Estimation of spectral refractive index of colloidal sulfur at 20°C

In the marine environment, colloidal sulfurs often occur due to the redox reaction of sulfide ions and oxygen molecules. It is important to know the spectral refractive index of colloidal sulfurs for the discussion of the light scattering in the region where colloidal sulfurs are formed. We presented new methods to estimate the refractive index from the wave length of maximum absorbance (turbidity) of a nearly mono-dispersed colloidal solution. In these methods, the ripples in a first main maximum of the scattering efficiency,Q _sca , were taken into consideration. By virtue of these methods, we obtained the spectral refractive index of colloidal sulfurs,m _s (), at 20°C. The Cauchy's expression of it was given by

In situ hydraulic tests in the active fault survey tunnel, Kamioka Mine, excavated through the active Mozumi-Sukenobu Fault zone and their hydrogeological significance

Abstract   The spatial hydrogeological and structural character of the active Mozumi-Sukenobu Fault (MSF) was investigated along a survey tunnel excavated through the MSF in the Kamioka Mine, central Japan. Major groundwater conduits on both sides of the MSF are recognized. One is considered to be a subvertical conduit between the tunnel and the surface, and the other is estimated to be a major reservoir of old meteoric water alongside the MSF. Our studies indicate that part of the MSF is a sub-vertical continuous barrier that obstructs younger meteoric water observed in the south-eastern part of the Active Fault Survey Tunnel (AFST) and water recharge to the rock mass intersected by the north-western part of the AFST. The MSF might be a continuous barrier resulting in the storage of a large quantity of older groundwater to the northwest. The observations and results of in situ hydraulic tests indicate that the major reservoir is not the fault breccia associated with the northeast–southwest trending faults of the MSF, but the zone in which blocks of fractured rocks occur beside high angle faults corresponding to X shears whose tectonic stress field coincides with the present regional stress field and antithetic Riedel shears of the MSF. The results from borehole investigations in the AFST indicate that secondary porosity is developed in the major reservoir due to the destruction of filling minerals and fracture development beside these shears. The increase in hydraulic conductivity is not directly related to increased density of fractures around the MSF. Development of secondary porosity could cause the increase in hydraulic conductivity around the MSF. Our results suggest that minor conduits of the fracture network are sporadically distributed in the sedimentary rocks around the MSF in the AFST.     

Rare earth element distribution in the Melrose-b howardite: Pre-terrestrial negative Ce anomaly

In order to investigate the genetic nature of the polymict breccia howardite Melrose-b, a whole-rock sample was separated into four fractions after pulverization and the rare earth element (REE) abundances were precisely determined by isotopic dilution in those fractions. Such an investigation shows that the three precipitated fine-particle fractions are depleted in Ce by the same factor (0.62 ～ 0.64) in spite of differences in mineralogy, while the corresponding factor of Ce depletion for the suspended-matter fraction is 0.462; the smaller value indicates a greater depletion in Ce.The weight fraction values of four fractions calculated from the REE abundances are in satisfactory agreement with the actual values. The concentration ratios between plagioclase and mainly pigeonite fractions accord with those observed in similar phases of the Juvinas eucrite [1]. Moreover, the bulk pattern synthesized from the three fine-particle fractions is similar in absolute level to that for the Zmenj howardite [1]. It is concluded that the negative Ce anomaly reflects the effect predating the igneous activity in the parent planetary body.     

Current state of integrated earthquake simulation for earthquake hazard and disaster

This paper presents the current state of integrated simulation for earthquake hazard and disaster. This simulation takes advantage of the macro–micro analysis method; this method estimates an earthquake’s strong motion with high spatial and temporal resolution, using the bounding medium theory to obtain optimistic and pessimistic estimates of expected strong motion distribution and the singular perturbation expansion that results in an efficient multi-scale analysis. Integrated earthquake simulation calculates seismic responses for all structures in a target area, inputting simulated strong ground motion to a structure analysis method that is plugged into the system by means of a wrapper; a suitable method, linear or nonlinear, is chosen depending on the type of the structure. The results of all simulations are visualized so that residences and government officials can share a common recognition of earthquake hazard and disaster. Two examples of this integrated earthquake simulations are presented; one is made by plugging nonlinear structure analysis methods into the system, and the other is made for an actual city, the computer model of which is constructed with the help of available geographical information systems.     

1679年三河-平谷8级地震破裂带的大地切片实验研究

大地切片调查法,就是在不搅动的状态下从地下切出未固结的第四纪浅部地层的垂直断片,它是一种较新的活动断层探测技术。发生在1679年9月2日的三河-平谷8级地震(烈度Ⅺ),是北京及附近地区历史上记录到的最大地震。在该地震的宏观震中——潘各庄附近,运用大地切片调查法对该地震破裂带进行了实验性探测,获得了较好的效果。实验研究表明:大地切片保留了完好的沉积细结构特征;大地切片调查实施时,要选择合适的动力源,对于北京平原这种黏土含量较高的沉积层,挖掘机加振动锤的动力组合优于吊车加振动锤的动力组合;大地切片由于振动会造成一定地层厚度的压缩,但黏土含量较高的北京地区,压缩比例基本<5%。另外,结合探槽和大地切片的对比分析,揭示了最近2次古地震事件,分别是1679年事件和该地震之前的一次事件,两次地震的垂直同震位移分别是1·4m和1·2m     

冻结作用下黏土中水、盐迁移试验研究

为了探究冻结作用下黏土中水盐迁移特性,采用室内单向冻结试验装置,基于TDR技术对添加不同溶质（NaCl）浓度的土样进行了土中温度、含水率及电导率（EC）的同时连续测量。结果表明：溶质的添加引起土中孔隙水冰点下降,造成土中成冰量减少,从而导致含溶质土样的冻结深度大于不含溶质土样;在封闭系统中随着溶质浓度的增大,土中水分迁移量和溶质迁移率均有增大趋势,距离冻结锋面越远,水分、溶质迁移量就越少;冻结锋面附近液态水凝结成冰,引起冻结锋面附近溶质浓度变化剧烈,溶质浓度急剧增大。     

Geochemical and Microbiological Analysis of Sambe Hot Springs,Shimane Prefecture,Japan

Microbiological contribution to the formation of the manganese deposits in Sambe hot springs, Shimane, was investigated in combination with water chemistry, characterization of sediments and microbial community structure. Analysis of bacterial and fungal community structure based on DNA extracted from a Mn‐oxidizing enrichment culture indicated close matches with Pseudomonas putida, Phoma sp. and Plectosphaerella cucumerina, all Mn‐oxidizing microorganisms. These sediments were poorly crystalline and formed at neutral pH values, which is characteristic of biogenic precipitates. The EPMA results demonstrated a positive correlation between Mn and Ba contents in well‐crystalline Mn oxide grains. Substantial Ba contents were observed inside Mn oxide grains. These findings indicated that Ba contents in sediments are influenced by not only aqueous Ba²⁺ concentrations but also crystallinity of biogenic birnessite. Barium would be incorporated in birnessite during biomineralization.     

Influence of contamination on banded iron formations in the Isua supracrustal belt,West Greenland: Reevaluation of the Eoarchean seawater compositions

Banded Iron Formations(BIFs) are chemical sediments, ubiquitously distributed in the Precambrian supracrustal belts; thus their trace element compositions are helpful for deciphering geochemical evolution on the Earth through time. However, it is necessary to elucidate factors controlling the whole-rock compositions in order to decode the ancient seawater compositions because their compositions are highly variable. We analyzed major and trace element contents of the BIFs in the 3.8-3.7 Ga Isua supracrustal belt(ISB), southern West Greenland. The BIFs are petrographically classified into four types:Black-,Gray-, Green-and White-types, respectively. The Green-type BIFs contain more amphiboles, and are significantly enriched in Co, Ni, Cu, Zn, Y, heavy rare earth element(HREE) and U contents. However,their bulk compositions are not suitable for estimate of seawater composition because the enrichment was caused by secondary mobility of metamorphic Mg, Ca and Si-rich fluid, involvement of carbonate minerals and silicate minerals of olivine and pyroxene and/or later silicification or contamination of volcanic and clastic materials. The White-type BIFs are predominant in quartz, and have lower transition element and REE contents. The Gray-type BIFs contain both quartz and magnetite. The Black-type BIFs are dominated by magnetite, and contain moderate to high transition element and REE contents. But,positive correlations of V, Ni, Zn and U contents with Zr contents suggest that involvement of detrital,volcanic and exhalative materials influences on their contents. The evidence for significant influence of the materials on the transition element contents such as Ni in the BIFs indicates the transition element contents in the Archean ocean were much lower than previously estimated. We reconstructed secular variations of V,Co, Zn and U contents of BIFs through time, which show Ni and Co contents decreased whereas V, Zn and U contents increased through time. Especially, the Ni and Co contents drastically decreased in the Mesoarchean rather than around the Great Oxidation Event. On the other hand, the V,Zn and U contents progressively increased from the Mesoarchean to the Proterozoic. Stratigraphical trends of the BIFs show increase in Y/Ho ratios and decrease in positive Eu anomaly upwards, respectively. The stratigraphic changes indicate that a ratio of hydrothermal fluid to seawater component gradually decrease through the deposition, and support the Eoarchean plate tectonics, analogous to the their stratigraphic variations of seafloor metalliferous sediments at present and in the Mesoarchean.