云南个旧老厂-卡房花岗岩体成因：锆石U-Pb年代学和岩石地球化学约束

在云南个旧地区发育大量与成矿时空密切相关的侵入岩。个旧东区的老厂-卡房花岗质岩体为一隐伏的花岗岩体,侵入于三叠纪个旧组灰岩和碳酸盐地层中,岩性主要为中细粒黑云母花岗岩,是个旧地区与成矿关系最为密切的花岗岩体之一。岩石的ACNK值大多在1.0以上,属于高钾钙碱性系列岩石;U、Th含量较高,应归属于HHP花岗岩;岩石类型属于S型花岗岩,但经历了高度的分异和演化;n(Rb)/n(Sn)- n(Rb)/n(Ba)与n(CaO)/n(Na2O)-n(Al2O3)/n(TiO2)图解均暗示岩石的源区性质为由粘土岩所派生的岩浆。锆石LA-ICP-MS定年结果表明,老厂-卡房岩体形成于85±0.85Ma,相当于晚白垩世。根据区域地质和花岗岩的地球化学特征,暗示个旧地区燕山晚期处于伸展构造背景。     

松科1井南孔选址、岩心剖面特征与特殊岩性层的分布

松科1井南孔是松辽盆地白垩系科学钻探工程两个钻孔中的一个,位于松辽盆地北部中央坳陷区齐家古龙凹陷敖南鼻状构造的翼部。通过对松科1井南孔嫩二段底部到泉三段顶部连续取心资料的详细描述,建立松科1井南孔岩心剖面,识别出5种常见岩性(泥岩、粉砂质泥岩、泥质粉砂岩、粉砂岩和细砂岩)和8种特殊岩性(白云岩、火山灰、油页岩、灰质泥岩、泥灰岩、重结晶灰岩、介形虫碎屑灰岩和介形虫灰岩)。特殊岩性出现的总层数为172层,总厚度为14.516m,分布在青一段,青二、三段,姚二、三段,嫩一段和嫩二段地层中。对松科1井的精细岩心描述和对特殊岩性的识别是后续研究工作开展的基础。     

Impact of land use covers upon karst processes in a typical Fengcong depression system of Nongla, Guangxi, China

The direction and intensity of karst processes can be deeply affected by soil physical and chemical variations which were resulted from land use. Taking Nongla Fengcong depression area, Mashan County, Guangxi as an example, authors discussed the impact of land use on karst processes based on the data of field limestone tablet. The results showed that the corrosional rates at varied soil depth are quite different. Corrosional rate in woodland and orchard is mostly bigger than 20 mg/a, which is much higher than that in tilled land and shrub. Generally, corrosional rate decreased from orchard, woodland, tilled land, fallow land and shrub successively, in which soil organic matter (OM) and soil pH are two major controlling factors: corrosion process is controlled remarkably by soil OM in woodland and orchard. The higher the organic matter content is and the less the pH value is, the higher the corrosional rate is. Owing to lower organic matter content, the corrosional rate is mainly affected by soil CO₂ in tilled land and shrub.     

Dissolved trace elements and heavy metals in the Danjiangkou Reservoir,China

Concentrations of trace elements and heavy metals (Al, As, Ba, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sb, Se, Sr, V and Zn) in the Danjiangkou Reservoir, the water source area of the Middle Route of China’s interbasin South to North Water Transfer Project, were analyzed using an Inductively Coupled Plasma Atomic Emission Spectrometer (ICP-AES) and compared with the national and international standards for drinking water. The results indicated that concentrations of As, Pb, Sb and Se in the Reservoir exceeded the standards and they would pose health risk for residents in the region and the water receiving areas of the interbasin water transfer project. Spatial and temporal variability of the trace elements and heavy metals in the Reservoir implies their mixed sources of natural processing and anthropogenic activities in the upper drainage of the Reservoir. The research results would help develop water resource management and conservation strategy for the interbasin water transfer project.     

Comparison of arsenic concentrations in simultaneously-collected groundwater and aquifer particles from Bangladesh,India, Vietnam,and Nepal

One of the reasons the processes resulting in As release to groundwater in southern Asia remain poorly understood is the high degree of spatial variability of physical and chemical properties in shallow aquifers. In an attempt to overcome this difficulty, a simple device that collects groundwater and sediment as a slurry from precisely the same interval was developed in Bangladesh. Recently published results from Bangladesh and India relying on the needle-sampler are augmented here with new data from 37 intervals of grey aquifer material of likely Holocene age in Vietnam and Nepal. A total of 145 samples of filtered groundwater ranging in depth from 3 to 36 m that were analyzed for As (1–1000 μg/L), Fe (0.01–40 mg/L), Mn (0.2–4 mg/L) and S (0.04–14 mg/L) are compared. The P-extractable (0.01–36 mg/kg) and HCl-extractable As (0.04–36 mg/kg) content of the particulate phase was determined in the same suite of samples, in addition to Fe(II)/Fe ratios (0.2–1.0) in the acid-leachable fraction of the particulate phase. Needle-sampler data from Bangladesh indicated a relationship between dissolved As in groundwater and P-extractable As in the particulate phase that was interpreted as an indication of adsorptive equilibrium, under sufficiently reducing conditions, across 3 orders of magnitude in concentrations according to a distribution coefficient of 4 mL/g. The more recent observations from India, Vietnam and Nepal show groundwater As concentrations that are often an order of magnitude lower at a given level of P-extractable As compared to Bangladesh, even if only the subset of particularly reducing intervals characterized by leachable Fe(II)/Fe >0.5 and dissolved Fe >0.2 mg/L are considered. Without attempting to explain why As appears to be particularly mobile in reducing aquifers of Bangladesh compared to the other regions, the consequences of increasing the distribution coefficient for As between the particulate and dissolved phase to 40 mL/g for the flushing of shallow aquifers of their initial As content are explored.     

CO2地质埋存渗漏风险及补救对策

目前,将CO2埋存于地下深部地质构造（如油气藏、煤层、地下含水层及岩溶盐腔）的减排方案能有效地减缓温室效应而备受关注。无论什么储集体,我们都希望CO2在地下埋存的时间越长越好。然而,对于一项具体工程的实施,必然存在一些客观和主观因素造成CO2渗漏,比如废弃井的不完善或不合理处理、地层断裂系统和水动力系统以及地震所造成的渗漏等等。存在渗漏就可能会对周围人和生态环境造成危害。因此,进行CO2地质埋存的风险评估是相当有必要的,是我们能长期有效安全地进行该项减排方案必不可少的基础和保证。本文即想从建立一套完整的风险评估、管理和监测体系的角度并以加拿大Weyburn油田为例,深入分析CO2地质埋存中可能存在的渗漏风险和途径,建立CO2渗漏风险评估机制,并针对具体的渗漏可能性提出相应的补救对策,为全球范围内,尤其对我国刚刚开展CO2地质埋存研究工作提供一些有益的思路。     

渤海湾盆地新生界生油岩系底界面温度分布

依据渤海湾盆地2000余口测温井的地温梯度数据、地层岩性描述、分层数据以及钻井资料,计算了该盆地各生油岩系底界面的温度。统计结果表明:渤海湾盆地沙河街组大部分凹陷区地层底界面温度介于90℃至150℃,目前仍具有大量生油的温度条件,而在隆起或一些凸起地区,该地层组段温度普遍小于90℃,未能达到生油的温度指标。东营组和孔店组地层也仍具有一定的生油温度条件。研究还表明:地层温度与地层界面埋深密切相关,温度随界面埋深的增大而升高,沉积厚度大的凹陷区地层界面温度大于沉积厚度小的凸起区或斜坡地带,说明地层界面埋深是决定地温高低的主要控制因素,而地温梯度对地层界面温度的影响相对较小。     

松南海坨子—大布苏地区泉四段— 姚家组层序地层研究

根据工区内现有的钻井、测井和地震资料,应用以多级次基准面旋回为参照面的高分辨层序地层学理论与研究方法,对松辽盆地南部海坨子—大布苏地区的泉四段—姚家组地层进行了详细的层序地层研究,共识别出5个长期基准面旋回（相当于三级层序）,9个中期基准面旋回（相当于四级层序）,建立了研究区的层序划分方案,在连井剖面的层序地层对比基础上,建立了该区的地层格架,并对层序构成特征进行了分析,研究了储集层在层序格架内的分布规律,揭示出浊积砂体和三角洲前缘相的分流河道形成于基准面上升期,三角洲前缘相的河口坝、远砂坝和席状砂沉积形成于基准面下降期,指出浊积砂体和三角洲前缘相的远砂坝、席状砂沉积是研究区形成岩性油气藏的有利储集体。     

中祁连东段什川杂岩基的岩石化学特征及年代学研究

祁连造山带被托菜南山-了高山构造带及宗务隆山-贵得构造带分为北祁连、中祁连及南祁连构造带。什川岩基位于中祁连构造带东部,由闪长岩、斜长花岗岩、二长花岗岩组成;对二长花岗岩进行U-Pb单颗粒锆石微区LA-ICP-MS同位素测定,获得444.6Ma及414.3Ma两组加权平均年龄,前者代表岩石的形成年龄,后者代表构造热事件年龄。二长花岗岩主量元素W(SiO_2)=68.66%～80.77%,w(K_2O)/w(Na_2O)>1和A/CNK介于0.95～1.21间,总体为钾质钙碱性过铝质花岗岩。岩石富集LILE元素(K、Th、Rb、Ba等),亏损HFSE元素(Ta、Nb、Y等);稀土元素总量较高(∑REE多介于109.05×10~(-6)～322.66×10~(-6)),轻重稀土强烈分馏(∑LREE/∑HREE介于7.92～31.68),稀土元素分配模式为轻稀土富集型,具中等-强Eu负异常(δEu=0.26～0.58)。岩石矿物组合及岩石地球化学特征共同表明,什川岩基为中上地壳泥砂质岩石部分熔融而成,形成温度较低,为加厚地壳拆沉熔融成因。这为祁连造山带构造演化及其深部动力学机制研究提供了新的资料。     

潮湿环境下古代土遗址的原位保护加固研究

古遗址的保护是文物保护工作中最复杂的问题之一,而土质文物是文物保护中最难保护的文物,所以古代土遗址的保护已在国际上被列为专门的保护项目,而处于潮湿环境下的古代土遗址保护的课题在文化遗产实物和遗迹就地保存和展示领域就更为迫切。浙江良渚文化是中国新石器时代长江流域最重要的史前文化, 塘山遗址位于良渚文化遗址的西北部,选择了PS（硅酸钾）、WD－10（十二烷基三甲氧基硅烷）、WD－S（低聚甲氧基硅烷）、RTV（聚有机硅氧烷+硅酸乙酯）4种保护材料对塘山遗址进行了保护加固实验研究。室内实验和现场实验（2个月,6个月,9个月）的结果都表明,RTV和WD-10防水性优于WD-S,WD-10和WD-S材料仅能作为防水材料,PS材料仅能作为加固材料使用,而RTV则具有较好的加固和防水效果,且加样量越大,强度提高越多。