Comparison of approaches for the characterization of contamination at rural megasites

The present work focuses on approaches for the characterization of subsurface contamination, which need to be reliable and cost-effective, particularly for extended and remote areas aimed at being redeveloped. Requirements are discussed with respect to specific conditions at megasites, in order to enable site valorization. In a case study, two approaches are compared, comprising (1) conventional site investigation based on historical surveys and concentration measurements at monitoring wells installed in areas suspected of being polluted and (2) the use of direct push (DP) methods covering the complete area. The DP investigation provided information on the contamination distribution and yielded also important information on hydraulic conditions. Statistical analysis of the results applying indicator kriging revealed that the conventional approach is markedly risky when decision-making relies solely on historical and sparse data. The DP campaign remarkably reduced the uncertainty concerning the estimated occurrence of polluted groundwater at the whole site. Furthermore, monitoring measurements are analyzed showing the possible importance of temporal variability. Taking economical consideration into account, DP-based groundwater screening is recommended to obtain either first or complementary information on the entire site. Based on these data, also locations for a long-term monitoring could be selected if temporal variability is assumed relevant.     

Testing different sorting techniques in macroinvertebrate samples from running waters

With the aim of finding an efficient, standardised and practical protocol for sorting macroinvertebrate samples for water management practice, three different sorting techniques were tested: RIVPACS sorting, a modified AQEM/STAR (MAS) sorting protocol and a Live-sorting method. Based on the same AQEM/STAR sample to ensure comparable results, we compared RIVPACS and MAS sorting for 20 samples, and Live-sorting and MAS for a different set of 20 samples. Comparisons were based on both ecological and financial parameters relevant for the implementation of the EU Water Framework Directive in Germany. Parameters include recently developed multimetric assessment indices, their stream type specific core metric results, time effort and costs. While RIVPACS and MAS sorting produced similar results in terms of ecological assessment, time effort and costs, Live-sorting differed notably in all three respects. Live-sorting is the quickest and least expensive protocol, but shows higher variability than the other protocols. We discuss the differences and the level of standardisation for each of these methods.     

OSL quartz age underestimation due to unstable signal components

When measuring samples from southern Peru, we discovered an age offset between feldspar infrared-stimulated luminescence (IRSL) and quartz optically stimulated luminescence (OSL) ages. This age offset was not only found in these particular samples but was also observed in samples from a range of geographical localities. Extensive analysis revealed that it is actually the quartz age that underestimates the true depositional age, and this is due to a very weak fast component combined with other thermally unstable OSL signal components. We discuss properties of these poorly behaving samples and how to detect such samples prior to the OSL single-aliquot regenerative-dose (SAR) measurement. Finally, existing approaches to improve equivalent dose (D_e) determination are discussed for samples from southern Peru.     

Satellite-based terrestrial production efficiency modeling

Production efficiency models (PEMs) are based on the theory of light use efficiency (LUE) which states that a relatively constant relationship exists between photosynthetic carbon uptake and radiation receipt at the canopy level. Challenges remain however in the application of the PEM methodology to global net primary productivity (NPP) monitoring. The objectives of this review are as follows: 1) to describe the general functioning of six PEMs (CASA; GLO-PEM; TURC; C-Fix; MOD17; and BEAMS) identified in the literature; 2) to review each model to determine potential improvements to the general PEM methodology; 3) to review the related literature on satellite-based gross primary productivity (GPP) and NPP modeling for additional possibilities for improvement; and 4) based on this review, propose items for coordinated research.     

Forward model nonlinearity versus inverse model nonlinearity

The issue of concern is the impact of forward model nonlinearity on the nonlinearity of the inverse model. The question posed is, “Does increased nonlinearity in the head solution (forward model) always result in increased nonlinearity in the inverse solution (estimation of hydraulic conductivity)?” It is shown that the two nonlinearities are separate, and it is not universally true that increased forward model nonlinearity increases inverse model nonlinearity.     

Structural control of low-sulfidation epithermal gold mineralization in the Rosario–Bunawan district, East Mindanao Ridge, Philippines

The Rosario–Bunawan district is situated about 200 km north of Davao City, the capital of the Mindanao Island, Southern Philippines. Gold is produced from the Co-O mine, containing about 2,034,000 t of ore at 10.9 g/t Au, and in numerous small-scale operations by local miners. Epithermal gold mineralization in the Rosario–Bunawan district and the Co-O mine is confined to narrow (0.2–4 m) low-sulfidation quartz–chalcedony–calcite veins in volcanic and volcaniclastic wall rocks. Three major vein orientations are distinguished: (1) the NNW–SSE-trending set with a sinistral strike-slip sense of deformation (Philippine Fault trend); (2) the ENE–WSW-trending dextral strike-slip set (Palawan trend) and associated veins in the Riedel geometry; and (3) the WNW–ESE-trending conjugate set (Co-O trend). Three structural stages are defined: (1) extensional shear or shear veins formed in the Co-O, the Philippine Fault, and Palawan trends during regional NW–SE compression and near vertical vein opening (D₁); (2) reactivation of veins in the Philippine Fault, veins associated with the Palawan, and, to a lesser extent, the Co-O trends during E–W compression and near horizontal N–S-oriented vein opening (D₂). New D₂ extensional shear or shear veins formed in the Philippine Fault, and structures associated with the Palawan and associated Riedel trends; (3) the D₃-stage block faulting subsequently displaced all of the auriferous veins. The auriferous Rosario–Bunawan district is situated between two splays of the Philippine Fault, which acted as a lateral ramp system during the oblique convergence of the Philippine Sea plate and the Eurasian plate. The oblique convergence resulted in a change from a compressional (D₁) to a transpressional (D₂) regime, which was a prerequisite for the two-stage vein opening and hydrothermal mineralization, leading to an economic gold enrichment. D₁ compressional tectonics may have caused an elevated geothermal gradient in shallow crustal levels, forming the heat source for the fluid plumbing system, which is at variance to typical epithermal deposits formed in extensional zones. D₂ thrusting of a limestone nappe together with syn-tectonic diorite intrusions may have further increased the geothermal gradient, maintaining the fluid plumbing system. The limestone nappe may, at the same time, have represented an aquitard forcing the hydrothermal fluids into the volcanic and volcaniclastic wall rocks, which is regarded as critical for the two-stage gold mineralization in the Rosario–Bunawan district.     

A Lateglacial and Holocene lake record from the Nianbaoyeze Mountains and inferences of lake, glacier and climate evolution on the eastern Tibetan Plateau

Our 12.81 m long record from Lake Ximencuo provides insight into the Lateglacial and Holocene evolution of the lake and the Nianbaoyeze glacier in its catchment, and the regional climate history since 19 kyr. Lake Ximencuo was a permanent deep lake throughout its history. In contrast to numerous lakes on the Tibetan Plateau which experienced shallow lake levels or even desiccation during the Lateglacial, Lake Ximencuo was fed by large quantities of meltwater in the Lateglacial. The existence of glaciated upper catchment areas is apparently a prerequisite for lakes on the Tibetan Plateau which maintained relatively high water levels during the generally cold and dry periods following the global LGM (21 kyr). A minor re-advance of the Nianbaoyeze glacier was recorded coeval with the Greenland Stadial 2a (16.4 and 14.5 kyr), followed by rapid warming apparently synchronous with the Greenland Interstadial 1. Warmest conditions were recorded at Lake Ximencuo during the early Holocene which was punctured by a remarkable pulse of climate deterioration around 8.3 kyr. This spell represents probably the 8.2 kyr event of the North Atlantic region, suggesting that it had a significant impact on the Tibetan Plateau. Colder conditions of longer duration occurred from 4.7 to 3.7 kyr, apparently in phase with numerous records signalling colder and drier conditions on the Tibetan Plateau. Two minor spells of colder conditions and probably catchment erosion were recorded in the late Holocene between 2.0 and 1.4 kyr and between 0.5 and 0.1 kyr with the latter representing the Little Ice Age. It is unclear, whether human activities may have accelerated or even solely triggered the late Holocene erosion events.