A high‐T metamorphic complex derived from the high‐P Suo metamorphic complex in the Omuta district,northern Kyushu,southwest Japan

New U–Pb ages of zircons from migmatitic pelitic gneisses in the Omuta district, northern Kyushu, southwest Japan are presented. Metamorphic zonation from the Suo metamorphic complex to the gneisses suggests that the protolith of the gneisses was the Suo metamorphic complex. The zircon ages reveal the following: (i) a transformation took place from the high‐P Suo metamorphic complex to a high‐T metamorphic complex that includes the migmatitic pelitic gneisses; (ii) the detrital zircon cores in the Suo pelitic rocks have two main age components (ca 1900–1800 Ma and 250 Ma), with some of the detrital zircon cores being supplied (being reworked) from a high‐grade metamorphic source; and (iii) one metamorphic zircon rim yields 105.1 ±5.3 Ma concordant age that represents the age of the high‐T metamorphism. The high‐P to high‐T transformation of metamorphic complexes implies the seaward shift of a volcanic arc or a landward shift of the metamorphic complex from a trench to the sides of a volcanic arc in an arc–trench system during the Early Cretaceous. The Omuta district is located on the same geographical trend as the Ryoke plutono‐metamorphic complex, and our estimated age of the high‐T metamorphism is similar to that of the Ryoke plutono‐metamorphism in the Yanai district of western Chugoku. Therefore, the high‐T metamorphic complex possibly represents the western extension of the Ryoke plutono‐metamorphic complex. The protolith of the metamorphic rocks of the Ryoke plutono‐metamorphic complex was the Jurassic accretionary complex of the inner zone of southwest Japan. The high‐P to high‐T transformation in the Omuta district also suggests that the geographic trend of the Jurassic accretionary complex was oblique to that of the mid‐Cretaceous high‐T metamorphic field.     

U–Pb and fission‐track dating of a submarine pyroclastic rock from southwest Japan

The Okinoshima Formation crops out on Okinoshima Island and comprises a thick sequence (> 200 m) of pyroclastic rocks and alternating beds of sandstone and mudstone. Because Okinoshima Island is located between Honshu and Tsushima Island, the Okinoshima Formation potentially provides an important record of volcanism during the opening of the Japan Sea in northwest Kyushu, as well as a record of the formation of the present Genkai Sea region. In consideration of the lack of previous geochronological work, dating (fission‐track and U–Pb) of igneous zircons extracted from the Okinoshima Formation were undertaken and studied the clay mineral alteration in the pyroclastic material in order to reveal its thermal history. These data are used to constrain the age of the Okinoshima Formation and the present Genkai Sea region. Our results show that no thermal event has reset the fission‐track age after deposition of the pyroclastic rocks, and that the Okinoshima Formation was deposited at 16.2 Ma. The present Genkai Sea region is a deep‐sea basin, and its formation at 16.2 Ma was accompanied by submarine volcanism and rapid subsidence that marked the climactic stage of Japan Sea formation. After 16 Ma, the tectonic setting of the present Genkai Sea region changed from one of extension (related to the formation of the Japan Sea) to one of compression, with uplift occurring under the influence of the clockwise rotation of southwest Japan. Consequently, after 16 Ma the present Genkai Sea region became isolated from the forming processes of the Japan Sea.     

Depositional ages and characteristics of Middle–Upper Jurassic and Lower Cretaceous lacustrine deposits in southeastern Mongolia

Lower Cretaceous lacustrine oil shales are widely distributed in southeastern Mongolia. Due to the high organic carbon content of oil shale, many geochemical studies and petroleum exploration have been conducted. Although most of the oil shales are considered to be Early Cretaceous in age, a recent study reveals that some were deposited in the Middle Jurassic. The present study aims at establishing depositional ages and characteristics of the Jurassic and Cretaceous lacustrine deposits in Mongolia. The Lower Cretaceous Shinekhudag Formation is about 250 m thick and composed of alternating beds of shale and dolomite. The Middle Jurassic Eedemt Formation is about 150 m thick and composed of alternating beds of shale, dolomitic marl, and siltstone. The alternations of shale and dolomite in both formations were formed by lake level changes, reflecting precipitation changes. Shales were deposited in the center of a deep lake during highstand, while dolomites were formed by primary precipitation during lowstand. Based on the radiometric age dating, the Shinekhudag Formation was deposited between 123.8 ±2.0 Ma and 118.5 ±0.9 Ma of the early Aptian. The Eedemt Formation was deposited at around 165–158 Ma of Callovian–Oxfordian. The calculated sedimentation rate of the Shinekhudag Formation is between 4.7 ±2.6 cm/ky and 10.0 ±7.6 cm/ky. Shales in the Shinekhudag Formation show micrometer‐scale lamination, consisting of algal organic matter and detrital clay mineral couplets. Given the average thickness of micro‐laminae and calculated sedimentation rate, the micro‐lamination is most likely of varve origin. Both Middle–Upper Jurassic and Lower Cretaceous lacustrine oil shales were deposited in intracontinental basins in the paleo‐Asian continent. Tectonic processes and basin evolution basically controlled the deposition of these oil shales. In addition, enhanced precipitation under humid climate during the early Aptian and the Callovian–Oxfordian was another key factor inducing the widespread oil shale deposition in Mongolia.     

U–Pb zircon ages of the Nakanogawa Group in the Hidaka Belt,northern Japan: Implications for its provenance and the protolith of the Hidaka metamorphic rocks

Zircon U–Pb ages of two acidic tuff and two turbidite sandstone samples from the Nakanogawa Group, Hidaka Belt, were measured to estimate its depositional age and the development of the Hokkaido Central Belt, northeast Japan. In the northern unit, homogeneous zircons from pelagic acidic tuff from a basal horizon dated to 58–57 Ma, zircons from sandstone from the upper part of the unit dated to 56–54 Ma, and zircons from acidic tuff from the uppermost part dated to 60–56 Ma and 69–63 Ma. Both of the tuff U–Pb ages are significantly older than the youngest radiolarian fossil age (66–48 Ma). Therefore, the maximum depositional age of the turbidite facies in the northern unit is 58 Ma and the younger age limit, estimated from the fossil age, is 48 Ma. In the southern unit, homogeneous zircons from turbidite sandstone dated to 58–57 Ma. Thus the depositional age of this turbidite facies was interpreted to be 66–56 Ma from the fossil age, probably close to 57 Ma. Most of the zircon U–Pb ages from the Nakanogawa Group are younger than 80 Ma, with a major peak at 60 Ma. This result implies that around Hokkaido volcanic activity occurred mainly after 80 Ma. Older zircon ages (120–80 Ma, 180–140 Ma, 340–220 Ma, 1.9 Ga, 2.2 Ga, and 2.7 Ga) give information about the provenance of other rocks in the Hidaka Belt. It is inferred that the Nakanogawa Group comprises protoliths of the upper sequence of the Hidaka Metamorphic Zone, which therefore has the same depositional age as the Nakanogawa Group (66–48 Ma). The depositional ages of the lower sequence of the Hidaka Metamorphic Zone and the Nakanogawa Group are probably the same.     

Zircon fission‐track and U–Pb double dating using femtosecond laser ablation–inductively coupled plasma–mass spectrometry: A technical note

We present a new LA–ICP–MS system for zircon fission‐track (FT) and U–Pb double dating, whereby a femtosecond laser combined with galvanometric optics simultaneously ablates multiple spots to measure average surface U contents. The U contents of zircon measured by LA–ICP–MS and standardized with the NIST SRM610 glass are comparable to those measured by the induced FT method, and have smaller analytical errors. LA–ICP–MS FT dating of seven zircon samples including three IUGS age standards is as accurate as the external detector method, but can give a higher‐precision age depending on the counting statistics of the U content measurement. Double dating of the IUGS age standards gives FT and U–Pb ages that are in agreement. A chip of the Nancy 91500 zircon has a homogeneous U content of 84 ppm, suggesting the possibility of using this zircon as a matrix‐matched U‐standard for FT dating. When using the Nancy 91500 zircon as a U‐standard, a zeta calibration value of 42–43 year cm² for LA–ICP–MS FT dating is obtained. While this value is strictly valid only for the particular session, it can serve as a reference for other studies.     

Identification of Lower Pleistocene widespread tephras associated with large caldera-forming eruptions in the Tohoku area,north-east Japan

Tephra fingerprinting techniques contributing to volcanology and palaeoenvironmental studies have been developed using a combination of laser-ablation inductively coupled-plasma mass spectrometry (LA-ICP-MS) and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS). In particular, femtosecond LA-ICP-MS can determine major- and trace element abundances in individual glass shards. On the basis of the major oxide and trace element composition of the glass shards, using those methods, we re-examined the identification of four lower Pleistocene tephras originating from north-east Japan. All trace element abundances exhibited the typical pattern of tephras from the Hokkaido–Tohoku area, and major element concentrations were distinct. As a result, we re-examined the correlation of the widespread Tmg-R4 tephra (2.0 Ma), and newly defined the widespread Kd44-Naka tephra (1.968–1.781 Ma), both originating from the Sengan geothermal region. Furthermore, we re-examined identifications of Sr-Asn-Kd8 (1.219 Ma) and Sr-Kc-U8 (0.922–0.910 Ma) in central Japan, both derived from the Aizu volcanic region. The extensive distributions of the former two tephras suggest the occurrence of two large caldera-forming eruptions (Volcanic Explosivity Index 7) during a short period. Also, the distributions and volumes of the latter two tephras are broader and larger than those previously assumed. The results provide insight into large volcanic eruption history and terrestrial and marine palaeoenvironmental history.     

Identification of the Unchanging Reference Component of Compositional Data from the Properties of the Coefficient of Variation

In analyses of compositional data, it is important to select a suitable unchanging component as a reference to detect the behavior of a single variable in isolation. This paper introduces two tests for detecting the unchanging component, based on a new approach that utilizes the coefficient of variation of component ratios. That is, the coefficient of variation of a compositional ratio is subject to change when the unchanging component is switched between the denominator and numerator, and the coefficient of variation tends to be small when the unchanging component occurs as the denominator against any arbitrary components (Test 1). In addition, the ratio of the component pair that gives the lowest coefficient of variation is most likely to represent the two unchanging components (Test 2). However, Tests 1 and 2 are not necessary and sufficient conditions for uniquely finding the unchanging component. To verify the effectiveness of the tests, 500 artificial datasets were analyzed and the results suggest that the tests are able to identify the unchanging component, although Test 1 underperforms when the dataset includes a component with skewness greater than 0.5, and Test 2 fails when the dataset includes components with a correlation coefficient greater than 0.75. These defects can be overcome by interpreting the two test results in a complementary manner. The proposed tests provide powerful yet simple criteria for identifying the unchanging component in compositional data; however, the reliability of this approach needs to be assessed in further studies.     

The stemflow of trees in a Bornean lowland tropical forest

Stemflow volume generation in lowland tropical forests was measured over a 1‐year period in the Malaysian state of Sarawak. The stemflow volume generated by 66 free‐standing trees with a diameter at breast height (DBH) over 1 cm and a tree height over 1 m were measured daily in a representative 10 m × 10 m plot of the forest. Throughfall in the plot was also measured using 20 gauges in a fixed position. Of the 2292 mm of total rainfall observed during the year‐long period, stemflow accounted for 3·5%, throughfall for 82% and there was an interception loss of 14·5%. Understory trees (DBH < 10 cm) played an important role in stemflow generation, producing 77% of the overall stemflow volume and 90% during storms with less than 20 mm of rainfall. Also, owing to their efficiency at funneling rainfall or throughfall water received by their crowns, some understory trees noticeably reduced the catches of the throughfall gauges situated under the reach of their crown areas. During storms producing greater than 20 mm of rainfall, 80% of the total stemflow occurred; trees with a large DBH or height and for which the ratio between crown's diameter and depth is less than 1, tended to generate more stemflow volume in these storms. Mean areal stemflow as a fraction of rainfall in this lowland tropical forest was 3·4%, but may range from 1–10% depending upon the proportion of trees that are high or poor stemflow yielders. Trees with DBH greater than 10 cm were likely to contribute less than 1% of the 3·4% mean areal stemflow in the forest. Copyright © 2004 John Wiley & Sons, Ltd.