Late Quaternary tephrochronology of Sweden: a review

Studies of Late Quaternary sediments in south and central Sweden have yielded a detailed tephrochronology for the Last Glacial–Interglacial transition (LGIT; ca. 15,000–10,000 cal. yr BP) and the Holocene. More than ten tephra layers have been detected and geochemically characterised. The most widespread tephra from the LGIT is the rhyolitic phase of the Vedde Ash (ca. 12,000 cal. yr BP) which has been found in lacustrine sediments and marine clays south of the Younger Dryas moraines in south Sweden. Other horizons from the LGIT identified to date include the Borrobol tephra (ca. 14,400 cal. yr BP), the Hässeldalen tephra (ca. 11,500 cal. yr BP), the 10-ka Askja tephra (ca. 11,300 cal. yr BP) and the Högstorpsmossen tephra (ca. 10,200 cal. yr BP). The most significant Holocene isochrones are Hekla-4 (ca. 4260 cal. yr BP), Hekla-Selsund/Kebister (ca. 3750 cal. yr BP), Hekla-3 (ca. 3000 cal. yr BP) and Askja-1875. Two new Late Holocene tephra horizons (the Stömyren tephra, ca. 2100 cal. yr BP and the Gullbergby tephra; ca. 2700 cal. yr BP) were identified in single sites and are so far less valuable as marker horizons, but are potentially important for the future.     

Earthquakes in Switzerland and surrounding regions during 2004

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2004. During this period, 677 earthquakes and 96 quarry blasts were detected and located in the region under consideration. With 22 events with M_L≥2.5, the seismic activity in the year 2004 was close to the average over the last 30 years. As in previous years, most of the activity was concentrated in the Valais and in Graubünden. In addition, several moderate earthquakes occurred in the lower crust below the northern Alpine foreland. Unusual was that five earthquakes were sufficiently strong to cause ground shaking of intensity IV over large portions of the territory. Two were located in Switzerland (Liestal, M_L 3.8, and Brugg, M_L 4.0). The epicenters of the other three strong events were located outside Switzerland (Besan?on in the French Jura, M_L 4.8, Waldkirch in southern Germany, M_L 5.1, and Lago di Garda in northern Italy, M_L 5.3).     

Simulated changes in vegetation distribution, land carbon storage, and atmospheric CO2 in response to a collapse of the North Atlantic thermohaline circulation

It is investigated how abrupt changes in the North Atlantic (NA) thermohaline circulation (THC) affect the terrestrial carbon cycle. The Lund–Potsdam–Jena Dynamic Global Vegetation Model is forced with climate perturbations from glacial freshwater experiments with the ECBILT-CLIO ocean–atmosphere–sea ice model. A reorganisation of the marine carbon cycle is not addressed. Modelled NA THC collapses and recovers after about a millennium in response to prescribed freshwater forcing. The initial cooling of several Kelvin over Eurasia causes a reduction of extant boreal and temperate forests and a decrease in carbon storage in high northern latitudes, whereas improved growing conditions and slower soil decomposition rates lead to enhanced storage in mid-latitudes. The magnitude and evolution of global terrestrial carbon storage in response to abrupt THC changes depends sensitively on the initial climate conditions. These were varied using results from time slice simulations with the Hadley Centre model HadSM3 for different periods over the past 21 kyr. Changes in terrestrial storage vary between −67 and +50 PgC for the range of experiments with different initial conditions. Simulated peak-to-peak differences in atmospheric CO₂ are 6 and 13 ppmv for glacial and late Holocene conditions. Simulated changes in δ¹³C are between 0.15 and 0.25‰. These simulated carbon storage anomalies during a NA THC collapse depend on their magnitude on the CO₂ fertilisation feedback mechanism. The CO₂ changes simulated for glacial conditions are compatible with available evidence from marine studies and the ice core CO₂ record. The latter shows multi-millennial CO₂ variations of up to 20 ppmv broadly in parallel with the Antarctic warm events A1 to A4 in the South and cooling in the North.     

Sensitivity analyses of a distributed catchment model to verify the model structure

Sensitivity analyses are valuable tools for identifying important model parameters, testing the model conceptualization, and improving the model structure. They help to apply the model efficiently and to enable a focussed planning of future research and field measurement. Two different methods were used for sensitivity analyses of the complex process-oriented model TAC^D (tracer aided catchment model, distributed) that was applied to the meso-scale Brugga basin (40 km²) and the sub-basin St Wilhelmer Talbach (15.2 km²). Five simulations periods were investigated: two summer events, two snow melt induced events and one summer low flow period. The model was applied using 400 different parameter sets, which were generated by Monte Carlo simulations using latin hypercube sampling. The regional sensitivity analysis (RSA) allowed determining the most significant parameters for the complete simulation periods using a graphical method. The results of the regression-based sensitivity analysis were more detailed and complex. The temporal variability of the simulation sensitivity could be observed continuously and the significance of the parameters could be determined in a quantitative way. A dependency of the simulation sensitivity on initial- and boundary conditions and the temporal and spatial variability of the sensitivity to some model parameters was revealed by the regression-based sensitivity analysis. Thus, the difficulty of transferring the results to different time periods or model applications in other catchments became obvious. The analysis of the temporal course of the simulation sensitivity to parameter values in conjunction with simulated and measured additional data sets (precipitation, temperature, reservoir volumes etc.) gave further insight into the internal model behaviour and demonstrated the plausibility of the model structure and process conceptionalizations.     

Palaeolimnology of Lake Zeribar, Iran, and its climatic implications

Lake Zeribar sediments covering the time period of the last 25,000 years were examined for the contents of seeds, fruits, Characeae, diatoms, and molluscs. Reconstructions of the variations in the lake water level, salinity, and trophy suggest a sequence of climatic changes. Three pronounced stages of low and varying lake-water level occurred ca. 17,700–15,400, 12,600–12,000, and 10,000–6000 cal yr BP. Some water-level changes were correlated with variations in salinity. The most pronounced increase of salinity occurred 17,700–15,700 and 12,600–12,000 cal yr BP, and less distinct ones occurred about 6400–5900 and 2500 cal yr BP. Diatom assemblages indicated a strong increase of lake trophy ca. 20,200 cal yr BP. Between 6000 and 5000 cal yr BP diatoms characteristic of eutrophy increased in core 63J, and at about 3200 cal yr BP a distinct increase in mesotrophic forms occurred in core 70B. The changes in the occurrence of various organisms indicate increased temperatures about 21,000 cal yr BP, between 15,400 and 12,600, about 12,000, and about 11,700 cal yr BP. The reduced occurrence or disappearance of some of them suggest temperature decreases about 17,700–15,400 and 12,600–12,000 cal yr BP.     

Rare earth element partitioning between titanite and silicate melts: Henry’s law revisited

We present detailed experimental results on the partitioning of rare earth elements (REE) between titanite and a range of different silicate melts. Our results show that Henry’s law of trace element partitioning depends on bulk composition, the available partners for heterovalent substitution, crystal composition, and melt composition. We illustrate that the partition coefficients for Sm depend very strongly on the bulk concentration of Sm in the system. The substitution mechanism, by which rare earth elements are incorporated into the crystal structure, plays an important role for trace element partitioning and also for the onset of Henry’s law. Our data show that there are clear differences between substitution mechanisms of major elements compared to elements which are present only as traces. Our experiments also clearly show that the onset of Henry’s law depends on the concentrations of the sum of all trace elements which are incorporated into the crystal by the same substitution mechanism. For geochemical modelling of magmatic processes involving titanite, and indeed other accessory phases, it is of crucial importance to first evaluate whether the REE, and other trace elements, are present as traces or as major elements, only then appropriate D values may be chosen.     

Impact of mechanical anisotropy and power-law rheology on single layer folding

The infinitesimal and finite stages of folding in nonlinear viscous material with a layer-parallel anisotropy were investigated using numerical and analytical methods. Anisotropy was found to have a first-order effect on growth rate and wavelength selection, and these effects are already important for anisotropy values (normal viscosity/shear viscosity) < 10. The effect of anisotropy must therefore be considered when deducing viscosity contrasts from wavelength to thickness ratios of natural folds. Growth rates of single layer folds were found to increase and subsequently decrease during progressive deformation. This is due to interference between the single layer folds and chevron folds that form in the matrix as a result of instability caused by the anisotropic material behaviour. The wavelength of the chevron folds in the matrix is determined by the wavelength of the folded single layer, which can explain the high wavelength to thickness ratios that are sometimes found in multilayer sequences. Numerical models including anisotropic material properties allow the behaviour of multilayer sequences to be investigated without the need for resolution on the scale of individual layers. This is particularly important for large-scale models of layered lithosphere.     

Mineralogical and geochemical patterns of urban surface soils, the example of Pforzheim, Germany

This study presents a combined geochemical and mineralogical survey of urban surface soils. Many studies on urban soils are restricted to purely chemical surveys in order to investigate soil pollution caused by anthropogenic activities such as traffic, heating, industrial processing, waste disposal and many more. In environmental studies, chemical elements are often distinguished as lithogenic and anthropogenic elements. As a novel contribution to those studies, the authors combined the analysis of a broad set of chemical elements with the analysis of the main mineralogical phases. The semi-quantification of mineralogical phases supported the assignment of groups of chemical elements to lithogenic or anthropogenic origin. Minerals are important sinks for toxic elements. Thus, knowledge about their distribution in soils is crucial for the assessment of the environmental hazards due to pollution of urban soils. In Pforzheim, surface soils (0–5 cm depth) from various land use types (forest, agriculture, urban green space, settlement areas of various site densities) overlying different geological units (clastic and chemical sediments) were investigated. Urban surface soils of Pforzheim reflect to a considerable degree the mineral and chemical composition of parent rocks. Irrespective of the parent rocks, elevated concentrations of heavy metals (Zn, Cu, Pb, Sn, Ag) were found in soils throughout the whole inner urban settlement area of Pforzheim indicating pollution. These pollutants will tend to accumulate in inner urban surface soils according to the available adsorption capacity, which is normally higher in soils overlying limestone than in soils overlying sandstone. However, inner urban surface soils overlying sandstone show elevated concentrations of carbonates, phyllo-silicates and Fe and elevated pH values compared with forest soils overlying sandstone. Thus, in comparison to forest soils overlying sandstones, inner urban soils overlying sandstone affected by pollution concurrently possess elevated concentrations of mineral phases typically providing relatively high adsorption capacities for heavy metals.     

Multi-stage thrusting at the "Penninic Front" in the Western Alps between Mont Blanc and Pelvoux massifs

The different segments of the tectonic boundary between external (European) and internal (Penninic) units in the Western Alps, the so-called Penninic Front (PF), formed at different times and according to different kinematic scenarios. During a first episode (Eocene), the PF corresponds to a transpressive suture zone between Penninic and European units. North- to NNW-trending stretching lineations, found along internal nappe contacts within the Penninic units, are related to this episode. This subduction zone was sealed by the Priabonian flysch of the Aiguilles d'Arves, a detrital trench formation that formed during the final stages of subduction. During a second episode, starting in mid-Oligocene times, the PF, imaged along the ECORS-CROP profile, acted as a WNW-directed thrust. This thrust, the Roselend Thrust (RT), only partially coincides with the PF. South of Moûtiers, the RT propagates into the Dauphinois units, carrying the former Eocene PF (including the Priabonian flysch) passively in its hangingwall. South of the Pelvoux massif the RT finds its continuation along the "Briançonnais Front", an out-of-sequence thrust behind the Embrunais-Ubaye nappes. On a larger scale, our findings indicate oblique (sinistral) collision within the future Western Alps during the Eocene, followed by westward indentation of the Adriatic block.