Hydrogeochemical evaluation and statistical analysis of groundwater of Sylhet,north-eastern Bangladesh

To investigate the hydrogeochemical characteristics of groundwater 23 shallow, 30 intermediate and 38 deep wells samples were collected from Sylhet district of Bangladesh, and analyzed for temperature, pH, Eh, EC,DO, DOC, Na^+, K^+, Ca²⁺, Mg²⁺, Cl^-, SO_4^2-, NO_3^-,HCO_3^-, SiO_2^-, Fe, Mn and As. Besides, 12 surface water samples from Surma and Kushiyara Rivers were also collected and analyzed to understand the influence into aquifers. Results revealed that, most of the groundwater samples are acidic in nature, and Na–HCO_3 is the dominant groundwater type. The mean value of temperature, EC,Na^+, K^+, Ca²⁺, Mg²⁺, Cl^-, NO_3^- and SO_4^2- were found within the range of permissible limits, while most of the samples exceeds the allowable limits of Fe, Mn and As concentrations. However, relatively higher concentration of Fe and Mn were found in deep water samples and reverse trend was found in case of As. The mean concentrations of As in shallow, intermediate and deep wells were 39.3, 25.3and 21.4 lg/L respectively, which varied from 0.03 to148 lg/L. From spatial distribution, it was found that Fe,Mn and As concentrations are high but patchy in northern,north-western, and south-western part of Sylhet region. The most influential geochemical process in study area were identified as silicate weathering, characterized by active cation exchange process and carbonate weathering, which thereby can enhance the elemental concentrations in groundwater. Pearson's correlation matrix, principal component analysis and cluster analysis were also employed to evaluate the controlling factors, and it was found that, both natural and anthropogenic sources were influencing the groundwater chemistry of the aquifers. However, surface water has no significant role to contaminate the aquifers,rather geogenic factors affecting the trace elemental contamination. Thus it is expected that, outcomes of this study will provide useful insights for future groundwater monitoring and management of the study area.     

Assessing Carbon Stock and Sequestration of the Tropical Seagrass Meadows in Indonesia

Ocean Science Journal - Seagrass meadows provide critical ecosystem services for coastal areas, e.g., as nursery habitats for various fish species, help with water filtration of suspended sediment,...     

Chemical and oxygen isotopic properties of ordinary chondrites (H5, L6) from Oman: Signs of isotopic equilibrium during thermal metamorphism

Mean bulk chemical data of recently found H5 and L6 ordinary chondrites from the deserts of Oman generally reflect isochemical features which are consistent with the progressive thermal metamorphism of a common, unequilibrated starting material. Relative differences in abundances range from 0.5–10% in REE (Eu = 14%), 6–13% in siderophile elements (Co = 48%), and >10% in lithophile elements (exceptions are Ba, Sr, Zr, Hf, U = >30%) between H5 and L6 groups. These differences may have accounted for variable temperature conditions during metamorphism on their parent bodies. The CI/Mg‐normalized mean abundances of refractory lithophile elements (Al, Ca, Sm, Yb, Lu, V) show no resolvable differences between H5 and L6 suggesting that both groups have experienced the same fractionation. The REE diagram shows subtle enrichment in LREE with a flat HREE pattern. Furthermore, overall mean REE abundances are ~0.6 × CI with enriched La abundance (~0.9 × CI) in both groups. Precise oxygen isotope compositions demonstrate the attainment of isotopic equilibrium by progressive thermal metamorphism following a mass‐dependent isotope fractionation trend. Both groups show a ~slope‐1/2 line on a three‐isotope plot with subtle negative deviation in ?¹⁷O associated with δ¹⁸O enrichment relative to δ¹⁷O. These deviations are interpreted as the result of liberation of water from phyllosilicates and evaporation of a fraction of the water during thermal metamorphism. The resultant isotope fractionations caused by the water loss are analogous to those occurring between silicate melt and gas phase during CAI and chondrule formation in chondrites and are controlled by cooling rates and exchange efficiency.     

Petrography and geochemistry of lunar meteorites Dhofar 1673, 1983, and 1984

The Dhofar 1673, Dhofar 1983, and Dhofar 1984 meteorites are three lunar regolith breccias classified based on their petrography, mineralogy, oxygen isotopes, and bulk chemistry. All three meteorites are dominated by feldspathic lithic clasts; however, impact melt rock clasts and spherules are also found in each meteorite. The bulk chemistry of these samples is similar to other feldspathic highland meteorites with the Al₂O₃ content only slightly lower than average. Within the lithic clasts, the Mg # of mafic phases versus the anorthite content of feldspars is similar to other highland meteorites and is found to plot intermediate of the ferroan‐anorthositic suite and magnesian suite. The samples lack any KREEPy signature and have only minor indications of a mare basalt component, suggesting that the source region of all three meteorites would have been distal from the Procellarum KREEP Terrane and could have possibly been the Feldspathic Highland Terrane. All three meteorites were found within 500 m of each other in the Dhofar region of Oman. This, together with their similar petrography, stable isotope chemistry, and geochemistry indicates the possibility of a pairing.     

Observation of temperature and velocity in the coastal water off Kuala Terengganu,Malaysia

Mooring observation of current and temperature was made at 17.8 m layer of 19 m depth about 8 km east to Kuala Terengganu, Peninsular Malaysia. Harmonic analysis was applied to tidal currents for 30 days in September 1993, and to the tides observed at Chendering. The K1 tide was the largest both in tidal currents and the tides. Daily mean temperature, currents, sea level, and winds were analyzed from September 1993 to May 1994. Northeast Monsoon from December to February caused sea level rise of 50 cm and temperature lowering of 1°C.     

Fluid dynamics model for salt-dome evolution

A fluid dynamics model for the evolution of salt domes and ridges is presented. The model assumes a rigid substrate, finite thickness of both strata with no slip and a rigid or free surface of overburden. Inertial terms in the Navier-Stokes equations are neglected due to the large viscosities considered and the initial perturbation is taken to be sinusoidal. Finite sine and cosine transforms are used to solve the flow equations and the resulting systems of equations reproduce the velocity field equation of Ramberg's model. Assuming an initial interface, the infinite series solution is truncated to obtain the constants of the integration from the boundary conditions. The interface is then moved to a new position. Thus, the new shape for the interface can be traced for any time.For small perturbations, we obtain results that are approximately those obtained by the linear theory. Results of the numerical solution of the model for both large and small perturbations are presented.     

Modeling the heat development in hydrating CPB structures

Cemented paste backfill (CPB) is a mixture of dewatered tailings, hydraulic binders and water. In addition to contributing to the stability of mine workplaces, CPB greatly benefits the environment by minimizing surface tailings disposal. Hence, it has become one of the most commonly used ways in mine backfilling around the world. Temperature can significantly affect the mechanical properties of cemented backfill. A source of heat in CPB is produced by binder hydration. Hence, a FLAC based numerical model is developed to predict and analyse the heat developed by hydrating CPB structures. To validate the model, results of the developed model are compared with three case studies (mathematical, laboratory, and field investigations). The validation results show a good agreement between the developed model and these cases. The effects of stope geometry, thermal properties of both rock and CPB, filling rate, binder content and initial boundary conditions are also investigated.     

Copper(II) Biosorption on Soda Lignin From Oil Palm Empty Fruit Bunches (EFB)

The adsorption of Cu(II) ions from aqueous solutions by soda lignin as an absorbent using a batch adsorption system is presented in this paper. The soda lignin used in this study was extracted from black liquor derived from oil palm empty fruit bunches (EFB) using 20% v/v sulfuric acid. The effects of varying experimental parameters such as pH value, adsorbent dosage, different concentrations of Cu(II) ions, and agitation period were investigated. The results revealed that the optimum adsorption of Cu(II) onto soda lignin was recorded at a pH of 5.0 at an adsorbent dosage of 0.5 g soda lignin and an agitation period of 40 min. The adsorption capacities and rates of Cu(II) ions onto soda lignin was evaluated. The Langmuir and Freundlich adsorption models were applied to calculate the isotherm constants. It was found that the adsorption isothermal data could be well interpreted by the Freundlich model. The kinetic experimental data properly correlated with the pseudo‐second‐order kinetic model, which implies that chemical sorption is the rate‐limiting step.     

Determination of aquifer geometry through geophysical methods: A case study from Quetta Valley, Pakistan

Due to increase in population and agricultural activities, the aquifer of Quetta Valley is under tremendous stress and the water table is declining at an increasing rate. This situation necessitates evaluation of the aquifer system, for which information about geometry of the aquifer is a prerequisite. However, there are no drilling-to-bedrock data available; therefore, electrical resistivity, seismic reflection and gravity methods were employed to determine geometry of the aquifer. Interpretation of vertical electrical soundings provided information about the depth-tobedrock at some specific points, whereas seismic reflection delineated bedrock topography along two lines. The depths to bedrock inferred from electrical resistivity and seismic reflection data were used as constraints in the modeling of gravity data. 2.75D gravity models were constructed along lines with a regular spacing. Map of depth-to-bedrock was prepared by contouring the depth given by the gravity models. Combination of these geophysical methods depicted the geometry of the aquifer. This example shows that in a similar geological setting proper integration of geophysical exploration methods can determine the aquifer geometry with an acceptable reliability and at an appropriate cost.     

Free Amino Acids Content in Some Halophytes under Salinity Stress in Arid Environment,Jordan

The variation in free amino acids concentration was examined in halophytes under salt stress conditions during spring and autumn in an arid environment, Jordan. The experiment was conducted in the southern region of the Jordan valley, using four different halophytes namely: Atriplex halimus, Atriplex nummularia, Tamarix aphylla L., and Portulaca oleracea L. Free amino acid concentrations showed changeable patterns under salinity stress conditions compared to the non‐stress (control) with respect to plant species and seasonal variation. In general, the amino acid pool during the spring experienced increases in A. halimus with increasing salinity; and decreased in A. nummularia, P. oleracea L., and T. aphylla L., respectively. Whereas, during the autumn, the overall amino acids decreased in A. halimus and A. nummularia, and increased in T. aphylla L. and P. oleracea with increasing salinity. The amino acid pool concentrations of A. halimus L. during the autumn was similar to that in spring under stress condition. Similarly, T. aphylla L. and P. oleracea showed higher rates in the autumn. In contrast, A. nummularia L. exhibited a slight increase in amino acid composition in the autumn under stress conditions. The plantation of salt tolerant plants such as halophytes in saline sodic soils showed an effective decline in soil salinity and can be recommended to be used as a bioreclamation method instead of the traditional leaching method, which requires large amount of fresh water.