Search for class I methanol maser emission toward several supernova remnants

Observations at 44 GHz in the 7₀−6₁ A ⁺ methanol line have been carried out on the 20-m telescope of the Onsala Space Observatory (Sweden) in the directions of the poorly studied region G27.4–0.2 and of several supernova remnants, at the coordinates of the OH(1720) maser satellite emission, with the aim of searching for Class I methanol maser emission in these sources. The region G27.4–0.2 has beenmapped, and contains maser sources and two supernova remnants with similar coordinates and radial velocities, which may accelerate condensation of the ambient gas-dust medium. This may play a role in enhancing the probability of methanol formation and maser emission. This is the first detection of 44 GHz maser emission in this source, and this maser is among the 10% of the strongest Class I methanol masers, within the uncertainties in the integrated flux (of a total of 198 currently knownmasers). A 27′ × 27′ region around the maser has been mapped at 44 GHz in steps of 1′. The 44-GHz emission forms only within the previously known maser region. Further studies in water lines are needed to estimate the influence of shocks from supernovae. No 44-GHz Class I methanol maser emission was detected at the 3σ level at the coordinates of the OH(1720) satellite emission in six supernova remnants; i.e., the presence of OH(1720) emission is not a sufficient condition for the detection of Class I methanol masers.     

Contribution of geophysical methods to karst-system exploration: an overview

The karst environment is one of the most challenging in terms of groundwater, engineering and environmental issues. Geophysical methods can provide useful subsurface information in karst regions concerning, for instance, hazard estimation or groundwater exploration and vulnerability assessment. However, a karst area remains a very difficult environment for any geophysical exploration; selection of the best-suited geophysical method is not always straightforward, due to the highly variable and unpredictable target characteristics. The state of the art is presented, in terms of the contributions made by geophysical methods to karst-system exploration, based on extensive analysis of the published scientific results. This report is an overview and should be used as a preliminary methodological approach, rather than a guideline.     

Geogene Versus Anthropogene Origin of Trace Metals in Sediments in Cua Luc Estuary and Ha Long Bay, Vietnam

In the present study, the geochemistry of 49 surficial-bed and 101 core sediment samples is investigated to clarify the origin of trace metals in the Cua Luc Estuary and Ha Long Bay, which is a famous World Natural Heritage Site in Vietnam. Moreover, the potential mobility of trace metals is also assessed and their relationship with reference elements (Al, Fe, and Ca) and organic matter is established in order to make recommendations for sediment management and monitor future pollution. Generally, trace metals display higher concentrations in Ha Long Bay compared to the Cua Luc Estuary. However, this is controlled by the distribution of the fine (clay?+?silt) fraction, and hence the concentrations of Al, Fe, Ca, and organic matter (OM). The comparison of concentrations of trace metals (normalized towards Al) between the surficial sediments and the subsurface core sediments based on ¹³⁷Cs datings indicates that almost all surficial-sediment data fall inside or deviate slightly from the 95 % prediction interval of a background regression line. In addition, as determined by a Community Bureau of Reference three-step extraction, trace metals mainly dominate in the residual fraction (assumed to relate to crystal lattice of primary and secondary minerals), and this fraction does not change much in recent sediment layers. Therefore, trace metals are supposed to be derived from natural bio/geochemical processes and are characterized by a low potential mobility. Consequently, the established linear regression relationships of trace metal vs. Al or multiple regression relationships of trace metal vs. multi-elements (Al, Fe, Ca, and OM) are useful for the prediction of background levels of trace metals in sediments in future pollution monitoring and assessment programs.     

Comparative phylogeography of African rain forest trees: A review of genetic signatures of vegetation history in the Guineo-Congolian region

The biogeographic history of the African rain forests has been contentious. Phylogeography, the study of the geographic distribution of genetic lineages within species, can highlight the signatures of historical events affecting the demography and distribution of species (i.e. population fragmentation or size changes, range expansion/contraction) and, thereby, the ecosystems they belong to. The accumulation of recent data for African rain forests now enables a first biogeographic synthesis for the region. In this review, we explain which phylogeographic patterns are expected under different scenarios of past demographic change, and we give an overview of the patterns detected in African rain forest trees to discuss whether they support alternative hypotheses regarding the history of the African rain forest cover. The major genetic discontinuities in the region support the role of refugia during climatic oscillations, though not necessarily following the classically proposed scenarios. We identify in particular a genetic split between the North and the South of the Lower Guinean region. Finally we provide some perspectives for future study.     

Discreteness of spatial-temporal manifestations of solar activity and solar-terrestrial phenomena

The discreteness of the time series of the solar-related geophysical phenomena is justified. The balance of the formation and decomposition (neglecting diffusion) of fractal elements during the evolution of the equilibrium systems as applied to the heliophysical and geomagnetic phenomena is the original position in this case. The discreteness properties of the spatial-temporal characteristics of solar activity are simply justified based on a fractal analysis. The performed calculations in the solar wind medium in the near-Earth space make it possible to classify the fluxes depending on their fractal dimension. The possible mechanism by which high-speed solar wind streams are generated is also briefly discussed in the scope of the fractal paradigm.     

Statistical Study and Prediction of Variability of Erythemal Ultraviolet Irradiance Solar Values in Valencia,Spain

The goal of this study was to statistically analyse the variability of global irradiance and ultraviolet erythemal (UVER) irradiance and their interrelationships with global and UVER irradiance, global clearness indices and ozone. A prediction of short-term UVER solar irradiance values was also obtained. Extreme values of UVER irradiance were included in the data set, as well as a time series of ultraviolet irradiance variability (UIV). The study period was from 2005 to 2014 and approximately 250,000 readings were taken at 5-min intervals. The effect of the clearness indices on global irradiance variability (GIV) and UIV was also recorded and bi-dimensional distributions were used to gather information on the two measured variables. With regard to daily GIV and UIV, it is also shown that for global clearness index (k_t) values lower than 0.6 both global and UVER irradiance had greater variability and that UIV on cloud-free days (k_t higher than 0.65) exceeds GIV. To study the dependence between UIV and GIV the χ² statistical method was used. It can be concluded that there is a 95% probability of a clear dependency between the variabilities. A connection between high k_t (corresponding to cloudless days) and low variabilities was found in the analysis of bi-dimensional distributions. Extreme values of UVER irradiance were also analyzed and it was possible to calculate the probable future values of UVER irradiance by extrapolating the values of the adjustment curve obtained from the Gumbel distribution.     

Windstorm of the eighteenth century in the Czech Lands: course,extent, impacts

Theoretical and Applied Climatology - This paper addresses the course, extent, and impacts of a windstorm that occurred on 20–21 December 1740, in the Czech Lands. The analysis is based on...     

Spectroscopic and bond-topological investigation of interstitial volatiles in beryl from Slovakia

Nine beryl samples from Western Carpathians, Slovakia, were investigated by infrared and Raman spectroscopy and differential thermal analysis. Two types of water H₂O I and H₂O II were detected. Infrared spectroscopy proved the presence of water type I and II in the presence of alkali cations with several bands: (1) symmetric stretching vibration—ν₁; (2) antisymmetric stretching mode—ν₃; (3) bending vibration—ν₂. The presence of singly and doubly coordinated type II water (IIs and IId) was confirmed by single-crystal IR spectroscopy. From Raman spectra a band at 3606 cm^?1 was assigned to ν₁ of water type I and the range of 3597–3600 cm^?1 to water type II. The presence of doubly coordinating water indicates a relatively highly hydrated environment with the presence of alkali ions including Na as the dominant cation coordinated by H₂O II. CO₂ bands were detected only by single-crystal IR spectroscopy. Thermal analysis proved total water loss in the range of 1.4–2.0 wt% and three main dehydration events. Based on the study of bond-topological arrangements two molecules of H₂O IId are each bound with two H···O1 bonds and one Na–O_W bond with an angular distortion, and by releasing one H₂O molecule more stable H₂O IIs is produced. The H₂O I molecule is bound only by two equivalent hydrogen bonds. The H₂O IIs molecule with a Na–O_W bond strength of 0.28 vu and two H···O1 bonds of 0.14 vu without any forced angular distortion is the most stable of all.