Model studies of the impact of chemical inhomogeneity on SO2 oxidation in warm stratiform clouds

A one-dimensional, time-dependent model of the physics and chemistry of a warm stratiform cloud is used to study the possible impact of chemical inhomogeneity among cloud and raindrops on the oxidation of SO₂ in clouds. The effects of chemical inhomogeneity are examined using two contrasting models: In Model 1 a bulk-solution parameterization is adopted which effectively treats all cloud and raindrops as if they are chemically homogeneous; in Model 2 we allow the cloud and raindrops to have a dichotomous distribution. The dichotomous distribution in Model 2 is simulated by assuming that the two groups of cloud droplets nucleate from two chemically distinct populations of condensation nuclei; one being acidic and the other being alkaline. While the two models yield essentially identical results when the ambient levels of H₂O₂ are greater than the ambient levels of SO₂, the rate of conversion of SO₂ to sulfuric acid and the amount of sulfate removed in the precipitation can be significantly enhanced in Model 2 over that of Model 1 under conditions of oxidant limitation (i.e., H₂O₂ < SO₂). This enhancement is critically dependent upon the fraction of alkaline nuclei assumed to be present in Model 2 and arises from the rapid increase in the aqueous-phase reaction between O₃+S_IV at high pH. Our results suggest that cloud models which adopt a bulk-solution parameterization for cloud droplet chemistry, may underestimate the amount of in-cloud SO₂ oxidation under oxidant-limited conditions.     

HP—3808A测距仪测距精度分析

本文采用数理统计方法,详细分析了HP—3808A激光测距仪近几年来积累的测量数据,求得仪器平均测距相对精度为1:70万。并且讨论了进一步提高测距精度的技术措施。     

Petrochemistry,Age and Petrogenesis of the Shexian Pluton in Southern Anhui

The Shexian gneissic granodiorite in southern Anhui trends NE 55° from Shexian in the west to Guitoujian in the east with a length of 22 km and an outcrop area of 32 km. It was considered formerly to be Caledonian on the basis of a biotite K-Ar age of 474 Ma (1982). However, new evidence indicates that it may be Early Jinning in age as shown by: (1) it is found intruding into the Mid-Proterozoic Shangxi Group and is unconformably overlain by the Sinian Xiuning Formation, and (2) a zircon U-Th-Pb age of 928 Ma is obtained for the pluton. The pluton is composed of plagioclase (An=27.37%), K-feldspar(14%), biotite(16%) and quartz(32%). Accessory minerals are ilmenite (150g/T), xenotime (15g/T). garnet(25g/T), monazite(10g/T), zircon (20g/T) and apatite (104g/T). Petrochemical characteristics of the intrusion are:(l) Al-enrichment (A/NKC=1.30); (2) H₂O enrichment (H₂O= 1.74%); and (3) low oxidation index (f ’=0.10). It belongs to the continental crust transformation type as evidenced by: (1) MF and Mg/Y values of biotite are 0.41 and 0.31 respectively; (2) (⁸⁷Sr/⁸⁶Sr)=0.71119; (3) δ Eu=0.52; and (4) A/NKC=130. The Shexian pluton is therefore considered as a product of melting of phyllite at depth in the light of similarities in trace element and REE contents with the phyllite of the Banxi Group. Calculations of REE batch partial melting indicate that it may have resulted from 75% melting of the Banxi phyllite.     

Theoretical research on intensity envelope function of strong ground motion

（金星，瘳振鹏）Ｔｈｅｏｒｅｔｉｃａｌｒｅｓｅａｒｃｈｏｎｉｎｔｅｎｓｉｔｙｅｎｖｅｌｏｐｅｆｕｎｃｔｉｏｎｏｆｓｔｒｏｎｇｇｒｏｕｎｄｍｏｔｉｏｎ￥ＸｉｎｇＪＩＮａｎｄＺｈｅｎ－ＰｅｎｇＬＩＡＯ（ＩｎｓｔｉｔｕｔｅｏｆＥｎｇｉｎｅｅｒｉｎｇＭｅｃｈ...     

The impact of high altitude aircraft on the ozone layer in the stratosphere

The paper discusses the potential effects on the ozone layer of gases released by the engines of proposed high altitude supersonic aircraft. The major problem arises from the emissions of nitrogen oxides which have the potential to destroy significant quantities of ozone in the stratosphere. The magnitude of the perturbation is highly dependent on the cruise altitude of the aircraft. Furthermore, the depletion of ozone is substantially reduced when heterogeneous conversion of nitrogen oxides into nitric acid on sulfate aerosol particles is taken into account in the calculation. The sensitivity of the aerosol load on stratospheric ozone is investigated. First, the model indicates that the aerosol load induced by the SO₂ released by aircraft is increased by about 10–20% above the background aerosols at mid-high latitude of the Northern Hemisphere at 15 km for the NASA emission scenario A (the NASA emission scenarios are explained in Tables I to III). This increase in aerosol has small effects on stratospheric ozone. Second, when the aerosol load is increased following a volcanic eruption similar to the eruption of El Chichon (Mexico, April 1982), the ozone column in spring increases by as much as 9% in response to the injection of NO _x from the aircraft with the NASA emission scenario A. Finally, the modeled suggests that significant ozone depletion could result from the formation of additional polar stratospheric clouds produced by the injection of H₂O and HNO₃ by the aircraft engines.     

1932年昌马地震构造力学特征探讨

１９３２年昌马地震构造力学特征探讨郭万武，张范民，邢成起，温增平（国家地震局兰州地震研究所，兰州）ＤＩＳＣＵＳＳＩＯＮＯＮＴＨＥＴＥＣＴＯＮＯＭＥＣＨＡＮＩＣＦＥＡＴＵＲＥＳＯＦ１９３２ＣＨＡＮＧＭＡＥＡＲＴＨＱＵＡＫＥＭｓ７．６￥ＧｕｏＷａｎｗｕ；...     

一个斜压海洋风生环流的数值模拟

为研究大尺度海气相互作用、气候以及气候的变化,一个具有规则海岸线和无海底地形的三层斜压海洋模式已经建立起来。积分区域包括了赤道地区在内,南北方向从-2750 km到+4750 km,东西方向宽10000 km,总深度是4 km。模式方程为原始方程,用了静力近似和Bou-sinesq近似。模式数值积分分两个阶段,在第一个阶段,海洋环流从静止状态开始,以只随纬度变化的年平均风应力和海表热通量作为强迫边条件数值积分十年,这时海洋上层的环流和温度都趋于平稳,我们将第十年末的积分状态作为模式气候的准平衡态。计算结果模拟了热带太平洋上气候平均的温度分布以及主要海流的大尺度特征,如赤道地区的狭长冷水带和强上翻区、南赤道洋流、北赤道逆流以及表层下面沿赤道自西向东的潜流。在第二个阶段,以在第一个阶段末尾得到的准平衡态作为初值,分别用冬季和夏季的风应力作为强迫边条件再积分一年。比较这两种计算结果,我们看到海洋环流随信风系统的季节变化也呈现出明显的季节变化,特别是北赤道逆流,其强度在夏季强,在冬季弱甚至不出现。南赤道洋流无论哪个季节都穿过赤道,在赤道以北的南赤道洋流冬季比夏季强,而在赤道以南的南赤道洋流夏季比冬季强。     

皖南和赣东北蛇绿岩成因及其构造意义：元素和Sm－Nd同位素制约

本文对扬子块体南缘构造侵位于板溪群（及相应地层）的皖南和赣东北晚元古代蛇绿岩进行了系统的元素和Ｓｍ－Ｎｄ同位素地球化学研究，结果表明两套蛇绿岩具有类似的元素地球化学特征，即二者的火山岩元素地球化学特征均类似于形成于弧后盆地构造环境的拉斑玄武岩。但是，两套蛇绿岩的Ｎｄ同位素组成明显不同。赣东北蛇绿岩具有相当均一的高εＮｄ（Ｔ）值（＋５．５±１．２），表明来源于一较亏损的上地幔源区，并且没有受到明显的较成熟地壳物质的混染。相反，皖南蛇绿岩的εＮｄ（Ｔ）值低，并有较大的变化范围（＋４．５──１．０），并和Ｓｍ／Ｎｄ、Ｎｄ、ＭｇＯ、ＳｉＯ２呈明显的二元混合相关关系，表明蛇绿岩是由亏损幔源岩浆（初始εＮｄ（Ｔ）≈＋５．５）在结晶分异过程中与地壳组分（初始εＮｄ（Ｔ）≈－１）混合形成的。皖南和赣东北蛇绿岩的Ｎｄ同位素和元素地球化学特征以及该地区的同时代花岗岩和火山岩的时空分布特征，可以用华南和扬子元古宙陆－弧－陆碰撞模式来解释。大约在１．０Ｇａ前，扬子和华南块体之间存在一多岛弧洋盆。大陆边缘岛弧和大洋岛弧在扬子块体南缘发育演化。皖南和赣东北蛇绿岩就是在大陆边缘盆地和弧间盆地演化过程中形成的洋壳构造侵位的碎片。该地区Ｉ型     

鄂西二叠系生物礁的基本特征及其发育规律

鄂西二叠系生物礁分布于利川县境,它是由海绵、水螅等造架生物组成的典型的生物礁,其层位属晚二叠世长兴组,出露于见天坝、黄泥塘等地(图1)。此生物礁从出露之完整、化石之丰富、结构之清楚来看,是我国最发育的生物礁之一。