Distribution and photo-physiological condition of phytoplankton in the tropical and subtropical North Pacific

To better understand the vertical distribution of phytoplankton in the tropical and subtropical North Pacific, we used fast repetition rate fluorometry to investigate the photo-physiological condition of the phytoplankton assemblage in this region between February and March 2007. Along 155°E, between the equator and 24°N, the peak of fluorescence (F _m), an indication of the deep chlorophyll maximum (DCM), was deeper than the top of the nitracline and occurred at the 2.4 ± 1.3 % (mean ± SD) light depth (relative to 0 m). The photochemical efficiency (F _v/F _m) and effective absorption cross-section of photosystem II (σ_PSII) were low at the surface but increased rapidly at depths between the top of the nitracline (40–138 m) and the DCM (70–158 m), an indication that the photo-physiological condition of the phytoplankton improved below the top of the nitracline. The depth of the maximal F _v/F _m [Z(F _v/F _{m max})] was 18–32 m deeper than the DCM and corresponded to the 0.8 ± 0.2 % light depth. The values of F _v/F _m at the Z(F _v/F _{m max}) were 20 % higher than those at the DCM and averaged 0.48 ± 0.01. These results suggest that the phytoplankton assemblage beneath the DCM had a high potential photosynthetic performance capacity and was growing by using the very low ambient light in this region.     

Molecular dynamics study of pressure-induced transformation of quartz-type GeO2

We simulated quartz-type GeO₂ and investigated its high-pressure transformation using the molecular dynamics (MD) simulation method with a model potential. The calculated results under hydrostatic compression indicated that a pressure-induced amorphization of quartz-type GeO₂ originated from the mechanical instability of the quartz lattice as, in previous theoretical studies of SiO₂. Furthermore, quartz-type GeO₂ directly transformed to a rutile-like structure with only subtle displacements of ions under σ _{x y} imposed shear stressed decompression. This is the first reproduction of the quartz-to-rutile transformation. A possible pathway of this transition is proposed in this study. Received: 14 April 1999 / Revised, accepted: 11 August 1999     

Clinopyroxene-perovskite phase transition of FeGeO3 under high pressure and room temperature

In order to confirm the possible existence of FeGeO₃ perovskite, we have performed in situ X-ray diffraction measurements of FeGeO₃ clinopyroxene at pressures up to 40 GPa at room temperature. The transition of FeGeO₃ clinopyroxene into orthorhombic perovskite is observed at about 33GPa. The cell parameters of FeGeO₃ perovskite are a=4.93(2) Å, b=5.06(6) Å, c=6.66(3) Å and V=166(3) ų at 40 GPa. On release of pressure, the perovskite phase transformed into lithium niobate structure. The previously reported decomposition process of clino-pyroxene into Fe₂GeO₄ (spinel)+GeO₂ (rutile) or FeO (wüstite) +GeO₂ (rutile) was not observed. This shows that the transition of pyroxene to perovskite is kinetically accessible compared to the decomposition processes under low-temperature pressurization.     

Development of a new operational system for monitoring and forecasting coastal and open-ocean states around Japan

We developed a new system to monitor and forecast coastal and open-ocean states around Japan for operational use by the Japan Meteorological Agency. The system consists of an eddy-resolving analysis model based on four-dimensional variational assimilation and a high (2-km) resolution forecast model covering Japanese coastal areas that incorporates an initialization scheme with temporal and spatial filtering. Assimilation and forecast experiments were performed for 2008 to 2017, and the results were validated against various observation datasets. The assimilation results captured well the observed variability in sea surface temperature, coastal sea level, volume transport, and sea ice. Furthermore, the volume budget for the Japan Sea was significantly improved by the use of the 2-km resolution forecast model compared with the 10-km resolution analysis model. The forecast results indicate that this system has a predictive limit longer than 1 month in many areas, including in the Kuroshio current area south of Japan and the southern Japan Sea. In the forecast results of case studies, the 2017 Kuroshio large meander was well predicted, and warm water intrusions accompanying Kuroshio path variations south of Japan were also successfully reproduced. Sea ice forecasts for the Sea of Okhotsk largely captured the evolution of sea ice in late winter, but sea ice in early winter included relatively large errors. This system has high potential to meet operational requirements for monitoring and forecasting ocean phenomena at both meso- and coastal scales.