Molecular and isotopic partitioning of low-molecular-weight hydrocarbons during migration and gas hydrate precipitation in deposits of a high-flux seepage site

Detailed knowledge of the extent of post-genetic modifications affecting shallow submarine hydrocarbons fueled from the deep subsurface is fundamental for evaluating source and reservoir properties. We investigated gases from a submarine high-flux seepage site in the anoxic Eastern Black Sea in order to elucidate molecular and isotopic alterations of low-molecular-weight hydrocarbons (LMWHC) associated with upward migration through the sediment and precipitation of shallow gas hydrates. For this, near-surface sediment pressure cores and free gas venting from the seafloor were collected using autoclave technology at the Batumi seep area at 845 m water depth within the gas hydrate stability zone.Vent gas, gas from pressure core degassing, and from hydrate dissociation were strongly dominated by methane (> 99.85 mol.% of ∑[C₁–C₄, CO₂]). Molecular ratios of LMWHC (C₁/[C₂ + C₃] > 1000) and stable isotopic compositions of methane (δ¹³C = ? 53.5‰ V-PDB; D/H around ? 175‰ SMOW) indicated predominant microbial methane formation. C₁/C₂₊ ratios and stable isotopic compositions of LMWHC distinguished three gas types prevailing in the seepage area. Vent gas discharged into bottom waters was depleted in methane by > 0.03 mol.% (∑[C₁–C₄, CO₂]) relative to the other gas types and the virtual lack of ¹⁴C–CH₄ indicated a negligible input of methane from degradation of fresh organic matter. Of all gas types analyzed, vent gas was least affected by molecular fractionation, thus, its origin from the deep subsurface rather than from decomposing hydrates in near-surface sediments is likely.As a result of the anaerobic oxidation of methane, LMWHC in pressure cores in top sediments included smaller methane fractions [0.03 mol.% ∑(C₁–C₄, CO₂)] than gas released from pressure cores of more deeply buried sediments, where the fraction of methane was maximal due to its preferential incorporation in hydrate lattices. No indications for stable carbon isotopic fractionations of methane during hydrate crystallization from vent gas were found. Enrichments of ¹⁴C–CH₄ (1.4 pMC) in short cores relative to lower abundances (max. 0.6 pMC) in gas from long cores and gas hydrates substantiates recent methanogenesis utilizing modern organic matter deposited in top sediments of this high-flux hydrocarbon seep area.     

Scientific uncertainty and climate change: Part II. Uncertainty and mitigation

In public debate surrounding climate change, scientific uncertainty is often cited in connection with arguments against mitigative action. This article examines the role of uncertainty about future climate change in determining the likely success or failure of mitigative action. We show by Monte Carlo simulation that greater uncertainty translates into a greater likelihood that mitigation efforts will fail to limit global warming to a target (e.g., 2 °C). The effect of uncertainty can be reduced by limiting greenhouse gas emissions. Taken together with the fact that greater uncertainty also increases the potential damages arising from unabated emissions (Lewandowsky et al. 2014), any appeal to uncertainty implies a stronger, rather than weaker, need to cut greenhouse gas emissions than in the absence of uncertainty.     

A study of hybrid and chaotic long-range propagation in a doublesound channel environment

This paper presents the results of the analysis of long range propagation (~200 km) in a range-dependent environment. The propagation medium is characterized by two deep sound channels. The range dependence enables energy transfer between the channels and leads to a mismatch between real data and ray predictions. To explain this mismatch, an analysis of hybrid ray propagation is presented. This analysis is completed by an interpretation in terms of chaos. This chaos is quantified in the particular case of the Bay of Biscay environment. This paper puts forward that mesoscale perturbations, such as the Mediterranean outflow in the North Atlantic, can affect long-range propagation. However, it shows that the ray theory remains reliable for a propagation range of several hundred kilometers     

Response of precipitation over Greenland and the adjacent ocean to North Pacific warm spells during Dansgaard–Oeschger stadials

ABSTRACT Palaeoceanographic reconstructions from the North Atlantic indicate massive ice breakouts from East Greenland near the onset of cold Dansgaard–Oeschger (D–O) stadials. In contrast to these coolings in the North Atlantic area, a new sea-surface temperature record reveals concomitant warm spells in the northern North Pacific. A sensitivity experiment with an atmospheric general circulation model is used to test the potential impact of sea-surface warmings by 3.5 °C in the North Pacific, on top of otherwise cold stadial climate conditions, on the precipitation regime over the Northern Hemisphere ice sheets. The model predicts a maximum response over East Greenland and the Greenland Sea, where a 40% increase in net annual snow accumulation occurs. This remote effect of North Pacific warm spells on the East Greenland snow-accumulation rate may play an important role in generating D–O cycles by rebuilding the ice lost during ice breakouts. In addition, the increased precipitation over the Greenland Sea may help to sustain the D–O stadial climate state.     

Getting Lost in Cities: Spatial Patterns of Phonetically Confusing Street Names

A large street network is likely to contain duplicated or similar sounding street names. These conflicts can cause confusion in communication between people or in machine‐human interaction. Municipal authorities have begun to see the importance of uncovering these existing street name conflicts and mitigating future ones, for improved record keeping, emergency response, etc. However the commonly used Soundex phonetic algorithm is generally considered to produce poor similarity results in terms of uncovering street name conflicts. This study reports on a new fusion algorithm that combines phonetic methods and approximate string matching for street names, weighted by street type suffix (Avenue, Boulevard, Court, etc.), to quantitatively measure the collision/confusion potential presented by a pair of streets. This algorithm is then applied to the entire street network in Greater Melbourne, Australia, and the pattern of collisions at various spatial scales, and within municipalities, is mapped. The goal of this work is to produce better tools that can aid policy makers, administrators and industries dealing with location‐based services to make better decisions when assigning and disambiguating street names.     

Urban green commons: Insights on urban common property systems

The aim of this paper is to shed new light on urban common property systems. We deal with urban commons in relation to urban green-space management, referring to them as urban green commons. Applying a property-rights analytic perspective, we synthesize information on urban green commons from three case-study regions in Sweden, Germany, and South Africa, and elaborate on their role for biodiversity conservation in urban settings, with a focus on business sites. Cases cover both formally established types of urban green commons and bottom-up emerged community-managed habitats. As our review demonstrates, the right to actively manage urban green space is a key characteristic of urban green commons whether ownership to land is in the private, public, the club realm domain, or constitutes a hybrid of these. We discuss the important linkages among urban common property systems, social–ecological learning, and management of ecosystem services and biodiversity. Several benefits can be associated with urban green commons, such as a reduction of costs for ecosystem management and as designs for reconnecting city-inhabitants to the biosphere. The emergence of urban green commons appears closely linked to dealing with societal crises and for reorganizing cities; hence, they play a key role in transforming cities toward more socially and ecologically benign environments. While a range of political questions circumscribe the feasibility of urban green commons, we discuss their usefulness in management of different types of urban habitats, their political justification and limitation, their potential for improved biodiversity conservation, and conditions for their emergence. We conclude by postulating some general policy advice.     

小型激光天文动力学空间计划概念

小型激光天文动力学空间计划是 :使用在太阳轨道上无拖曳航天器和地面站以激光干涉和脉冲测距的方法 ,精确地探讨天文动力学 ,检测相对论与时空基本定律 ,改进探测引力波的灵敏度以及更准确地测定太阳、行星和小行星的参数。 1 969年开始的月球激光 (反射 )测距 ,对地球物理、参考坐标的选定、相对论的检验均有重要的贡献。 3 0年来 ,激光技术的长足进步 ,使现在正是适合于开始进行研究空间有源 (主动 )测距和光波空间通讯的时候。激光天文动力学的兴起是必然的趋势 ,其精确度将比现在提高 3到 6个数量级 ,将是天文动力学革命性的发展。小型激光天文动力学空间计划可以起到带头作用。它的关键技术有三 ,即 :弱光锁相、极精确无拖曳航天和高衰减日冕仪。弱光锁相已有长足的进步。对高衰减日冕仪的研究 ,也有了初步的方案。LISA空间计划将于 2 0 0 6年 8月发射SMART -2 ,研究测试极精确无拖曳航天。小型激光天文动力学空间计划的关键技术已日趋成熟。在第一届国际激光天文动力学研讨会 ( 2 0 0 1 ,9.1 3 -2 3 )中介绍了各相关学科背景及前沿研究 ,讨论了激光天文动力学空间计划科学目标及相关技术 ,并召开了两次小型激光天文动力学空间计划预研究筹备会 ,建立了和欧洲的合作关系。会后着手进行此项对基础     

The timing and nature of recession of outlet glaciers of Hielo Patagónico Norte, Chile, from their Neoglacial IV (Little Ice Age) maximum positions

The dates of recession of eleven outlet glaciers of the Hielo Patagónico Norte (Northern Patagonian Icefield) from their recent maximum positions have been inferred from dendrochronology, lichenometry, radiocarbon dating and historical sources. We have refined the dating for part of the Little Ice Age period in this area placing a glacial advance to between AD 1650 and 1766 with the latter date favoured as conformable with historical records and an uncalibrated radiocarbon determination. Glacier recession from maximal positions began in the early 1860s–1870s. Recession was largely synchronous on the western and eastern sides of the Icefield. This synchronicity suggests that climate forcing over-rides second-order controls on glacier behaviour such as the nature of the terminal environment (e.g. calving/non-calving) or differences in glacier drainage basin area. We argue that this icefield-wide glacier recession represents a response to post-Little Ice Age warming, and provides further evidence for the global extent and near synchronous termination of the Little Ice Age.