Impact of Reservoir Permeability,Permeability Anisotropy and Designed Injection Rate on CO2 Gas Behavior in the Shallow Saline Aquifer at the CaMI Field Research Station,Brooks, Alberta

Natural Resources Research - Carbon capture and storage is part of Canada’s climate change action plan to reduce greenhouse gas emissions. The Containment and Monitoring Institute Field...     

Statistical analysis of surface urban heat island intensity variations: A case study of Babol city,Iran

The urban heat island is considered as one of the most important climate change phenomena in urban areas, which can result in remarkable negative effects on flora, concentration of pollutants, air quality, energy and water consumption, human health, ecological and economic impacts, and even on global warming. The variation analysis of the surface urban heat island intensity (SUHII) is important for understanding the effect of urbanization and urban planning. The objective of this study was to present a new strategy based on the Shannon’s entropy and Pearson chi-square statistic to investigate the spatial and temporal variations of the SUHII. In this study, Landsat TM, ETM+, OLI and TIRS images, MODIS products, meteorological data, topographic and population maps of the Babol city, Iran, from 1985 to 2017, and air temperature data recorded by ground recorder devices in 2017 were used. First, Single-Channel algorithm was used to estimate land surface temperature (LST), and the maximum likelihood classifier was employed to classify Landsat images. Then, based on LST maps, surface urban heat island ratio index was employed to calculate the SUHII. Further, several statistical methods, such as the degree-of-freedom, degree-of-sprawl and degree-of-goodness, were used to analyse the SUHII variation along different geographic directions and in various time periods. Finally, correlation between various parameters such as air temperature, SUHII, population variation and degree-of-goodness index values were investigated. The results indicated that the SUHII value increased by 24% in Babol over different time periods. The correlation coefficient yielded 0.82 between the values of the difference between the mean air temperature of the urban and suburbs and the SUHII values for the geographic directions. Furthermore, the correlation coefficient between the population variation and the degree-of-goodness index values reached 0.8. The results suggested that the SUHII variation of Babol city had a high degree-of-freedom, high degree-of-sprawl and negative degree-of-goodness.     

Uptake and fixation of Zn, Pb, and Cd by Thlaspi caerulescens: application in the cases of old mines of Mibladen and Zaida (West of Morocco)

Contaminated soils and mine tailings pose major environmental and agricultural problems worldwide. These problems may be partially solved by an emerging new technology: phytoremediation. This technique uses plants to extract soil contaminants from the ground. Thlaspi caerulescens is known to accumulate in their tissues several heavy metals from soil and aerial deposition. This study was conducted to screen plants growing on a contaminated site to determine their potential for metal accumulation. Seeds of T. caerulescens metallicolous have been collected in the vicinity of F.T. Laurent le Minier in the Pb–Zn mining district of les Malines (North of Montpellier, Southern France), and seeds of T. caerulescens non-metallicolous were sampled on Larzac Plateau (North of Montpellier, Southern France). Soil substrates were collected from a mine site of Mibladen and Zaida (West, Morroco). Cultivated plant and surface soil samples were analyzed for zinc, lead, and cadmium concentrations by inductively coupled plasma mass spectrometry. A non-metallicolous (NM) ecotype of T. caerulescens and a metallicolous (M) ecotype are compared for Pb, Cd, and Zn accumulation in shoot and root in five metal-contaminated soils and one uncontaminated soil. The growth of individuals from uncontaminated soil was greater than that of individuals from metal-contaminated soils. The NM populations had markedly higher root/shoot ratio compared to M populations. The results indicate that both ecotypes of T. caerulescens are highly tolerant of zinc and Cd. Ecotype NM had constitutively higher Zn uptake capacity than the M ecotype. T. caerulescens species accumulate higher amount of Zn and Cd in their tissues in polluted soil and, in both of the two ecotypes, the root Pb concentrations were much greater than those of the shoot Pb contents. From both uncontaminated and metal-contaminated soils, we conclude that T. caerulescens are interesting material for phytoremediation of zinc and cadmium.     

Electrical earth resistivity surveying for delineating the characteristics of ground water in a semi‐arid region in the Khanasser Valley,northern Syria

A resistivity survey is conducted in Khanasser Valley, a semi‐arid region in northern Syria, to delineate the characteristics of ground water affected by the salt‐water intrusion related to Al‐Jaboul Sabkha. Existing wells were used to measure salinity and conductivity of water samplings. Vertical electrical sounding was carried out near the existing wells. The combination of resistivity and hydrogeological data enables the establishment of empirical relationships between earth resistivity, water resistivity, and the amount of total dissolved solids. These relationships are then used in order to derive salinity maps for electrode spacings of 70, 100, and 150 m. The distribution of fresh, brackish and salt‐water zones and their variations in space along two longitudinal profiles (LP1 and LP2) are established through converting subsurface depth–resistivity models into different ground‐water areas. The constructed ground‐water area maps allow interfaces between different water zones to be determined. Copyright © 2006 John Wiley & Sons, Ltd.     

Marine geochemistry—2: scavenging redux

Inorganic surfaces sorb dissolved and particulate phases from seawater onto organic films from a variety of sources. Heavy metals such as Au, Pt, Mn and Cd come to the coatings primarily from particulate phases. This observation confirms a previous finding of this laboratory for the uptake of U, Pu and Po. With depth in the open ocean there are greater contributions from the dissolved phases. Microbial and photochemical processes can enrich surfaces in some metals through reduction reactions. Copper and Mn enrichments in the films are attributed to the photo-reductions of Cu(II) to Cu(I) and manganese oxides to Mn(II), respectively, while the uptake of Mo is a consequence of the reduction, mediated by organisms, of molybdate to Mo(V) or Mo(IV). Cadmium, on the other hand, appears to be bioaccumulated in the films.     

Biogeochemical Prospecting of Sulphide Minerals in Winder Valley, Balochistan, Pakistan

Abstract: The Mor Range is mountainous terrain in southern Balochistan dominantly occupied by exposures of rocks of the Ferozabad Group which is comprised of Lower‐Middle Jurassic carbonates and siliciclastics. This group contains syngenetic and epigenetic Zn–Pb–Ba mineralization classified as Stratiform Sediment‐Hosted (SSH) and Mississippi Valley Type (MVT) deposits. Three important flora of the Saharo–Sindian, phytogeographical region of Pakistan, namely Tamarix aphyl–la, Salvadora oleoides and Acacia arabica have been studied as a mineralization prospecting tool. Samples of these species were collected from Winder Valley adjoining the Mor Range to prospect for new areas of mineralization, besides the known sulphide deposits. This study revealed the Draber, Thorar, Raj, Mithi and Kanrach localities as new prospect. Quantitative estimation of biophile elements (Zn–Cu–Pb) from the three species was made. A number of new Zn, Cu and Pb anomalies were distinguished in the area. The variation in the constituents of these species from different localities possibly varies with nature and distance from bedrock, mobility, climate, average abundance in the plant ash and exclusion mechanism of the flora. Acacia arabica with deep penetrating roots shows the best results and could be used to delineate new horizons of mineralization. In these species Zn and Cu are relatively concentrated whereas Pb shows limited enrichment. Lead therefore is the element best suited for pinpointing the mineralization owing to its relatively less mobile character. Relationships among Zn–Cu–Pb have been established using scattergrams and triangular variation diagram, which also demonstrate their genetic affiliation. Statistical analyses, such as determination of mean, mode, median, standard deviation, and coefficient of correlation, were also made to improve the raw geochemical data. These biogeochemical methods appear to be suitable in arid climate of Balochistan, if proper attention is paid to species selection.     

Stable isotope dynamics of groundwater interactions with Ganges river

Groundwater depletion has been an emerging crisis in recent years, especially in highly urbanized areas as a result of unregulated exploitation, thus leaving behind an insufficient volume of usable freshwater. Presently Ganges river basin, the sixth largest prolific fluvial system and sustaining a huge population in South Asia, is witnessed to face (i) aquifer vulnerability through surface waterborne pollutant and (ii) groundwater stress due to summer drying of river as a result of indiscriminate groundwater abstraction. The present study focuses on a detailed sub-hourly to seasonally varying interaction study and flux quantification between river Ganges and groundwater in the Indian subcontinent which is one of the first documentations done on a drying perennial river system that feeds an enormous population. Contributing parameters to the total discharge of a river at its middle course on both temporal and spatial scale is estimated through three-component hydrograph separation and end-member mixing analysis using high-resolution water isotope (δ¹⁸O and δ²H) and electrical conductivity data. Results from this model report groundwater discharge in river to be the highest in pre-monsoon, that is, 30%, whereas, during post-monsoon the contribution lowers to 25%; on the contrary, during peak monsoon, the flow direction reverses thus recharging the groundwater which is also justified using annual piezometric hydrographs of both river water and groundwater. River water-groundwater interaction also shows quantitative variability depending on river morphometry. The current study also provides insight on aquifer vulnerability as a result of pollutant mixing through interaction and plausible attempts towards groundwater management. The present study is one of the first in South Asian countries that provides temporally and spatially variable detailed quantification of baseflow and estimates contributing parameters to the river for a drying mega fluvial system.