Lateral variations of coda Q and attenuation of seismic waves in the Gulf of Suez, Egypt

Gulf of Suez consists mainly of three tectonic provinces that are separated by two accommodation zones. The southern edge of the gulf is bordered by N–S faults which mark the transition between the shallow water, Suez Basin and the deep northern Red Sea Basin. The sensitivity of coda Q measurements with respect to geological differences in the crust is demonstrated in three regions with a large variety of tectonic and geologic properties. The estimation of coda Q (Qc) is performed for 370 local earthquakes recorded at 12 digital seismic stations during the period from 2000 to 2007. The magnitudes of the earthquakes between 1.5 and ~4.5 have been used at central frequencies 1.5, 3, 6, 9, 12, 15, 18, and 24 Hz through three lapse time windows 10, 20, 30 s starting at once and twice the time of the primary S wave from the origin time. The time domain coda decay method of the single isotropic scattering model is employed to calculate frequency-dependent values of coda Q. The Qc values are frequency dependent in the range 1–25 Hz, and are approximated by a least squares fit to the power law [Qc(f) = Qo(f/fo)η]. The observed coda Q indicates that the area is seismically and tectonically active with high heterogeneities. The variation of the quality factor Qc has been estimated at different regions to observe the effect of different tectonic province. The average frequency-dependent estimated relations of Qc vary from 65f1.1 to 96f0.9 at 10 to 30 s window length, respectively. The decreasing value of the frequency parameter with increasing lapse time shows that the crust acquires homogeneity with depth. The variation of Qc with the variations in the geologic and tectonic properties of the crust was investigated. The frequency exponent η might be larger in active tectonic areas and smaller in more stable regions. In the northern region of the Gulf of Suez, the obtained value of η?=?0.8?±?0.011, which might indicate a low level of tectonic activity compared with η?=?1.1?±?0.005 and 1.3?±?0.009 for the central and southern regions of the gulf.     

Mineralization of Catechol by Fenton and Photo‐Fenton Processes

Catechol is one of the most abundant phenolic components of olive mill wastewaters. In this article, the mineralization of this compound in synthetic aqueous solutions by the Fenton and photo‐Fenton processes is studied. It has been found that for 1.44 mM catechol, the total organic carbon of solutions is reduced about 94.4% at best after 60 min of Fenton treatment at optimized conditions of pH 3.0, 0.2 mM Fe²⁺, 7.09 mM H₂O₂, and 25°C. A faster and overall mineralization is attained by applying photo‐Fenton with UVA irradiation. o‐Benzoquinone, 1,2,3‐trihydroxybenzene and 1,2,4‐trihydroxybenzene were identified by GC–MS as primary quinonic and polyhydroxylated derivatives. Small amounts of generated carboxylic acids like muconic, maleic, malonic, acetic, oxalic, and formic acids were detected by ion‐exclusion chromatography. The Fe(III) complexes of these acids persist in the medium under Fenton conditions, while their photolysis by UVA light and that of other by‐products account for by the faster degradation and total mineralization achieved in the photo‐Fenton process. A reaction sequence for catechol mineralization by Fenton and photo‐Fenton involving all intermediates detected is proposed.     

Residual oil as a tool in migration and filling history analysis of petroleum reservoirs,Ghazal Field,Saudi Arabia

Stepwise extraction and molecular analysis of non-recoverable oil from intact reservoir core plugs is used to provide constraints on the accumulation history of petroleum in the Permo-Carboniferous Unayzah reservoirs at the Ghazal Field, Saudi Arabia. When integrated with existing tools such as oil geochemistry, gas geochemistry, stable carbon isotopes, fluid inclusions and thermal modeling, the sequential extraction approach helped decode a previously unrecognized component of the hydrocarbon accumulation history. In particular, it indicates that the region received early petroleum charges that were less mature than currently produced light oil and gas condensates, possibly from the prolific Early Silurian Qusaiba shale source rock and other sources. This has significant implications for prospecting for additional oil, particularly in the north/northwest of the Ghazal region where paleo-oil accumulations may have been displaced or spilled. The lower portion of the Unayzah reservoir (Unayzah-C) remained water-wet during early filling of the upper reservoir unit (Unayzah-A) and appears to have been filled only by a late oil charge. Anomalous molecular and carbon isotopic behavior of residual oil extracts from the uppermost segment of the Unayzah reservoir, where the free oil (first of the sequential extracts) is less mature (0.95% Rc) and isotopically lighter (δ¹³C?31.15‰) than the adsorbed oil (last sequential extract, 1.05% Rc; δ¹³C?29.65‰), suggests a late oil contribution or bitumen contamination from the overlying Khuff Formation.     

Integration of RADARSAT and GIS modelling for estimating future Red River flood risk

A new geomatics-based approach for flood prediction was developed and used to model the magnitude and spatial extent of a future Red River flood in southern Manitoba. This approach combines the statistical modelling capabilities of Markov (non-spatial) analysis and logistic regression (spatial) within a geographic information system (GIS) environment, utilizing modelling inputs derived from remotely sensed RADARSAT imagery and other digital geographic data. The 1997 Red River flood was the second largest in recorded history, and the largest for which accurate data are available. The results indicate: (i) a flood “one time interval-in terms of 3 days time unit measurement- larger in area” than the 1997 flood is expected to affect 17.6% more land (an additional 47.6 km²) within the study area compared to 1997 levels based on Markovian probability derived from observations from the 1997 event; and (ii) the majority of this excess flooding will take place on agricultural land; no additional communities are expected to be at risk. Quantitative assessment verified the capability of this modelling approach for producing statistically significant results. The methodology used in this research would be easily transferable to other areas, and may provide the basis for a viable alternative to conventional hydrologic-based flood prediction approaches This revised version was published online in August 2006 with corrections to the Cover Date.     

An intercomparison between the GSWM, UARS, and ground based radar observations: a case-study in January 1993

The Global-Scale Wave Model (GSWM) is a steady-state two-dimensional linearized model capable of simulating the solar tides and planetary waves. In an effort to understand the capabilities and limitations of the GSWM throughout the upper mesosphere and thermosphere a comparative analysis with observational data is presented. A majority of the observational data used in this study was collected during the World Day campaign which ran from 20 January to 30 January 1993. During this campaign data from 18 ground-based observational sites across the globe and two instruments located on the UARS spacecraft were analyzed. Comparisons of these data with the simulations from the GSWM indicate that the GSWM results are in reasonable agreement with the observations. However, there are a number of cases where the agreement is not particularly good. One such instance is for the semidiurnal tide in the northern hemisphere, where the GSWM estimates may exceed observations by 50%. Through a number of numerical simulations, it appears that this discrepancy may be due to the eddy diffusivity profiles used by the GSWM. Other differences relating to the diurnal tide and the quasi-two-day wave are presented and discussed. Additionally, a discussion on the biases and aliasing difficulties which may arise in the observational data is alos presented.     

Les minéralisations ferrifères du Sahara Algerien: le gisement de fer oolithique de Mecheri Abdelaziz (bassin de Tindouf)

Résumé Le gisement de fer oolithique de Mecheri Abdelaziz (Famennien terminal du bassin de Tindouf), présente des caractères morphologiques et sédimentologiques qui permettent de penser que la minéralisation s'est mise en place dans des édifices deltaïques progradants.La minéralisation est complexe et comprend trois paragenèses principales; maghémite-magnétite, bavalite-hématite, bavalite-magnétite et quatre faciès types: faciès microconglomératique (FMC), faciès à oolithes dispersées dans une matrice détritique (FOD), faciès à oolithes dispersées dans une matrice non détritique (FOND) et faciès à oolithes jointives, cimentées (FOC).Les caractères des oolithes et de la mésostase montrent que les corps minéralisés résultent de l'accumulation d'oolithes, développées essentiellement par concrétionnement intrasédimentaire et ayant subi, avant le dépôt définitif, des phases alternantes d'oolithisation et de remise en suspension.Sur l'ensemble du gisement, les teneurs moyennes sont les suivantes: Fe total: 43,49%; SiO₂=13,66%; P₂O₅=2,31%; CaO=5,35%.En ce qui concerne la source du fer, il semble que la mise en place du minerai soit liée aux importantes réserves de quartzites ferrugineux situées dans le Précambrien du socle Réguibat, dont le stock métal initial a subi des remobilisations successives.

---

The Mecheri Abdelaziz oolitic iron deposit (late Famennian of Tindouf Basin) shows morphological and sedimentological features of prograding deltaic sequences.The mineralization is complex and allows the recognition of 3 types of paragenesis: maghemite-magnetite, bavalite-hematite, bavalite-magnetite; and 4 types of facies: microconglomerate facies, oolites dispersed in a matrix with detritic elements, oolites dispersed in a matrix without detritic elements and oolites with cement.The comparison of oolites and matrix suggests that the orebodies are the result of oolites deposition, developed by intrasedimentary processes and before the final deposition, by alternating phases of oolitization and suspension.For the whole ore deposit, the main composition is: total Fe=43.49%; SiO₂=13.66%; P₂O₅=2.31%; CaO=5.35%.The major portion of iron was probably provided by continental leaching of the very important iron formations of the Precambrien Reguibat shield.

     

Contribution of satellite altimetry data in the geophysical investigation of the Red Sea Region, Egypt

Successful development of geodetic satellite missions has aroused new interest in determining global and regional gravity field based on satellite data. Satellite altimetry data enable direct determination of the geoid over sea regions. In Egypt, where land and marine geophysical data are inadequate because of rough topography and economic reasons, the use of satellite altimetry data is of special importance. The northern Red Sea region has been selected as a site for case study of the current research, after applying spectral analysis to reveal near-surface structure, the residual geoid of the studied region shows a good correlation with the known geologic features. Moreover, satellite-based gravity data enhance small-scale features and agrees well with land and marine gravity data. Thus, geoid undulation and satellite gravity data can be a complementary source of data to determine near-surface and deep structures.     

Current motion and short-term deformations in the Suez–Sinai area from GPS observations

We analyze observations from eight GPS campaigns carried out between 1997 and 2005 on a network of 13 sites in the Suez–Sinai area, where separation between the African and the Arabian plates takes place. This is the key area to understand if and in which way Sinai behaves like a sub-plate of the African plate and the role played by seismic and geodetic (long-term) deformation release.Our analysis shows that, on average, the Suez–Sinai area motion, in terms of ITRF00 velocities, matches the African plate motion defined by the NNR-NUVEL-1A model.The horizontal principal strain rate axes estimated separately in the Gulf of Suez area and in the northern Sinai vary from compression across the Gulf (−2.2 ± 1.2) × 10⁻⁸ year⁻¹ to NE extension (1.0 ± 1.5) × 10⁻⁸ year⁻¹ in the North, showing the presence of two distinct domains, so that in our opinion Sinai cannot be considered simply a unique rigid block.The analysis of GPS baseline length variations shows short-term deformations across the Gulf of Suez, reaching up a maximum value of more than 1 cm in 8 years.Since current geodynamical models do not predict significant tectonic deformation in this area, we work under the hypothesis that a contribute may be expected by post-seismic relaxation effects. Under this hypothesis, we compare the baselines length variations with the post-seismic relaxation field associated with five major local earthquakes occurred in the area, testing two different viscoelastic models. Our results show that the detected short-term deformations are better modeled for viscosity values of 10¹⁸ Pa s in the lower crust and 10²⁰ Pa s in the asthenosphere. However, since the modeled post-seismic effect results modest and a certain amount of the detected deformation is not accounted for, we think that an improved modeling should take into account the lateral heterogeneities of crust and upper mantle structures.