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41.
42.
In this paper, we examine the distribution of incompatible elements in Earth’s mantle based on data reported for 20 mantle
xenoliths collected from 5 localities worldwide. A structural model combined with an element partitioning model forms the
basis for our analyses. The former separates a bulk peridotite into mineral crystal lattices, interfaces (grain and interphase
boundaries), and intra- and inter-granular inclusions as sites for incompatible elements. The latter relates the distribution
of elements among these sites based on lattice strain theory. By treating both intra- and inter-granular inclusions as a melt-like
phase, the combined models successfully reproduce the relative concentrations of incompatible elements among minerals, clean
rock (reconstituted from mineral compositions and mineral mode), and whole rock. The analyses reveal common signatures in
the rocks: (1) incompatible elements in the crystal lattices of olivine, orthopyroxene and clinopyroxene achieved chemical
equilibrium. (2) Olivine, orthopyroxene and clinopyroxene grains contain similar amounts of an intra-granular, melt-like component
possibly in the form of sub-micron inclusions with weight (≈volume) fractions between 5 × 10−5 and 1 × 10−2. (3) All rocks contain an inter-granular melt-like component with a fraction between 10−4 and 10−2, well above the amount expected to be stored along interfaces. (4) Fractions of the inter- and intra-granular components
are positively correlated, indicating that they were originated from the same process. (5) The inter- and intra-granular melt-like
phases are chemically equilibrated with other structural components. Based on plausible upwelling rates for mantle xenoliths,
it is unlikely that the melt-like component formed during ascent. Instead, its ubiquitous appearance, its invisibility to
optical microscopy, and its absorption of the incompatible elements in a manner similar to a melt phase even at sub-solidus
condition, all might be explained by the presence of amorphous silica precipitates such as those observed previously in naturally
occurring and experimentally annealed mantle composites. From the mineral mode, grain size, and mineral plus whole rock concentrations
of incompatible elements, we can ascribe the chemical signatures of xenoliths to achievement of chemical equilibrium at mantle
conditions rather than to a consequence of some disequilibrium (metasomatic) effect as has been done previously. Although
it should be tested by additional analytical studies, our model will make it possible to determine whether or not a rock is
chemically equilibrated in terms of the distribution of incompatible elements or if a metasomatic (disequilibrium) event is
required. 相似文献
43.
Use of flood chronology for detailed environmental analysis: a case study of Lake Kizaki in the northern Japanese Alps,central Japan 总被引:1,自引:1,他引:0
Takuma Ito Haruka Iwamoto Koichi Kamiya Takehiko Fukushima Fujio Kumon 《Environmental Earth Sciences》2010,60(8):1607-1618
This paper presents a study of the usefulness of flood layers as a time marker in sediments and a report of a case study of
Lake Kizaki in central Japan. A flood layer can be identified as a layer having a higher density, coarser grain size, lower
TN content, and higher C/N ratio than those of the upper and lower horizons. It can also be characterized by a hyperpycnal
sequence composed of a basal coarsening-upward unit and a top fining-upward unit. When flood layers can be correlated with
heavy rains in meteorological records, detailed age markers are well established in the sediment. Five flood layers were identified
in the surface sediment of Lake Kizaki, and they could be attributed to the historical heavy rainfalls that took place on
July 12, 1995; September 28, 1983; August 25, 1974; September 26, 1959; and September 1, 1949 under the constraint of an age
model. A precise age model is essential to clarify the environmental changes such as the pollutant history in detail. 相似文献
44.
Ken Niwa Takehiko Yagi Kenya Ohgushi Sébastien Merkel Nobuyoshi Miyajima Takumi Kikegawa 《Physics and Chemistry of Minerals》2007,34(9):679-686
Lattice preferred orientations (LPO) developed in perovskite and post-perovskite structured CaIrO3 were studied using the radial X-ray diffraction technique combined with a diamond anvil cell. Starting materials of each
phase were deformed from 0.1 MPa to 6 GPa at room temperature. Only weak LPO was formed in the perovskite phase, whereas strong
LPO was formed in the post-perovskite phase with an alignment of the (010) plane perpendicular to the compression axis. The
present result suggests that the (010) is a dominant slip plane in the post-perovskite phase and it is in good agreement with
the crystallographic prediction, dislocation observations via transmission electron microscopy, and a recent result of simple
shear deformation experiment at 1 GPa–1,173 K. However, the present result contrasts markedly from the results on MgGeO3 and (Mg,Fe)SiO3, which suggested that the (100) or (110) is a dominant slip plane with respect to the post-perovskite structure. Therefore
it is difficult to discuss the behavior of the post-perovskite phase in the Earth’s deep interior based on existing data of
MgGeO3, (Mg,Fe)SiO3 and CaIrO3. The possible sources of the differences between MgGeO3, (Mg,Fe)SiO3 and CaIrO3 are discussed. 相似文献
45.
Norimasa Nishiyama Takehiko Yagi Shigeaki Ono Hirotada Gotou Tatsuhiko Harada Takumi Kikegawa 《Physics and Chemistry of Minerals》2007,34(3):131-143
In situ X-ray diffraction measurements of Fe- and Al-bearing MgSiO3-rich perovskite (FeAl-Pv), which was synthesized from a natural orthopyroxene, were performed at pressures of 19–32 GPa and
temperatures of 300–1,500 K using a combination of a Kawai-type apparatus with eight sintered-diamond anvils and synchrotron
radiation. Two runs were performed using a high-pressure cell with two sample chambers, and both MgSiO3 perovskite (Mg-Pv) and FeAl-Pv were synthesized simultaneously in the same cell. Thus we were able to measure specific volumes
(V/V
0) of Mg-Pv and FeAl-Pv at the same P−T conditions. At all the measurement conditions, values of the specific volume of FeAl-Pv are consistent with those of Mg-Pv
within 2 Standard Deviation, strongly suggesting that effect of incorporation of iron and aluminum on the thermoelastic properties
of magnesium silicate perovskite is undetectable in this composition, pressure, and temperature range. Two additional runs
were performed using a high-pressure cell that has one sample chamber and unit-cell volumes of FeAl-Pv were measured at pressures
and temperatures up to 32 GPa and 1,500 K, respectively. All the unit-cell volume data of FeAl-Pv perovskite were fitted to
the high temperature Birch–Murnaghan equation of state and a complete set of thermoelastic parameters of this perovskite was
determined with an assumption of K′
300,0 = 4. The determined parameters are K
300,0 = 243(3) GPa, (∂K
T,0/∂T)
P
= −0.030(8) GPa/K, a
0 = 2.78(18) × 10−5 K−1, and b
0 = 0.88(28) × 10−8 K−2, where a
0 and b
0 are the coefficients of the following expression describing the zero-pressure thermal expansion: α
T,0 = a
0 + b
0
T. The equation-of-state parameters of FeAl-Pv are in good agreement with those of MgSiO3 perovskite at the conditions corresponding to the uppermost part of the lower mantle. 相似文献
46.
Takehiko Fukushima Je-chul Park Akio Imai Kazuo Matsushige 《Aquatic Sciences - Research Across Boundaries》1996,58(2):139-157
The seasonal and spatial changes in dissolved organic carbon (DOC) in Lake Kasumigaura, a shallow, eutrophic lake, were analyzed and the lability of DOC was tested by long-term incubations. There was a nearly 1 mgCl–1 downstream increase in refractory DOC in the lake; at the center it fluctuated little seasonally. The characteristic UV-absorbance: DOC ratios were determined for samples from the influent rivers (pedogenic: used interchangeably with allochthonous) and outdoor experimental ponds (autochthonous) during incubations. These ratios were then used to calculate the proportion of total measured lake water DOC in each of four components: pedogenic-refractory (PR), pedogenic-labile (PL), autochthonous-refractory (AR) and autochthonous-labile (AL). PR was uniform (around 1.5 mgCl–1) or diminished very slightly over time. AR increased from nearly zero at the station closest to an influent river to 1 mgCl–1 at the lake center. PL declined downstream from 0.3 mgCl–1 to zero. AL was virtually constant at 0.8 mgCl–1 except at the station closest to the influent river. The constancy of the UV-absorbance: DOC ratio during the biodegradation process was confirmed for Lake Kasumigaura; hence a two-component model (pedogenic-autochthonous) could be applied here without consideration of DOC lability. However, this assumption is not always met for other water bodies, and therefore it should be checked before applying a two-component model elsewhere. 相似文献
47.
A direct numerical approach to the Chandrasekhar'sH-functions for arbitrary characteristic functions
The purpose of this paper is to present a numerical technique to directly compute the Chandrasekhar'sH ()-function for anisotropic scattering in terms of the roots of the characteristic equations as well as the quadrature points of a certain degreen employed to approximate the definite integral involved in the basic equation. The principal feature of the algorithm proposed here is a compact computer code to enumerate
n
C
m
combinations ofn distinct integers {1,...,n} takenm at a time. With these quantities available, the coefficients of the polynomial equation of the characteristics equation can be readily computed for any given characteristic function, so that a standard technique such as the Laguerre method can be applied to find all the roots.It is shown that the results obtained for some representativeH()-functions using the present technique with relatively low-order formula (e.g.,n=7) are sufficiently accurate for all practical purposes. 相似文献
48.
In order to clarify the structure of the strong tidal current at the Naruto Strait in the Seto Inland Sea of Japan, the sea-level values were observed in the strait and the current measurements were made with an Acoustic Doppler Current Profiler (ADCP).The tidal volume transports for M2 and S2 tides were about 74×103 and 26×103 m3 sec–1, respectively. The horizontal profile of the velocity at the phase of the strong tidal current compares favorably with a theoretical profile of the two-dimensional steady turbulent jet except for the side parts of the profile. Moreover, the entrainment rate of the surrounding water into the strong tidal jet was estimated from the difference of mass flux between two cross-sections at the strait, the entrainment rate and entrainment constant for both the northward and southward flows being about 1.3–2.5×10–4m–1 and about 0.03–0.05, respectively. 相似文献
49.
Observations of sediment contamination along the coast of Japan were analyzed. When the pollutant concentration is divided by the fine particle fraction in the sediment, a regular pattern is observed in the quantitative relationship among the degree and the area of contamination and the discharge rate of pollutant released continuously into the water along the coast. This regularity was observed with respect to COD,n-hexane soluble substances and heavy metals, and could be expressed by a formula.Polluted particles were supposed to disperse through suspension in the bottom water layer, and thus their distribution in the surface sediment is expected to become similar to effluent dispersion in the surface water. 相似文献
50.
Masahiro Takenobu Masafumi Miyata Yu Otake Takehiko Sato 《Georisk: Assessment and Management of Risk for Engineered Systems and Geohazards》2019,13(3):195-204
ABSTRACTThe Partial Factor Method (PFM) based on the Level 1 reliability design method was introduced in 2007 to the Technical Standards for Port and Harbour Facilities (TSPHF-2007) in Japan. After nearly 10 years of practical use of TSPHF-2007, the design standard has been revised based on requests from the practitioners who recommend the transition from the PFM to the Load Resistance Factor Design (LRFD). In this paper, we discuss the setting method of the target failure probability to determine the partial factors based on code calibration. Furthermore, we examine the impacts of implementing the LRFD concept to the TSPHF by taking the sliding and overturning of a gravity type quay wall as an example to represent port and harbour facilities. We found no practical difference in caisson width derived using the LRFD and the PFM, whereas the degree of matching of the target failure probability was somewhat more precise for the PFM. This finding indicates that the LRFD is a more reasonable design method than the PFM in terms of the simplicity of the performance function itself and the ease of engineering interpretation during the design procedure. 相似文献