胶东望儿山金矿床氢-氧同位素地球化学

胶东金成矿省位于华北克拉通东南缘,是我国最重要的黄金集区,约占全国黄金储量的25%。其中约90%的金资源量集中于胶东半岛的西北部,主要受3个一级断裂带(三山岛断裂带、焦家断裂带和招平断裂带)控制。望儿山金矿床赋存于晚侏罗世玲珑型黑云母花岗岩中,受焦家断裂带的次级断裂带(望儿山断裂带)控制,是胶东地区受二级断裂带控制的已探明规模最大的金矿床,同时发育蚀变岩型矿化和石英脉型矿化。金矿化与硅化和绢云母化蚀变密切相关,矿体多呈脉状,主要为矿区内主干断裂F1和F5控制的1号和5号矿体以及F1和F5的次级断裂控制的3号和23号矿体。矿石分为蚀变岩型和石英脉型,主要由石英、绢云母及黄铁矿、黄铜矿、方铅矿、闪锌矿等金属硫化物等组成。本研究通过详细的野外和岩相学、矿相学观察,依据蚀变特征、脉体穿插关系及矿石结构构造和矿物共生组合,将成矿过程分为四个阶段:黄铁矿-石英-绢云母阶段(Ⅰ)、石英-黄铁矿阶段(Ⅱ)、石英-多金属硫化物阶段(Ⅲ)和石英-碳酸盐阶段(Ⅳ)。针对不同高程、不同成矿阶段、不同矿石类型、不同矿体,系统采集了26件样品,分别挑选石英单矿物进行氢、氧同位素测试,总体δD值分布于-77.3‰~-54.2‰,δ18O值分布于-5.56‰~7.20‰,Ⅰ阶段δD=(-62.2±6.6)‰(n=8),δ18O=(4.60±1.52)‰(n=8);Ⅱ阶段δD=(-62.5±4.5)‰(n=7),δ18O=(0.47±2.86)‰(n=7);Ⅲ阶段δD=(-66.5±3.9)‰(n=8),δ18O=(-0.44±2.21)‰(n=8);Ⅳ阶段δD=(-65.6±4.5)‰(n=3),δ18O=(-4.43±1.09)‰(n=3)。根据氢-氧同位素组成及流体混合作用图解和水-岩交换氢氧同位素演化曲线,得出变质水与大气降水的混合流体与成矿相关。成矿流体来源主要为胶东群变质水,随着成矿作用的进行,更多大气降水混入成矿流体,成矿Ⅲ、Ⅳ阶段流体很可能以大气降水为主。成矿流体依据其流动方式主要分为渗透式流动和隧道式流动两种,蚀变岩型矿石的氧同位素组成较为集中,表明渗透式流动很可能是形成蚀变岩型矿石的成矿流体的主要流动方式;石英脉型矿石的δ18O值分布范围较大并小于或等于蚀变岩型矿石的δ18O值,表现出成矿流体的隧道式流动特征。在垂向上δD值表现出由深部到浅部总体降低的趋势,可能是在流体沸腾过程中发生了动力学分馏。横向上δ18O值的变化与已探明的矿体规模之间具有明显的负相关关系,很可能表明F1和F5断裂是具有低δ18O值大气降水下渗的主要通道,混合后的成矿流体沿F1和F5断裂运移的同时向其两侧的次级断裂流动。成矿流体与玲珑黑云母花岗岩不断发生水-岩交换作用,并发生减压沸腾作用,可能是导致望儿山金矿床同位素梯度变化及巨量金沉淀成矿的最主要原因。     

芦山地震同震和震后地表形变及重力变化的理论模拟

为了研究芦山地震的孕震过程和震源区的长期构造过程以及解释实测的震后形变和重力资料, 采用分层介质模型, 利用数值模拟的方法, 考虑区域流变系数, 计算了地震引起的地表同震、震后的形变和重力变化以及区域内部分GPS与重力连续观测台站的震后形变和重力变化的时间序列.结果表明: 芦山地震的地表同震形变显示出发震断层明显的逆冲特性; 粘弹性松弛效应引起的震后地表形变和重力变化比同震形变和重力变化的范围明显扩大, 但随着粘滞系数的增加, 变化量明显减小; 观测台站的震后变化时变曲线显示震后形变和重力变化在震后50 a间变化显著, 100 a后基本平缓, 趋于稳定; 模拟计算的GPS台站中除了MEIG台和MYAN台以外, 其余台站的震后观测必须考虑粘弹性松弛的影响.      

新疆阿合奇地区晚石炭世-早二叠世筵类动物群

在塔里木盆地西北缘的阿合奇地区晚石炭世-早二叠世地层中发现大量的筵类化石,共计18属61种,另有较多未定种,自下而上建立了4个筵带,依次为Pseudostaffella带、Profusulinella带、Fusulinella—Fusulina带和Pseudoschwagerma带。各篷带与华南、帕米尔达尔瓦兹等地能很好的对比,且筵类动物群面貌与华南地区相似。根据筵类化石确定别根他乌组为晚石炭世早中期罗苏期-达拉期,康克林组为晚石炭世晚期小独山期一早二叠世紫松期,将该区石炭系、二叠系的界线置于71层底部。石炭纪末期区域上海退和古地形的影响导致筵带Triticites带的缺失。     

阿尔泰南缘可可托海地区二厂房岩体LA-ICP-MS锆石U-Pb年代学、岩石成因及其地质意义

对出露于阿尔泰造山带南缘可可托海地区二厂房岩体中的黑云母花岗闪长岩进行了LA-ICP-MS锆石U-Pb定年和岩石地球化学分析。结果显示,锆石的²⁰⁶Pb/²³⁸U年龄加权平均值为398.0±3.5 Ma（MSWD=1.3）,表明该岩体形成于早中泥盆世。岩体的SiO₂含量介于65.40%～69.31%之间,里特曼指数值为1.27～1.65,A/CNK值为0.92～1.02,属中钾、钙碱性、准铝质岩石。具有富集Cs、Rb、Th、U等大离子亲石元素和轻稀土元素,相对亏损重稀土元素和Nb、Ta、Zr、Hf等高场强元素,负Eu异常明显（δEu=0.48～0.65）的岛弧岩浆岩特征。结合区域地质资料,认为二厂房岩体形成于陆缘弧构造环境,是在古亚洲洋俯冲过程中,幔源的基性岩浆底侵下地壳后使之熔融并发生了岩浆混合作用的产物。     

叠覆式三角洲——一种特殊的浅水三角洲

不同于常规三角洲以分流河道体系所形成的分流河道、河口坝、席状砂等微相为三角洲朵体的基本单元,叠覆式三角洲以内部结构简单的朵体为基本构成单元,朵体相互叠置,形成复合叠合体,进而构成三角洲骨架。单个朵体由河道扫描或扩展而成,复合朵体则是由单朵体侧向迁移或前(退)积而成。三角洲因大量朵体叠置而形成厚层状、内部结构复杂的复合砂体。不同朵体形成于不同时期,因而不存在统一的分流体系,单一沉积体具有层状特征,但不同期朵体受可容空间和地貌控制,呈三维叠置,而非简单的层状叠加,从而使得三角洲内部呈现出拼合式、立体式特点。单朵体是结构的基本单元,发育范围有限,与相邻朵体发育于不同时间单元,因而只能在复合体约束下小范围追踪。单一朵体接触关系及接触界面的渗流能力决定了油气富集和注水开发响应特征。朵体迁移、叠置造成大面积、巨厚的砂层可形成大型油气藏,而同时朵体间泥岩的不均匀分布也造就了砂体局部不连通或朵体间连通性变化,为岩性油气藏形成创造了条件,并且影响了注水开发中的注采对应性,进而影响水驱采油效果。     

扬子克拉通东南缘新元古代陆缘弧型TTG的厘定及其构造意义

在扬子克拉通东南缘的江山-绍兴结合带沿线多处出露新元古代深成杂岩,以往被认为是沿扬子克拉通和华夏地块碰撞缝合带侵入的板内型深成岩类。本文选择其中的浙江金华罗店中酸性深成杂岩进行了系统的岩石学、年代学和地球化学研究,提出它们属TTG岩石组合,包括英云闪长岩-奥长花岗岩-花岗闪长岩组合(T1T2G1)和二长花岗岩-花岗岩组合(G2QM)两类,普遍以明显富集Rb、Ba、K、Pb等大离子亲石元素而强烈亏损Nb、Ta、Ti、P等高场强元素为特征,δCe为弱负异常或无异常,属典型的弧岩浆岩类。T1T2G1组合富钠贫钾,εNd(t)值=+2.6~+9.4,Mg#值为41.5~63.1,推断由玄武质俯冲板片脱水部分熔融而成,并受到地幔楔橄榄岩熔体的混染。G2QM组合与T1T2G1组合地球化学特征类似,但又明显富K2O(2.75%~5.08%)、LILE和LREE,低Mg#值(27.2~52.31)和εNd(t)值(+1.7~+2.0),应是T1T2G1源区继续部分熔融的产物,可能未受到明显的地幔楔橄榄岩混染。测得花岗闪长岩(G1)锆石SHRIMP U-Pb年龄为841±10Ma,奥长花岗岩(T2)锆石LA-ICPMS U-Pb年龄为793±13Ma,前人报道之花岗岩(G2)年龄为832±44Ma,结合上述地球化学特征,说明T1T2G1和G2QM组合是由新元古代古华南洋向扬子东南缘持续俯冲形成的。综合区域地质资料及前人研究结果,提出金华罗店与诸暨璜山、绍兴平水等地的深成杂岩共同构成了扬子克拉通东南缘一条长达200km的青白口纪(930~793Ma)陆缘弧型深成杂岩带,反映迟至793Ma前仍存在强烈的洋壳俯冲,扬子克拉通尚未与华夏地块发生碰撞拼合,且T1T2G1-G2QM组合的出现指示洋壳俯冲正处于早-中期阶段。     

Geochemical features and origin of natural gas in heavy oil area of the Western Slope,Songliao Basin,China

The Western Slope of the Songliao Basin is rich in heavy oil resources (>70 × 10⁸ bbl), around which there are shallow gas reservoirs (∼1.0 × 10¹² m³). The gas is dominated by methane with a dryness over 0.99, and the non-hydrocarbon component being overwelmingly nitrogen. Carbon isotope composition of methane and its homologs is depleted in ¹³C, with δ¹³C₁ values being in the range of −55‰ to −75‰, δ¹³C₂ being in the range of −40‰ to −53‰ and δ¹³C₃ being in the range of −30‰ to −42‰, respectively. These values differ significantly from those solution gases source in the Daqing oilfield. This study concludes that heavy oils along the Western Slope were derived from mature source rocks in the Qijia-Gulong Depression, that were biodegraded. The low reservoir temperature (30–50 °C) and low salinity of formation water with neutral to alkaline pH (NaHCO₃) appeared ideal for microbial activity and thus biodegradation. Natural gas along the Western Slope appears mainly to have originated from biodegradation and the formation of heavy oil. This origin is suggested by the heavy δ¹³C of CO₂ (−18.78‰ to 0.95‰) which suggests that the methane was produced via fermentation as the terminal decomposition stage of the oil.     

Genesis study of high abundant 17a（H）-diahopanes in Lower Cretaceous lacustrine source rocks of the Lishu Fault Depression,Songliao Basin,Northeast China

Relatively abundant 17α（H）-diahopanes have been detected in the lower cretaceous lacustrine source rocks from the Lishu Fault Depression in the Songliao Basin Northeast China. Rich long chain tricyclic terpanes （carbon number up to C35） and gammacerane have been observed in those source rocks with relatively abundant 17α（H）-diahopanes, which is rarely seen in previous reports. In this paper, the formation of 17α（H）-diahopanes has been discussed from three aspects including maturity, oxidation-reduction nature of depositional environment and parent material composition by the GC/MS analyses. The results reveal that maturity and oxidation-reduction nature of depositional environment have little effect on the formation of 1 7α（H）-diahopanes in the investigated area. How- ever, the positive correlation between long-chain tricyclic terpanes and 17α（H）-diahopanes argues strongly for a common origin, and the origin is related to the algaes in saline water environment. The algaes in saline water envi- ronment may be a kind of origin of 1 7α（H）-diahopanes.     

Arsenic Distribution Pattern in Different Sources of Drinking Water and their Geological Background in Guanzhong Basin,Shaanxi, China

To study arsenic(As) content and distribution patterns as well as the genesis of different kinds of water, especially the different sources of drinking water in Guanzhong Basin, Shaanxi province, China, 139 water samples were collected at 62 sampling points from wells of different depths, from hot springs, and rivers. The As content of these samples was measured by the intermittent flowhydride generation atomic fluorescence spectrometry method(HG-AFS). The As concentrations in the drinking water in Guanzhong Basin vary greatly(0.00–68.08 μg/L), and the As concentration of groundwater in southern Guanzhong Basin is different from that in the northern Guanzhong Basin. Even within the same location in southern Guanzhong Basin, the As concentrations at different depths vary greatly. As concentration of groundwater from the shallow wells(50 m deep, 0.56–3.87 μg/L) is much lower than from deep wells(110–360 m deep, 19.34–62.91 μg/L), whereas As concentration in water of any depth in northern Guanzhong Basin is 10 μg/L. Southern Guanzhong Basin is a newly discovered high-As groundwater area in China. The high-As groundwater is mainly distributed in areas between the Qinling Mountains and Weihe River; it has only been found at depths ranging from 110 to 360 m in confined aquifers, which store water in the Lishi and Wucheng Loess(Lower and Middle Pleistocene) in the southern Guanzhong Basin. As concentration of hot spring water is 6.47–11.94 μg/L; that of geothermal water between 1000 and 1500 m deep is 43.68–68.08 μg/L. The high-As well water at depths from 110 to 360 m in southern Guanzhong Basin has a very low fluorine(F) value, which is generally 0.10 mg/L. Otherwise, the hot springs of Lintong and Tangyu and the geothermal water in southern Guanzhong Basin have very high F values(8.07–14.96 mg/L). The results indicate that highAs groundwater in depths from 110 to 360 m is unlikely to have a direct relationship with the geothermal water in the same area. As concentration of all reservoirs and rivers(both contaminated and uncontaminated) in the Guanzhong Basin is 10 μg/L. This shows that pollution in the surface water is not the source of the high-As in the southern Guanzhong Basin. The partition boundaries of the high- and low-As groundwater area corresponds to the partition boundaries of the tectonic units in the Guanzhong Basin. This probably indicates that the high-As groundwater areas can be correlated to their geological underpinning and structural framework. In southern Guanzhong Basin, the main sources of drinking water for villages and small towns today are wells between 110–360 m deep. All of their As contents exceed the limit of the Chinese National Standard and the International Standard(10 μg/L) and so local residents should use other sources of clean water that are 50 m deep, instead of deep groundwater(110 to 360 m) for their drinking water supply.     

新型旋转减冲装置对桩基局部冲刷防护试验研究

为减轻海上风电单桩基础周围局部冲刷对其结构安全的影响,提出了一种新型旋转减冲装置。在波流水槽中开展物理模型试验,改变波流条件、装置安装高度、安装距离,记录桩周冲刷发展历时,运用激光地形仪扫描冲刷坑形态,分析各工况下冲刷坑形态差异,验证装置不同安装距离、安装高度下的冲刷防护效果,提出了不同安装位置下的防护效率公式。结果表明：新型旋转减冲装置具有较好的冲刷防护效果,本试验工况下,桩周最大冲刷深度可减小44%左右。装置安装距离对冲刷防护效果影响较小,波流作用下的冲刷防护效果受装置安装高度影响显著,冲刷防护效果随装置安装高度的增加而减弱。