Sequential Chemical Separation of Cr and Ti from a Single Digest for High‐Precision Isotope Measurements of Planetary Materials

Combined determination of Cr and Ti isotopes of planetary materials offers a means with which to investigate their genetic relationship and the evolution of the protoplanetary disk. Here, we report the new sequential chemical separation procedure for combined Cr and Ti isotope ratio measurements. It comprises three steps: (a) Fe removal using AG1‐X8 anion exchange resin, (b) Ti separation using TODGA resin and (c) Cr separation using AG50W‐X8 cation exchange resin (with one additional step of Ti purification using AG1‐X8 anion exchange resin for samples having high Cr/Ti and Ca/Ti ratios). We applied the proposed procedure to terrestrial and meteorite samples with various compositions. Typical recovery rates of 90–100% were achieved with total procedural Cr and Ti blanks of 3–5 and 2–3 ng, respectively. We measured the Cr and Ti isotope compositions of the separated samples using thermal ionisation mass spectrometry and multiple collector‐inductively coupled plasma‐mass spectrometry, respectively. Our Cr and Ti isotope data were found to be consistent with those of previous studies of individual Cr and Ti isotopic compositions of the meteorites. These results demonstrate the capability of our separation method when applied to combined high‐precision Cr and Ti isotope analyses for single digests of planetary materials.     

Observation of far ultraviolet radiation from early-type stars

Rocket-borne photon counters sensitive to bands 1060–1180, 1230–1350, and 1350–1480 were used to measure the celestial ultraviolet radiation above the terrestrial atmosphere. The energy spectra of six objects, Leo, CMa, Ori, , , Ori (combined), Ori, and Tau were obtained. The comparison of them with those calculated with the stellar model atmospheres indicates the deficiency of about 1 mag. in the ultraviolet region, when corrected for interstellar extinction, for all stars except Tau. The observed spectrum of Tau agreed with the theoretical one for normal interstellar extinction. The effects of line blanketing were examined for B1 and B2 stars, and found to account for a part of the difference between the observed and the theoretical values.     

The paradox of smooth and abrupt bends in two-dimensional in-plane shear-crack mechanics

It is pointed out, in the context of the boundary integral equation method (BIEM), that, in the mechanics of 2-D curved in-plane shear cracks, a smooth curve, along which the crack orientation changes continuously, and an abrupt kink, across which it changes discontinuously, are not equivalent to each other. The discrepancy is illustrated by numerical results, and a set of conceptual models is used to demonstrate analytically how the equations that govern the crack mechanics have inherently distinct forms depending on whether the crack orientation changes continuously or abruptly across a bend, as long as one abides by the principles of linear elasticity theory. This has serious implications for the numerical treatment of a curved crack, which can be modelled as a chain of finite elements that are connected either smoothly or at abrupt kinks, the two methods producing different numerical outcomes. No similar paradox arises in the cases of anti-plane shear or open in-plane cracks.     

Expansion of the Nishinomiya Built Environment Database

The Nishinomiya Built Environment Database, which can be used to analyze the disaster process of the 1995 Hanshin-Awaji Earthquake Disaster in Nishinomiya City, has been expanded with new data entries. The database contains the following very detailed datasets: (1) the urbanization area base map, (2) casualty data, (3) three sets of building damage data surveyed by the Nishinomiya City, the Architectural Institute of Japan and the City Planning Institute of Japan, and the Kobe University, (4) building property data based on the real estate tax roll, (5) photographs of the damaged buildings with the information on the place and orientation of the picture, and (6) the estimated distribution of the seismic ground motion. The seismic ground motion was simulated for the southern part of Nishinomiya City and two verification sites in Kobe City and Amagasaki City. In the simulation, the borehole data of public facilities were used to model the surface soils as one-dimensional layers, taking into consideration the fact that the spatial distribution of the sediment/basement interface forms a slope. The model of the fault rupture process simulated the characteristics of the seismic motion at basement level, and amplification effects of the surface layers were evaluated based on multiple reflection theory. The distribution of peak ground acceleration and peak ground velocity was estimated from acceleration response spectra at each borehole point. In addition, the relationship between simulated seismic ground motion and building damage was studied based on newly proposed band-passed spectrum intensity using the expanded database. This confirmed that detailed categorization is necessary in order to evaluate the fragility functions, especially for reinforced concrete structures. The database should provide fundamental information for identifying the relationship between the ground motions and the extent and pattern of building damage, or the pattern of the occurrence of casualties.Presently     

Fine structure in photoluminescence spectrum of S<Subscript>2</Subscript><Superscript>−</Superscript> center in sodalite

The photoluminescence and excitation spectra of sodalites from Greenland, Canada and Xinjiang (China) are observed at 300 and 10 K in detail. The features of the emission and excitation spectra of the orange-yellow fluorescence of these sodalites are independent of the locality. The emission spectra at 300 and 10 K consist of a broad band with a series of peaks and a maximum peak at 648 and 645.9 nm, respectively. The excitation spectra obtained by monitoring the orange-yellow fluorescence at 300 and 10 K consist of a main band with a peak at 392 nm. The luminescence efficiency of the heat-treated sodalite from Xinjiang is about seven times as high as that of untreated natural sodalite. The emission spectrum of the S₂ ⁻ center in sodalite at 10 K consists of a band with a clearly resolved structure with a series of maxima spaced about 560 cm⁻¹ (20–25 nm) apart. Each narrow band at 10 K shows a fine structure consisting of a small peak due to the stretching vibration of the isotopic species of ³²S³⁴S⁻, a main peak due to that of the isotopic species of ³²S₂ ⁻ and five peaks due to phonon sidebands of the main peak.     

On the importance of accurately ray-traced troposphere corrections for Interferometric SAR data

Numerical weather models offer the possibility to compute corrections for a variety of space geodetic applications, including remote sensing techniques like interferometric SAR. Due to the computational complexity, exact ray-tracing is avoided in many cases and mapping approaches are applied to transform vertically integrated delay corrections into slant direction. Such an approach works well as long as lateral atmospheric gradients are small enough to be neglected. But since such an approximation holds only for very rare cases it is investigated how horizontal gradients of different atmospheric constituents can evoke errors caused by the mapping strategy. Moreover, it is discussed how sudden changes of wet refractivity can easily lead to millimeter order biases when simplified methods are applied instead of ray-tracing. By an example, based on real InSAR data, the differences of the various troposphere correction schemes are evaluated and it is shown how the interpretation of the geophysical signals can be affected. In addition, it is studied to which extend troposphere noise can be reduced by applying the exact ray-tracing solution.     

Pore Creation due to Fault Slip in a Fluid-permeated Fault Zone and its Effect on Seismicity: Generation Mechanism of Earthquake Swarm

—Spatio-temporal variation of rupture activity is modeled assuming fluid migration in a narrow porous fault zone formed along a vertical strike-slip fault in a semi-infinite elastic medium. Pores are assumed to be created in the fault zone by fault slip. The effective stress principle coupled to the Coulomb failure criterion introduces mechanical coupling between fault slip and pore fluid. The fluid is assumed to flow out of a localized high-pressure fluid compartment in the fault with the onset of earthquake rupture. The duration of the earthquake sequence is assumed to be considerably shorter than the recurrence period of characteristic events on the fault. The rupture process is shown to be significantly dependent on the rate of pore creation. If the rate is large enough, a foreshock–mainshock sequence is never observed. When an inhomogeneity is introduced in the spatial distribution of permeability, high complexity is observed in the spatio-temporal variation of rupture activity. For example, frequency-magnitude statistics of intermediate-size events are shown to obey the Gutenberg–Richter relation. Rupture sequences with features of earthquake swarms can be simulated when the rate of pore creation is relatively large. Such sequences generally start and end gradually with no single event dominating in the sequence. In addition, the b values are shown to be unusually large. These are consistent with seismological observations on earthquake swarms.