A kinematic evolutionary model for the Penninic sector of the central Ligurian Alps

The nappe pile presently cropping out in the central sector of the Ligurian Alps, is represented by some principal groups of tectonic units. Starting from the foreland, the outer and lower, weakly metamorphic (up to 0.3 GPa) Briançonnais units support the high-pressure (up to 1.3 GPa) ensemble of inner Briançonnais nappes, in turn overridden by the Prepiedmont units, sourced from the European continental margin. Prepiedmont units form two superposed groups. The lower is composed only of a pre-Namurian basement (Alpine metamorphism up to 0.6 GPa); and the upper is mainly composed of a slightly metamorphic (greenschist facies) post-Namurian cover. At the top lie the high-pressure metamorphosed (up to 0.8 GPa in the sector here considered) ophiolitic units. The group of the non-metamorphic Helminthoid Flysch nappes (original stratigraphic cover of the ophiolitic units) has travelled the greatest distance and is presently mainly set onto the outer part of the chain. Only events up to the stacking of the nappe pile are discussed, disregarding late-stage deformation. As the examined sector is located at a considerable distance from the collisional zone, late processes did not change the overall order of superposition formerly acquired. The model proposes the development of two major, subhorizontal detachment surfaces. The first, shallower one confines at the base a very thin-skinned set of nappes, nearly totally made up of Prepiedmont sedimentary covers that are bounded at their top by the Helminthoid Flysch units. Both these groups underwent a mainly horizontal outwards transport. In contrast, the underlying Prepiedmont crust and the adjoining Briançonnais inner sector (separated by the second, deeper major detachment surface) were progressively dragged into the subduction zone under the ophiolitic units and duplexes were generated. Exhumation of the metamorphic units occurred along the subduction channel, as did stacking of the nappe pile.     

Morphotectonics of a high plateau on the northwestern flank of the Continental Rift of southeastern Brazil

Integration of landform and structural analysis allowed the identification of Late Pleistocene–Holocene pulses of tectonic activity in the Campos do Jordão Plateau with ages and regimes similar to the ones from the continental rift. Fault reactivation along Precambrian shear zones give rise to a series of conspicuous morphotectonic features, determine the formation of stream piracy phenomena, and divide the plateau into smaller blocks. Recognition of these tectonic pulses as well as of their effects in landform development—particularly clear on the Campos de São Francisco at the highest area of the SE edge of the plateau—show that besides the climate-related Quaternary environmental changes significant neotectonic instability should be considered in the geomorphic evolution of the Campos do Jordão Plateau.     

Magma–carbonate interaction: An experimental study on ultrapotassic rocks from Alban Hills (Central Italy)

The Alban Hills ultrapotassic volcanic district is one of the main districts emplaced during Quaternary time along the Tyrrhenian margin of Italy. Alban Hills lava flows and scoria clasts are made up essentially of clinopyroxenes and leucites and their chemical composition is mostly K-foiditic. Differentiated products (MgO < 3 wt.%) are characterised by low SiO₂ concentration (< 50 wt.%) and geochemical features indicate that this unique differentiation trend is driven by crystal fractionation plus carbonate crust interaction. Notably, the Alban Hills Volcanic District was emplaced into thick limestone units. With the aim of constraining the magmatic differentiation, we performed experiments on the Alban Hills parental composition (plagioclase-free phono-tephrite) under anhydrous, hydrous, and hydrous-carbonated conditions. Experiments were carried out at 1 atm, 0.5 GPa and 1 GPa, temperatures ranging from 1050 to 1300 °C, and H₂O and CaCO₃ in the starting material up to 2 and 7 wt.%, respectively. The experiments performed at 0.5 GPa are the most representative of the Alban Hills plumbing system. Clinopyroxene and leucite are the main phases occurring under all the investigated conditions and the liquidus phases. Nevertheless, our experimental results demonstrate that the occurrence of CaCO₃ in the starting material strongly affects phase relations. Experiments performed under hydrous conditions crystallize magnetite and phlogopite at relatively high temperature. This early crystallization drives the glass composition towards a silica enrichment, resulting in a differentiation trend moving from phono-tephritic (Alban Hills parental composition) to phonolitic compositions. This is in contrast with micro-textural evidence showing late crystallization of magnetite and phlogopite in the natural products and with the composition of the juvenile products. On the contrary, in the CaCO₃-bearing experiments (i.e., simulating magma–carbonate interaction) the magnetite and phlogopite stability fields are strongly reduced. As a consequence, the melt differentiation is mainly controlled by the cotectic crystallization of clinopyroxene and leucite, resulting in a differentiation trend moving towards K-foiditic compositions. These experimental results are in agreement with micro-textural features and chemical compositions of Alban Hills natural products and with the magmatic differentiation model inferred by geochemical data. Magma–carbonate interaction is not a rare process and its occurrence has been demonstrated for different plumbing systems. However, the uniqueness of the Alban Hills liquid line of descent suggests that the efficacy of the carbonate contamination process is controlled by different factors, the dynamics of the plumbing system being one of the most important.     

Timing of erosion and satellite data: A multi-resolution approach to soil erosion risk mapping

Erosion reduces soil productivity and causes negative downstream impacts. Erosion processes occur on areas with erodible soils and sloping terrain when high-intensity rainfall coincides with limited vegetation cover. Timing of erosion events has implications on the selection of satellite imagery, used to describe spatial patterns of protective vegetation cover. This study proposes a method for erosion risk mapping with multi-temporal and multi-resolution satellite data. The specific objectives of the study are: (1) to determine when during the year erosion risk is highest using coarse-resolution data, and (2) to assess the optimal timing of available medium-resolution images to spatially represent vegetation cover during the high erosion risk period. Analyses were performed for a 100-km² pasture area in the Brazilian Cerrados. The first objective was studied by qualitatively comparing three-hourly TRMM rainfall estimates with MODIS NDVI time series for one full year (August 2002–August 2003). November and December were identified as the months with highest erosion risk. The second objective was examined with a time series of six available ASTER images acquired in the same year. Persistent cloud cover limited image acquisition during high erosion risk periods. For each ASTER image the NDVI was calculated and classified into five equally sized classes. Low NDVI was related to high erosion risk and vice versa. A DEM was used to set approximately flat zones to very low erosion risk. The six resulting risk maps were compared with erosion features, visually interpreted from a fine-resolution QuickBird image. Results from the October ASTER image gave highest accuracy (84%), showing that erosion risk mapping in the Brazilian Cerrados can best be performed with images acquired shortly before the first erosion events. The presented approach that uses coarse-resolution temporal data for determining erosion periods and medium-resolution data for effective erosion risk mapping is fast and straightforward. It shows good potential for successful application in other areas with high spatial and temporal variability of vegetation cover.     

Analisi periodale delle serie dei livelli marini di Trieste e Venezia

Riassunto Alle due serie di livelli medi, quella cinquantennale di Trieste e quella settantennale di Venezia, si applica l'analisi periodale secondo il metodoVercelli. Si ottengono onde componenti di anni 22, 11,3, 8, 5,5, 4, 3, 2. Le onde corrispondenti delle due località sono in buon accordo di fase. Le ampiezze delle componenti di Venezia sono leggermente maggiori di quelle di Trieste. L'asse medio del diagramma di Trieste presenta una salita di 11 cm in 52 anni, quello di Venezia di 15 cm in 70 anni.

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Summary To the series of yearly values of the mean heights of the sea-level for the ports of Trieste and Venice has been applied the periodal analysis after the method ofVercelli. From this are derived component waves almost-persistent and almost-periodical of 22, 11,3, 8, 5,5, 4, 3, 2 years. The mean axis shows the following variations for every ten years: an ascent of 2 cm in the port of Trieste and of 2.5 cm in the port of Venice.

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Zusammenfassung Es wird dieVercelli Periodalanalyse an den zwei Reihen, eine 50- eine 70jährige, von jährlichen mittleren Wasserständen bezüglich der Hafen von Triest und Venedig angewendet. Man erhält Komponentwellen die Perioden von 22-11,3-8-5,5-4-3-2 Jahren haben. Die entsprechenden Wellen der zwei Lokalitäten sind in einer guten Uebereinstimmung der Phase. Die Amplituden der Komponentwellen von Venedig sind etwas grösser als diejenigen von Triest. Die mittlere Achse stellt einen Aufstieg dar, welche für ein Jahrzehnt 2 cm für Triest und 2,5 für Venedig beträgt.

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Lavoro eseguito con il contributo del Consiglio Nazionale delle Ricerche.     

Modelling of natural and synthetic polyelectrolyte interactions in natural waters by using SIT, Pitzer and Ion Pairing approaches

In this paper SIT and Pitzer models are used for the first time to describe the interactions of natural and synthetic polyelectrolytes in natural waters. Measurements were made potentiometrically at 25 °C in single electrolyte media, such as Et₄NI and NaCl (for fulvic acid 0.1 < I /mol L^− 1 < 0.75), and in a multi-component medium simulating the composition of natural waters at a wide range of salinities (for fulvic and alginic acids: 5 < S < 45) with particular reference to sea water [Synthetic Sea Water for Equilibrium studies, SSWE]. In order to simplify calculations, SSWE was considered to be a “single salt” BA, with cation B and anion A representing all the major cations (Na⁺, K⁺, Mg²⁺, Ca²⁺) and anions (Cl⁻, SO₄²⁻) in natural sea water, respectively. The ion pair formation model was also applied to fulvate and alginate in artificial sea water by examining the interaction of polyanions with the single sea water cation. Results were compared with those obtained from previous speciation studies of synthetic polyelectrolytes (polyacrylic and polymethacrylic acids of different molecular weights). Results indicate that the SIT, Pitzer and Ion Pairing formation models used in studies of low molecular weight electrolytes may also be applied to polyelctrolytes with a few simple adjustments.     

Andamento diurno,stagionale ed annuo della visbillità nel Golfo di Trieste

Riassunto Dalle osservazioni di visibilità verso il mare, eseguite giornalmente a Trieste alle ore 8, 14 e 19, nel ventennio 1931–1950, si deducono le medie mensili, stagionali e annue. La visibilità risulta massima alle ore 14 e nei mesi estivi. Il valore medio annuo è 6.5 del codice internazionale, la visibilità è di 15.000 m ed è classificata mediocre-buona. Nel ventennio l'andamento medio annuo risulta leggermente crescente.

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Summary From the visibility-observations towards the sea, effectuated every day at 8^h, 14^h and 19^h, during the period of twenty years (1931–1950), the monthly and annual mean values are calculated. The visibility results maximum at 14^h of the summer months. The mean annual value is 6.5 of the International Codex, the visibility is 15.000 m and it is classified middle-good. In the twenty years 1931–1950, the mean annual going results lightly increasing.