We document compositions of minerals and melts from 3 GPa partialmelting experiments on two carbonate-bearing natural lherzolitebulk compositions (PERC: MixKLB-1 + 2·5 wt% CO
2; PERC3:MixKLB-1 + 1 wt% CO
2) and discuss the compositions of partialmelts in relation to the genesis of alkalic to highly alkalicocean island basalts (OIB). Near-solidus (PERC: 1075–1105°C;PERC3: 1050°C) carbonatitic partial melts with <10 wt%SiO
2 and 40 wt% CO
2 evolve continuously to carbonated silicatemelts with >25 wt% SiO
2 and <25 wt% CO
2 between 1325 and1350°C in the presence of residual olivine, orthopyroxene,clinopyroxene, and garnet. The first appearance of CO
2-bearingsilicate melt at 3 GPa is 150°C cooler than the solidusof CO
2-free peridotite. The compositions of carbonated silicatepartial melts between 1350 and 1600°C vary in the rangeof 28–46 wt% SiO
2, 1·6–0·5 wt% TiO
2,12–10 wt% FeO*, and 19–29 wt% MgO for PERC, and42–48 wt% SiO
2, 1·9–0·5 wt% TiO
2,10·5–8·4 wt% FeO*, and 15–26 wt% MgOfor PERC3. The CaO/Al
2O
3 weight ratio of silicate melts rangesfrom 2·7 to 1·1 for PERC and from 1·7 to1·0 for PERC3. The SiO
2 contents of carbonated silicatemelts in equilibrium with residual peridotite diminish significantlywith increasing dissolved CO
2 in the melt, whereas the CaO contentsincrease markedly. Equilibrium constants for Fe*–Mg exchangebetween carbonated silicate liquid and olivine span a rangesimilar to those for CO
2-free liquids at 3 GPa, but diminishslightly with increasing dissolved CO
2 in the melt. The carbonatedsilicate partial melts of PERC3 at <20% melting and partialmelts of PERC at 15–33% melting have SiO
2 and Al
2O
3 contents,and CaO/Al
2O
3 values, similar to those of melilititic to basaniticalkali OIB, but compared with the natural lavas they are moreenriched in CaO and they lack the strong enrichments in TiO
2characteristic of highly alkalic OIB. If a primitive mantlesource is assumed, the TiO
2 contents of alkalic OIB, combinedwith bulk peridotite/melt partition coefficients of TiO
2 determinedin this study and in volatile-free studies of peridotite partialmelting, can be used to estimate that melilitites, nephelinites,and basanites from oceanic islands are produced from 0–6%partial melting. The SiO
2 and CaO contents of such small-degreepartial melts of peridotite with small amounts of total CO
2can be estimated from the SiO
2–CO
2 and CaO–CO
2 correlationsobserved in our higher-degree partial melting experiments. Thesesuggest that many compositional features of highly alkalic OIBmay be produced by 1–5% partial melting of a fertile peridotitesource with 0·1–0·25 wt% CO
2. Owing to verydeep solidi of carbonated mantle lithologies, generation ofcarbonated silicate melts in OIB source regions probably happensby reaction between peridotite and/or eclogite and migratingcarbonatitic melts produced at greater depths. KEY WORDS:
alkali basalts; carbonated peridotite; experimental petrology; ocean island basalts; partial melting 相似文献