Wave interaction with T-type breakwaters

The wave transmission, reflection and energy dissipation characteristics of partially submerged ‘T'-type breakwaters (Fig. 1) were studied using physical models. Regular and random waves, with wide ranges of wave heights and periods and a constant water depth were used. Five different depths of immersions of the ‘T'-type breakwater were selected. The coefficient of transmission, K_t, coefficient reflection, K_r, were obtained from the measurements and the coefficient of energy loss, K_l is calculated using the law of conservation of energy. It is found that the coefficient of transmission generally reduces with increased wave steepness and increased relative water depth, d/L. This breakwater is found to be effective closer to deep-water conditions. K_t values less than 0.35 is obtained for both normal and high input wave energy levels, when the horizontal barrier of the T type breakwater is immersed to about 7% of the water depth. This breakwater is also found to be very efficient in dissipating the incident wave energy to an extent of about 65% (i.e. K_l>0.8), especially for high input wave energy levels. The wave climate in front of the breakwater is also measured and studied.

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Fig. 1. Schematic view of the T-type breakwater.     

Hydroxylamine formation in laboratory experiments on marine nitrification

As a part of studies on the production of dissolved and particulate organic matter in the decomposition of various biological materials, observations were also made on the chemosynthetic microbial process of nitrification. During the oxidation of ammonia to nitrate, hydroxylamine was detected and it seemed to be an unstable intermediate compound in the first phase of marine nitrification.     

Wave interaction with ‘’-type breakwaters

The wave transmission, reflection and energy dissipation characteristics of ‘’-type breakwaters were studied using physical models. Regular and random waves in a wide range of wave heights and periods and a constant water depth were used. Five different depths of immersion (two emerged, one surface flushing and two submerged conditions) of this breakwater were selected. The coefficient of transmission, K_t, and coefficient of reflection, K_r, were obtained from the measurements, and the coefficient of energy loss, K_l was calculated using the law of balance of energy. It was found that the wave transmission is significantly reduced with increased relative water depth, d/L, whether the vertical barrier of the breakwater is surface piercing or submerged, where ‘d’ is the water depth and ‘L’ is the wave length. The wave reflection decreases and energy loss increases with increased wave steepness, especially when the top tip of the vertical barrier of this breakwater is kept at still water level (SWL). For any incident wave climate (moderate or storm waves), the wave transmission consistently decreases and the reflection increases with increased relative depth of immersion, Δ/d from −0.142 to 0.142. K_t values less than 0.3 can be easily obtained for the case of Δ/d=+0.071 and 0.142, where Δ is the height of exposure (+ve) or depth of immersion (−ve) of the top tip of the vertical barrier. This breakwater is capable of dissipating wave energy to an extent of 50–80%. The overall performance of this breakwater was found to be better in the random wave fields than in the regular waves. A comparison of the hydrodynamic performance of ‘’-type and ‘T’-type shows that ‘T’-type breakwater is better than ‘’-type by about 20–30% under identical conditions.     

Integration of VNIR and SWIR spectral reflectance for mapping mineral resources; A case study,north east of Hajjah,Yemen

Laboratory reflectance spectra of 18 rock samples from the Precambrian basement of north east of Hajjah were measured and analyzed using the instrument of FieldSpec3 with spectral range 0.250–2.500 μm. The aim of this study is to use the spectral reflectance of rocks for mapping the mineral resources in the north east of Hajjah. The altered system in the study area comprises of silicification, sericitification, oxidation, clay minerals and carbonatization. Silicified alteration is not distinguishable in the regions of Visible-Near Infrared (VNIR) and Short wave Infrared (SWIR) of the electromagnetic spectrum, because of lack of diagnostic spectral absorption features in silica in this wavelength. Although the arsenopyrite and pyrite are wide spread in the whole study area their features do not appear in any range of spectra because they exhibit trans-opaque behavior and often lack distinction in VNIR and SWIR. The entire spectral reflectance curves of samples show alteration. Based on the examination of laboratory spectra all samples in the study area show promise in the field of mineral resources.     

Probability distributions for carbon emissions and atmospheric response

Probability distributions for carbon burning, atmospheric CO₂, and global average temperature are produced by time series calibration of models of utility optimization and carbon and heat balance using log-linear production functions. Population growth is used to calibrate a logistically evolving index of development that influences production efficiency. Energy production efficiency also includes a coefficient that decreases linearly with decreasing carbon intensity of energy production. This carbon intensity is a piecewise linear function of fossil carbon depletion. That function is calibrated against historical data and extrapolated by sampling a set of hypotheses about the impact on the carbon intensity of energy production of depleting fluid fossil fuel resources and increasing cumulative carbon emissions. Atmospheric carbon balance is determined by a first order differential equation with carbon use rates and cumulative carbon use as drivers. Atmospheric CO₂ is a driver in a similar heat balance. Periodic corrections are included where required to make residuals between data and model results indistinguishable from independently and identically distributed normal distributions according to statistical tests on finite Fourier power spectrum amplitudes and nearest neighbor correlations. Asymptotic approach to a sustainable non-fossil energy production is followed for a global disaggregation into a tropical/developing and temperate/more-developed region. The increase in the uncertainty of global average temperature increases nearly quadratically with the increase in the temperature from the present through the next two centuries.     

Parameter Optimization of Activated Carbon Production from Agave sisalana and Punica granatum Peel: Adsorbents for C.I. Reactive Orange 4 Removal from Aqueous Solution

In the present study, activated carbons were prepared from sisal fiber (Agave sisalana sp.) and pomegranate peel (Punica granatum sp.) using phosphoric acid as the activating agent. Both sisal fiber activated carbon (SFAC) and pomegranate peel activated carbon (PPAC) were characterized using methylene blue number, iodine number, BET surface area, SEM, and FTIR. The BET surface area of the SFAC and PPAC were 885 and 686 m²/g, respectively. The adsorption studies using C.I. Reactive Orange 4 dye on the SFAC and PPAC were carried out. The effects of time, initial adsorbate concentration, pH, and temperature on the adsorption were studied. The isotherm studies were carried and it was found that the Langmuir and Freundlich isotherms fit well for the adsorption of RO 4 on SFAC, while adsorption of RO 4 on PPAC is better represented by the Langmuir and Temkin isotherms. Adsorption kinetics of adsorption was determined using pseudo first order, pseudo second order, Elovich and intraparticle diffusion models and it was found that the adsorption process follows pseudo second order model. Thermodynamics parameters such as changes in free energy (ΔG), enthalpy (ΔH), and entropy (ΔS) were determined by using van't Hoff equation. The positive ΔH value indicates that RO 4 dye adsorption on SFAC and PPAC is endothermic in nature.     

Monsoon circulation interaction with Western Ghats orography under changing climate

In this study, the authors have investigated the likely future changes in the summer monsoon over the Western Ghats (WG) orographic region of India in response to global warming, using time-slice simulations of an ultra high-resolution global climate model and climate datasets of recent past. The model with approximately 20-km mesh horizontal resolution resolves orographic features on finer spatial scales leading to a quasi-realistic simulation of the spatial distribution of the present-day summer monsoon rainfall over India and trends in monsoon rainfall over the west coast of India. As a result, a higher degree of confidence appears to emerge in many aspects of the 20-km model simulation, and therefore, we can have better confidence in the validity of the model prediction of future changes in the climate over WG mountains. Our analysis suggests that the summer mean rainfall and the vertical velocities over the orographic regions of Western Ghats have significantly weakened during the recent past and the model simulates these features realistically in the present-day climate simulation. Under future climate scenario, by the end of the twenty-first century, the model projects reduced orographic precipitation over the narrow Western Ghats south of 16°N that is found to be associated with drastic reduction in the southwesterly winds and moisture transport into the region, weakening of the summer mean meridional circulation and diminished vertical velocities. We show that this is due to larger upper tropospheric warming relative to the surface and lower levels, which decreases the lapse rate causing an increase in vertical moist static stability (which in turn inhibits vertical ascent) in response to global warming. Increased stability that weakens vertical velocities leads to reduction in large-scale precipitation which is found to be the major contributor to summer mean rainfall over WG orographic region. This is further corroborated by a significant decrease in the frequency of moderate-to-heavy rainfall days over WG which is a typical manifestation of the decrease in large-scale precipitation over this region. Thus, the drastic reduction of vertical ascent and weakening of circulation due to ??upper tropospheric warming effect?? predominates over the ??moisture build-up effect?? in reducing the rainfall over this narrow orographic region. This analysis illustrates that monsoon rainfall over mountainous regions is strongly controlled by processes and parameterized physics which need to be resolved with adequately high resolution for accurate assessment of local and regional-scale climate change.     

Reassessing the earthquake hazard in Kerala based on the historical and current seismicity

Given the lack of proper constraints in understanding earthquake mechanisms in the cratonic interiors and the general absence of good quality database, here we reassess the seismic hazard in the province of Kerala, a part of the •stable continental interior•, based on an improved historical and instrumental database. The temporal pattern of the current seismicity suggests that >60% of the microtremors in Kerala occurs with a time lag after the peak rainfall, indicating that hydroseismicity may be a plausible model to explain the low-level seismicity in this region. Further, an increment in overall seismicity rate in the region in the recent years is explained as due to increased anthropogenic activities, which includes changes in hydrological pathways as a consequence of rapid landscape changes. Our analyses of the historical database eliminate a few events that are ascribed to this region; this exercise has also led to identification of a few events, not previously noted. The improved historical database essentially suggests that the central midland region is more prone to seismic activity compared to other parts of Kerala. This region appears to have generated larger number of significant earthquakes; the most prominent being the multiple events (doublets) of 1856 and 1953, whose magnitudes are comparable to that of the 2000/2001 (central Kerala) events. Occurrences of these historical events and the recent earthquakes, and the local geology indicative of pervasive faulting as shown by widely distributed pseudotachylite veins suggest that the NNW-SSE trending faults in central midland Kerala may host discrete potentially active sources that may be capable of generating light to moderate size earthquakes. The frequency of earthquakes in central Kerala evident from the historical database requires that the seismic codes stipulated for this region are made mandatory.