of oxidation and （or） bio-degradation for the areas; the Awati and Tabei areas underwent relatively strong oxidation and bio-degradation. During the first stage of hydrocarbon pool formation in the Silurian system in the Tazhong and Tabei areas of the Tarim Basin （at the end of the Silurian period） and at the second stage in the Awati area （in Permian）, the hydrocarbons experienced a long-distance migration.     

Multifractal Analysis of Element Distribution in Skarn-type Deposits in the Shizishan Orefield, Tongling Area, Anhui Province, China

A series of element concentrations sampled from four drill cores with a length about 1000 m into different skarn-type deposits were selected from the Shizishan orefield, central Tongling, southeastern part of Anhui Province. Using the multifractal method, the distribution and migration characteristics of the major and trace elements are analyzed. The multifractal spectrum of the major elements is left-skewed, whereas the spectrum of the trace elements is right-skewed, which shows that in the process of skarn formation, the trace elements were enriched only locally, and major elements transported within a much larger range. The correlation coefficients of the multifractal parameters Aa （width of the multifractal spectrum） of the four drill cores are relatively low, but the correlation coefficients of the multifractal parameters R （spectrum symmetry parameter） and Af are relatively higher, indicating that although the non-homogeneous intensity of the distribution of elements is inconsistent, their spatial accumulation patterns are almost the same during the ore-forming process. The statistics of the mnltifractal parameters of various elements in the different locations show that the ore-forming processes and element migration pattern in the Shizishan orefield are consistent, and that the migrations of trace elements and major elements exhibit some differences.     

基于高分辨率影像城市建筑物研究

建筑物是城市的重要组成部分,近年来城市化进程不断加快,城市人口与城市建筑物日益增多,及时获取建筑物的空间分布以及建筑覆盖率、建筑容积率等相关指标,有利于城市居住环境状况进行科学评价,促进土地利用优化配置,还可为交通与通讯等科学规划提供参考.随着高分辨率影像应用的日益推广以及信息提取技术的不断提高,利用高分辨率卫星影像提取城市建筑物及建筑覆盖率、建筑容积率等指标与传统手段相比具有快速、高效等特点,得到广泛应用并取得丰硕成果.本文在前人研究的基础上,对基于高分辨率城市建筑物提取及相关研究的理论基础、存在问题、发展趋势进行了深入分析,对于高分辨率影像城市建筑物研究系统化、促进城市遥感的深化具有重要意义.     

碳中和目标下关键矿产在清洁能源转型中的作用、供需分析及其建议

在"碳中和"目标的驱动下，全球能源系统向清洁化、低碳化甚至无碳化发展已是大势所趋。针对向清洁能源转型的需求，采用了统计对比、分类汇总、综合分析等方法，分析研究了关键矿产在电池、电网、低碳发电和氢能等行业中的作用和需求。结合当前关键矿产产量的地理集中度高、项目开发周期长、资源质量下降等矿产供应和投资计划不能满足清洁能源转型的需求等问题，提出确保关键矿产多样性供应，推动价值链各环节的技术创新，扩大回收利用，增强供应链弹性和市场透明度，将更高的环境、社会和治理标准纳入主流程及加强生产者和消费者之间的国际合作等建议。     

钻孔灌注桩施工对邻近运营隧道变形影响研究

桩基施工将引起周边地层位移和邻近隧道结构变形,以南京龙津桥改建项目桩基工程为背景,通过现场实测,分析研究钻孔灌注桩施工全过程各工况条件对地层位移场和邻近既有隧道结构变形的影响规律。结果表明:由于钢套管的护壁作用,钻孔灌注桩施工过程中产生的最大地层位移和隧道结构变形较小,说明采用“钢套管边旋压边取土”、“群桩间跳施工”等工艺,对周围土体扰动影响程度较小,建议近隧桩基工程采用全套管灌注桩的施工方法,监测分析结果可为类似工程提供技术参考。     

秦皇岛市矿产开发引发的地质环境问题及对策

秦皇岛市矿产资源丰富,矿业已成为秦皇岛市特别是地方经济的支柱之一。伴随着矿业的发展,在矿产开发过程中引发的地质环境问题日益突出,如采空区地表变形(地面塌陷、地裂缝等)、岩溶塌陷、露天采矿边坡失稳、尾矿引发的泥石流、水土流失以及地貌景观的破坏等。这些地质环境问题主要分布在北部的山区和丘陵台地区。形成的原因复杂,主要有法制不健全、缺乏强制恢复机制、布局不合理、监管不到位、开采技术落后、不合理开采、资金缺乏以及从业者环保意识淡薄等方面的原因。对于矿山地质环境的保护,应采取加强立法、建立保证金制度、统一规划、加强监管、加大宣传力度以及建立责任追究制度等措施。