An invariance in the carbazoles of petroleum

A remarkable invariance in the ratio of 1,3-dimethylcarbazole （DMC） to 1,6-DMC was discovered in crude oils from the Pearl River Mouth Basin, South China Sea. The remarkably invariant ratio is kept at a constant of about unity regardless of their concentrations, sources or maturities for the sampies. In combination with the molecular structures of 1,3- and 1,6-DMCs, the invariance might indicate that the nitrogen compounds share a common precursor with a skeleton of 1-methylcarbazole and are formed through methylation at C3 and C6 with an essentially identical rate.     

Geochemical and Sr-Nd isotopic study of alkaline syenites in Liangtun-Kuangdonggou, Liaoning Province, China： Evidence for enriched mantle before 1.86 Ga and implications

The 1.86 Ga Liangtun-Kuangdonggou complex (LKC) is one of the oldest alkaline syenite bodies so far discovered in China. This syenite suite has elevated contents of total alkali (K2O Na2O), with an average of 10.50%, and a mean Rittmann Index (σ) of 6.48. The intrusions have slightly higher concentrations of K2O than those of Na2O on a weight percent basis, indicating the rocks belong to potassium-rich alkaline syenite series. Total rare-earth element concentrations (∑REE ) of the rocks are relatively high, ranging from 324×10 -6 to 1314×10 -6, with a mean value of 666×10 -6. The REE patterns are subparallel and rightward steep with (La/Yb)N >33, showing mild negative to positive Eu anomalies (δEu: 0.63-1.15). All samples exhibit strong LILE and LREE enrichments and TNT (Nb, Ta, Ti) and P depletions in multi-element spidergrams. On the εSr(t)-εNd(t) correlation diagram, most analytical data points plot within the enriched mantle field with low ( 87Sr/86Sr)i ratios (0.7045-0.7051) and negative εNd(t) values (-3.72--3.97), falling among those kimberlites from Fuxian County, Liaoning Provinve, from Mengyin County, Shandong Province and the Ⅱ-type kimberlites from South Africa. These characteristics imply that the LKC-rocks may have the same source as the above-mentioned kimberlites, i.e., they have close connections to the materials derived from enriched mantle reservoirs, further revealing that the upper mantle beneath the northeastern part of the North China Plate had been highly enriched before 1.86 Ga. Geodynamically, the LKC-rocks were formed in a within-plate environment with close genetic connections to rift-related alkaline magma activities possibly controlled by ancient mantle plumes.     

地理新课程教师培训模式初探

地理新课程改革是基础教育课程改革的重要内容之一.随着地理课程的全方位变革,新教师培训也是一个不容忽视的问题.地理新课程教师培训模式从不同的方面划分有不同的类型,每种模式既有优越性,也有局限性.要更好地推进地理新课程改革,必须对地理新课程教师培训模式进行不断的修正、补充和完善.     

Impacts of land use changes on groundwater resources in the Heihe River Basin

Land use and land cover changes have a great impact on the regional hydrological process. Based on three periods of remote sensing data from the 1960s and the long-term observed data of groundwater from the 1980s, the impacts of land use changes on the groundwater system in the middle reach of Heihe River Basin in recent three decades are analyzed by the perspective of groundwater recharge and discharge system. The results indicate that with the different intensities of land use changes, the impacts on the groundwater recharge were 2.602×108 m3/a in the former 15 years (1969-1985) and 0.218×108 m3/a in the latter 15 years (1986-2000), and the impacts on the groundwater discharge were 2.035×108 m3/a and 4.91×108 m3/a respectively. When the groundwater exploitation was in a reasonable range less than 3.0×108 m3/a, the land use changes could control the changes of regional groundwater resources. Influenced by the land use changes and the large-scale exploitation in the recent decade, the groundwater resources present apparently regional differences in Zhangye region. Realizing the impact of land use changes on groundwater system and the characteristics of spatial-temporal variations of regional groundwater resources would be very important for reasonably utilizing and managing water and soil resources.     

Gas accumulation from oil cracking in the eastern Tarim Basin: A case study of the YN2 gas field

Oil and gas exploration in eastern Tarim Basin, NW China has been successful in recent years, with several commercial gas accumulations being discovered in a thermally mature to over-mature region. The Yingnan2 (YN2) gas field, situated in the Yingnan structure of the Yingjisu Depression, produces gases that are relatively enriched in nitrogen and C₂₊ alkanes. The δ¹³C₁ (−38.6‰ to −36.2‰) and δ¹³C₂ values (−30.9‰ to −34.7‰) of these gases are characteristic of marine sourced gases with relatively high maturity levels. The distributions of biomarkers in the associated condensates suggest close affinities with the Cambrian–Lower Ordovician source rocks which, in the Yingjisu Sag, are currently over-mature (with 3–4%Ro). Burial and thermal maturity modeling results indicate that paleo-temperatures of the Cambrian–Lower Ordovician source rocks had increased from 90 to 210 °C during the late Caledonian orogeny (458–438 Ma), due to rapid subsidence and sediment loading. By the end of Ordovician, hydrocarbon potential in these source rocks had been largely exhausted. The homogenization temperatures of hydrocarbon fluid inclusions identified from the Jurassic reservoirs of the YN2 gas field suggest a hydrocarbon emplacement time as recent as about 10 Ma, when the maturity levels of Middle–Lower Jurassic source rocks in the study area were too low (<0.7%Ro) to form a large quantity of oil and gas. The presence of abundant diamondoid hydrocarbons in the associated condensates and the relatively heavy isotopic values of the oils indicate that the gases were derived from thermal cracking of early-formed oils. Estimation from the stable carbon isotope ratios of gaseous alkanes suggests that the gases may have been formed at temperatures well above 190 °C. Thus, the oil and gas accumulation history in the study area can be reconstructed as follows: (1) during the late Caledonian orogeny, the Cambrian–Lower Ordovician marine source rocks had gone through the peak oil, wet gas and dry gas generation stages, with the generated oil and gas migrating upwards along faults and fractures to form early oil and gas accumulations in the Middle–Upper Ordovician and Silurian sandstone reservoirs; (2) since the late Yanshanian orogeny, the early oil accumulations have been buried deeper and oil has undergone thermal cracking to form gas; (3) during the late Himalayan orogeny, the seals for the deep reservoirs were breached; and the gas and condensates migrated upward and eventually accumulating in the relatively shallow Jurassic reservoirs.     

桂林地区古人类演化及环境变迁研分

桂林地区曾是古人类活动活跃的地区，据可以断代的古人类洞穴遗址统计，发现桂北地区大部分的洞穴遗址其年代的下限都在距今约7000a 左右，此后古人类离开了洞穴，史前文化也随之发生了重要改变。影响古人类演化的因素鹅很多，究竟是什么原因驱使古人类离开洞穴，改变生活习性，这一问题一直都是困扰考古学界的难题。本文通赤研究桂北地区洞穴遗址的堆积特点，结合洞穴沉积－堆积物的特征及其孢粉记录的古气候信息，探讨了季风气候变化对桂林地区古气候变化的影响作用和气候演变历史，揭示了桂林地区全新世以来的季风气候变化时间序列和突变事件以及对古人类生存环境的影响。距今7000a 左右为中全新世气候适宜期，东亚夏季风强盛，气温升高，桂林地区的降雨增多，一方面由于地下河水位升高，淹没了穴居洞穴，其次是由于降雨增多，导致洞穴湿度增大，从而迫使古人类搬出洞穴。     

含钒金红石可见光下催化降解亚甲基蓝实验研究

利用含有钒等杂质的金红石可部分吸收可见光的特性,以500 W卤素灯作为光源,实验研究了其对亚甲基蓝的可见光催化降解,结果表明,该金红石具有催化活性,7 h后亚甲基蓝可降解71 2%。经过加热、粉碎改性方法处理后的金红石光催化活性明显提高,加热1 100 ℃的金红石样品7 h后可使亚甲基蓝的降解率达到90 4%。增加光照强度、加入适当的H2O2 都可提高降解效果。实验为充分开发利用天然金红石提出了新的途径,为环境污染治理提出了新方法。     

微生物技术在地质找矿和矿石冶炼中的应用现状及展望

评述了微生物技术在地质找矿和矿石冶炼中的研究和应用现状,并结合现代分子生物学的研究进展,着重对核苷酸序列分析、基因探针、DNA重组技术等有望在地质学中进一步应用的分子生物学技术进行了论述,展望了利用微生物的分子鉴定技术和基因探针技术寻找隐伏矿床、利用原生质体融合技术和基因工程创建高效工程菌用于矿石冶炼等方面的应用前景.     

桩基筒形翼状钻头的改进设计及应用

针对浙江省温州市世贸中心大厦桩基施工中硬岩钻进时出现的堵管、卡钻和效率低等问题,从所钻地层和钻头的磨损分析出发,提出了钻头的改进设计方案.改进型筒形翼状钻头比原先使用的平底滚刀钻头增加了18个孕镶金刚石-针状硬质合金复合式钻齿和3个钎头,并按受力特点进行了合理分布.实际钻进效果表明改进型钻头应用于超深、大直径钻孔的钻进效率较高、钻进过程平稳.针对钻头的实际磨损情况提出了钻头进一步改进设计的建议.