Source Enrichment Control on the Scale of Magmatic-Hydrothermal W-Sn Mineralization: Insights from Triassic and Jurassic Magma Reservoirs in the Continental Crust, Xitian, South China

There are two factors, source composition and magmatic differentiation, potentially controlling W-Sn mineralization. Which one is more important is widely debated and may need to be determined for each individual deposit. The Xitian granite batholith located in South China is a natural laboratory for investigating the above problem. It consists essentially of two separate components, formed in the Triassic at ca. 226 Ma and Jurassic at ca. 152 Ma, respectively. The Triassic and Jurassic rocks are both composed of porphyritic and fine-grained phases. The latter resulted from highly-differentiated porphyritic ones but they have similar textural characteristics and mineral assemblages, indicating that they reached a similar degree of crystal fractionation. Although both fine-grained phases are highly differentiated with elevated rare metal contents, economic W–Sn mineralization is rare in the Triassic granitoids and this can be attributed to less fertile source materials than their Jurassic counterparts, with a slightly more enriched isotopic signature and whole-rock εNd(226 Ma) of ?10.4 to ?9.2 (2σ = 0.2) compared with εNd(152 Ma) of ?9.2 to ?8.2 (2σ = 0.2) for the Jurassic rocks. The initial W-Sn enrichment was derived from the metasedimentary rocks and strongly enhanced by reworking of the continental crust, culminating in the Jurassic.     

中国东北~500Ma泛非期孔兹岩带的确定及其意义

东北地区的变质基底,如佳木斯地块的麻山群、兴安地块的兴华渡口群等岩石组合是以(含石墨)大理岩、夕线石榴片麻岩、斜长角闪岩等为主要标志的孔兹岩系。在额尔古纳、兴安和佳木斯-兴凯地块的夕线石榴片麻岩分别得到锆石U-Pb年龄,证明这些高级变质岩的原岩年龄以新元古代(600~850Ma)为主,变质年龄为~500Ma,因此东北地区的变质基底记录了从Rodinia 到 Gondwana大陆的聚合与离散的过程。泛非期高级变质岩及其同期岩浆岩在额尔古纳、兴安、松辽、佳木斯 和兴凯地块等断续分布,总体出露范围>1300km,并沿虎头、鸡西、萝北、兴华渡口和漠河一线总体北西向沿黑龙江断续分布,因此我们命名为"中国东北泛非期孔兹岩带"。 "中国东北泛非期孔兹岩带"的提出和进一步研究, 对深入探讨东北地区各地块基底组成的异同性以及陆块聚合的过程,以及东北地区的构造演化历史及其在Gondwana大陆重建中的位置都具有重要的科学意义。     

吉林-黑龙江高压变质带的初步厘定:证据和意义

本文定义的吉林-黑龙江高压变质带是指我国东北地区佳木斯-兴凯地块西缘和南缘共同发育的呈弧形展布的高压变质带,具体包括佳木斯-兴凯地块西缘增生杂岩带(黑龙江蓝片岩带和张广才-小兴安岭增生杂岩带)和佳木斯-兴凯地块南缘的长春-延吉增生杂岩带.其中佳木斯-兴凯地块西缘增生杂岩带形成于晚三叠-早侏罗世(180 ～ 210Ma),为佳木斯-兴凯地块向西冲增生而形成的高压变质带;而长春-延吉增生杂岩带由一系列特征性俯冲-增生杂岩组成,包括石头口门-烟筒山红帘石片岩带、呼兰群变质杂岩、色洛河群变质杂岩、青龙村群变质杂岩和开山屯变质杂岩等,形成时代为187～230Ma,峰期为220～230Ma.长春-延吉增生杂岩带曾被认为是西拉木伦河断裂带的东延部分,但是区域构造分析表明,它们形成的动力学背景与佳木斯-兴凯地块西缘增生杂岩带相同,均为太平洋板块三叠纪-早侏罗世的西向俯冲导致佳木斯-兴凯地块自东向西的“剪刀式”闭合过程.我们将佳木斯-兴凯地块西缘和南缘发育的三叠纪-早侏罗世增生杂岩带作为统一的构造单元来考虑,结合该区发育有典型的高压变质带,因此命名为“吉林-黑龙江高压变质带,简称吉黑高压带”.吉黑高压带形成于太平洋板块三叠纪-早侏罗世的西向俯冲导致佳木斯-兴凯地块自东向西的“剪刀式”闭合的过程,同时该带记录了古亚洲构造域的结束和太平洋俯冲开始的关键时期,为两大构造域叠加与转换的关键性地质证据.     

佳木斯地块片麻状花岗岩的锆石离子探针U—Pb年龄

我国东北地区佳木斯地块分布有大量的花岗质岩石，这些花岗岩可分为两个大的类型，其一为基底花岗片麻岩类，岩石曾经历过50Ma左右的角闪岩相－麻粒岩相变质作用的改造，并具有与麻山群变质岩系相同或一致的片麻理构造。其二为片麻状花岗岩类，片麻理发育程度不等，岩石显示明显的岩浆结晶结构，不具有任何后期变质作用叠加的痕迹，传统认为片麻状花岗岩形成于新元古代，但本文通过高精度的锆石离子探针U－Pb测年表明，这些花岗岩主要形成于270－254Ma的晚古生代，且部分岩石中含有较老的锆石颗粒或残留，表明这些花岗岩主要来源于基底岩石的部分熔融，测定岩石的矿物组成和化学成分特点暗示，它的形成可能与佳木斯地块与周围块体或佳木斯地块内部块体间的拼合作用有关。     

鞍山地区铁架山花岗岩及表壳岩的锆石SHRIMP年代学和Hf同位素组成

辽宁鞍山中太古代铁架山花岗岩是华北克拉通时代最古老、分布范围最大的富钾质花岗岩。具相对高钾(4.77～5.75%)低钠(3.16～3.52%)、强烈负铕负钡异常(Eu/Eu*=0.40～0.51,Ba/Ba*=0.15～0.26)的组成特征,且高t_(DM)(Nd) (3.42～3.38Ga),低ε_(Nd)(t)(-3.61～-2.51)。花岗岩样品A9837和A0433岩浆锆石年龄分别为2992±10Ma和2983±10Ma。结合前人定年结果,可把铁架山花岗岩主体形成时代限制在2.96～2.99Ga之间。另一花岗岩样品A9825岩浆锆石年龄为2914±4Ma,可能代表了铁架山花岗岩形成后局部深熔作用的时代。首次在铁架山花岗岩中获得残余锆石年龄,其最大达3759Ma。2个花岗岩样品(A9837,A9825)岩浆锆石的t_(DM)(Hf)和ε_(Hf)(t)分别为3.48～3.32Ga和-7.85～-2.29.残余锆石的t_(DM)(Hf)和ε_(Hf)(t)分别为3.89～3.47Ga和-19.5～-6.2。这些资料为铁架山花岗岩形成于古老陆壳物质再循环提供了直接证据。存在于铁架山花岗岩中的表壳岩主要为变质沉积岩,其地球化学组成特征与铁架山花岗岩类似。3个变质沉积岩样品(A9819,A0435,A0436)的碎屑锆石年龄大都为～3.0Ga,其中2个样品(A0435,A0436)的碎屑锆石ε_(Hf)(t)和t_(DM)(Hf)分别为-9.93～-2.29和3672～3297Ma,与铁架山花岗岩中的岩浆锆石类似。表明这些变质沉积岩形成于铁架山花岗岩之后,而不是以前认为的那样为铁架山花岗岩中的包体。     

High-Pressure Granulites (Retrograded Eclogites) from the Hengshan Complex, North China Craton: Petrology and Tectonic Implications

Both high- and medium-pressure granulites have been found asenclaves and boudins in tonalitic–trondhjemitic–granodioriticgneisses in the Hengshan Complex. Petrological evidence fromthese rocks indicates four distinct metamorphic assemblages.The early prograde assemblage (M₁) is preserved only in thehigh-pressure granulites and represented by quartz and rutileinclusions within the cores of garnet porphyroblasts, and omphacitepseudomorphs that are indicated by clinopyroxene + sodic plagioclasesymplectic intergrowths. The peak assemblage (M₂) consists ofclinopyroxene + garnet + sodic plagioclase + quartz ±hornblende in the high-pressure granulites and orthopyroxene+ clinopyroxene + garnet + plagioclase + quartz in the medium-pressuregranulites. Peak metamorphism was followed by near-isothermaldecompression (M₃), which resulted in the development of orthopyroxene+ clinopyroxene + plagioclase symplectites and coronas surroundingembayed garnet grains, and decompression-cooling (M₄), representedby hornblende + plagioclase symplectites on garnet. The THERMOCALCprogram yielded peak (M₂) P–T conditions of 13·4–15·5kbar and 770–840°C for the high-pressure granulitesand 9–11 kbar and 820–870°C for the medium-pressuregranulites, based on the core compositions of garnet, matrixpyroxene and plagioclase. The P–T conditions of pyroxene+ plagioclase symplectite and corona (M₃) were estimated at