Deglaciation history at the Alpine-Mediterranean transition (Argentera-Mercantour,SW Alps) from 10Be dating of moraines and glacially polished bedrock

Estimating the extent and age of the last glacial maxima as well as the chronology of glacial recessions in various environmental contexts is key to source-to-sink studies and paleoclimate reconstructions. The Argentera-Mercantour massif is located at the transition between the Alps and the Mediterranean Sea, therefore, its deglaciation chronology can be compared to the sediment budget of the Var River basin. Based on 13 new cosmic-ray exposure (CRE) beryllium-10 (¹⁰Be) datings performed on moraines and polished crystalline bedrocks and 22 reassessed ¹⁰Be CRE ages from similar altitude nearby steep basement surfaces, and from a lake sediment core, we can constrain the deglaciation chronology of the Argentera-Mercantour massif. These data allow for the first time to fully reconstruct the deglaciation history at the scale of the entire massif in agreement with a major glacier recession at c. 15 ka, at the onset of Bølling transition between the Oldest and Older Dryas. Main deglaciation of the upper slopes [2700–2800 m above sea level (a.s.l.)] occurred after the Last Glacial Maximum (LGM) at 20.8–18.6 ka, followed by the main deglaciation of the lower slopes (2300 m a.s.l.) at 15.3–14.2 ka. Finally, the flat polished surfaces above 2600 m a.s.l. and the zones confined within narrow lateral valleys were likely affected by progressive ice melting of remaining debris covered glaciers and moraine erosion following the Younger Dryas re-advance stage between 12 and 8–9 ka. At lower elevations, the Vens Lake located at 2300 m a.s.l., allows evidence of the onset of lake sedimentation at c. 14 ka and a transition towards a vegetated environment that mainly occurred before 8 ka. Moraine final stabilization at 5 ka might reflect denudation acceleration during the Holocene humid phase. This contribution reveals a glacier–climate relationship more sensitive to warming phases in the southern Alps highlighted by a major decrease of glaciers after c. 15 ka. This major deglaciation is correlated with a 2.5-fold decrease of sediment discharge of rivers into the Mediterranean Sea. © 2019 John Wiley & Sons, Ltd.     

Behavior of arsenic and antimony in the surface freshwater reaches of a highly turbid estuary, the Gironde Estuary, France

This study reports on the behavior of two redox-sensitive elements, As and Sb, along the turbidity gradient in the freshwater reaches of the turbid Gironde Estuary. During a 17-month survey, surface water and suspended particulate matter (SPM) were sampled monthly at six sites representing both fluvial branches of the Gironde Estuary. Additionally, two longitudinal high resolution profiles were sampled along the fluvial estuary of the Garonne Branch during two contrasted seasons, i.e. with and without the presence of the maximum turbidity zone (MTZ). Seasonal variability and spatial distribution of dissolved (<0.2 μm; <0.02 μm) and particulate As, Sb and Fe were measured and combined with SPM data to understand metalloid behavior in the estuarine freshwater turbidity gradient.At the two main fluvial entries of the Gironde Estuary, dissolved As and Sb concentrations showed strong (by a factor of 2–4) seasonal variations, that were only partly controlled by discharge-related dilution. Seasonal addition of dissolved As and Sb was attributed to the degradation of particulate As and Sb carrier phases in bottom sediment and/or in the adjacent aquifers, rather than release from SPM. In the surface freshwater reaches of the Gironde Estuary, Sb behaved conservatively under all hydrological conditions. In contrast, As was strongly reactive in the presence of the MTZ, with opposite behaviors in the two fluvial branches of the estuary: in the Garonne Branch As was removed from the dissolved phase, whereas in the Dordogne Branch As was added. Redistribution of As between the dissolved and the particulate phases along the turbidity gradient in estuarine freshwater only affected the <0.02 μm fraction, as the 0.02–0.2 μm fraction remained constant (300 ng L⁻¹ in September 2005). Accordingly, As removal seemed to be decoupled from concomitant “colloidal” (0.02–0.2 μm) Fe flocculation in the turbidity gradient. The contrasting behavior of dissolved As in the fluvial estuaries of the Garonne and Dordogne Branches was attributed to sorption processes during equilibration of river-borne dissolved As with estuarine SPM forming the MTZ. This equilibrium, described by a distinct distribution coefficient K_d(As)  11,000 L kg⁻¹ in the MTZ, resulted in either As release (desorption; Dordogne Branch) or removal (adsorption; Garonne Branch) in the respective fluvial estuaries. A mixing experiment under controlled laboratory conditions tended to support that equilibration between the dissolved phase and MTZ particles may induce both As release and removal in the estuarine freshwater reaches, with As distribution evolving towards a distinct K_d value for increasing SPM concentrations. The long-term survey allowed estimating annual (2004) dissolved fluxes of As and, for the first time Sb, at the main fluvial entries of the Gironde Estuary at 30.7 t a⁻¹ and 3.2 t a⁻¹ (Garonne River) and at 8.0 t a⁻¹ and 2.3 t a⁻¹ (Dordogne River), respectively.     

The use of acidimetric titration as a novel approach to study particulate trace metal speciation and mobility: Application to sediments of the Scheldt estuary

The study of trace metal speciation has benefited from a great deal of interest leading to the development and the diversification of sequential extraction schemes (SES), which triggered the need for harmonization by the standard, measurements and testing programme (SM & T). However, some uncertainties still persist in the application of the harmonized 3-step protocol, because of the difficulty in conceptualizing a technique that can be applied to environmental samples irrespective of their nature. The alternative method proposed in this study is based on the solubility of the sample components progressively dissolved during the course of an acidimetric titration by 1 mol L⁻¹ HCl. The major HCl-reactive mineralogical components are identified using mass balance calculation of H⁺ consumed by their dissolution together with the amount of major elements released into solution. The speciation of minor and trace elements is investigated by comparing their titrations to those of the major elements. This approach is much simpler than SES because it uses simple non-selective H⁺ at room temperature instead of a complex experimental design of so-called specific reagents. The different mineral components of the solid are no longer operationally defined and the problem of selectivity is irrelevant to the titration approach. The method was applied to several sediment samples from the Scheldt estuary and the particulate phase was further examined by Scanning Electron Microprobe and X-ray Diffraction techniques. The nearly complete consumption of H⁺ in the suspension is balanced by the total dissolution of carbonates and Fe-oxyhydroxides. In contrast to the speciation inferred from the Tessier SES, the acidimetric titration has demonstrated that the carbonate phase does not significantly contain trace metals with the exceptions of 40% of the Mn and 30% of the Co. In contrast, the Fe-oxyhydroxides seem to play a major role and account for 70% of Pb and 20% of Cr, in addition to 60% of P and additional amounts of 20% Co and 40% Mn. 70% of the Cu also occur in the oxyhydroxide phase, more likely coprecipitated with gibbsite. 90% of the Cd and 85% of Zn can be attributed to the Acid Volatile Sulfide (AVS) phase as evidenced from S titration. The acidimetric titration method not only provides information on the speciation of trace metals but also allows the quantification of their reactivity and mobility, if one considers that the titration roughly mimics pH changes that may occur as a result of chemical disequilibrium in the environment. The results demonstrate the potential of the acidimetric titration as an alternative to SES protocols in geochemical and environmental regulation studies. This method is applicable to a wide variety of environmental materials with little or minor adjustments.     

Erosion rates and sediment budgets in vineyards at 1-m resolution based on stock unearthing (Burgundy, France)

A new and simple method is developed to efficiently quantify erosion and deposition rates based on stock unearthing measurements. This is applicable to spatial scales ranging from plot to hillslopes, and to time scales ranging from single hydrologic events to centennial scales. The method is applied to a plot area on vineyard hillslopes in Burgundy (Monthélie, France), with measurement of 4328 vine plants. A sediment budget established at the plot scale shows a mean soil lowering of 3.44 ± 1 cm over 20 years, involving a minimal erosion rate of 1.7 ± 0.5 mm yr^− 1. Locally, erosion rates can reach up to 8.2 ± 0.5 mm yr^− 1.This approach allows the sediment redistribution to be mapped and analyzed at 1-m resolution. It provides novel insights into the characterization of erosion patterns on pluri-decennial scales and into the analysis of spatial distribution of erosion processes on cultivated hillslopes.     

Environmental Radioxenon Levels in Europe: a Comprehensive Overview

Activity concentration data from ambient radioxenon measurements in ground level air, which were carried out in Europe in the framework of the International Noble Gas Experiment (INGE) in support of the development and build-up of a radioxenon monitoring network for the Comprehensive Nuclear-Test-Ban Treaty verification regime are presented and discussed. Six measurement stations provided data from 5 years of measurements performed between 2003 and 2008: Longyearbyen (Spitsbergen, Norway), Stockholm (Sweden), Dubna (Russian Federation), Schauinsland Mountain (Germany), Bruyères-le-Châtel and Marseille (both France). The noble gas systems used within the INGE are designed to continuously measure low concentrations of the four radioxenon isotopes which are most relevant for detection of nuclear explosions: ^131mXe, ^133mXe, ¹³³Xe and ¹³⁵Xe with a time resolution less than or equal to 24 h and a minimum detectable concentration of ¹³³Xe less than 1 mBq/m³. This European cluster of six stations is particularly interesting because it is highly influenced by a high density of nuclear power reactors and some radiopharmaceutical production facilities. The activity concentrations at the European INGE stations are studied to characterise the influence of civilian releases, to be able to distinguish them from possible nuclear explosions. It was found that the mean activity concentration of the most frequently detected isotope, ¹³³Xe, was 5–20 mBq/m³ within Central Europe where most nuclear installations are situated (Bruyères-le-Châtel and Schauinsland), 1.4–2.4 mBq/m³ just outside that region (Stockholm, Dubna and Marseille) and 0.2 mBq/m³ in the remote polar station of Spitsbergen. No seasonal trends could be observed from the data. Two interesting events have been examined and their source regions have been identified using atmospheric backtracking methods that deploy Lagrangian particle dispersion modelling and inversion techniques. The results are consistent with known releases of a radiopharmaceutical facility.     

Review on dating methods: Numerical dating in the quaternary geology of High Asia

Over the past few years, OSL and TCN datings of glacial material from High Asia have come into fashion. To this day, however, these techniques do not permit safe calibration. The intensity of the cosmic ray flux is being modulated by the solar and terrestrial magnetic fields and their secular fluctuations in the past. So far, these variations cannot be converted into the respective local TCN production rates for High Asia. We have reason to believe that the ages that are being calculated despite these uncertainties are generally overestimated. This assessment is supported by conventional radiocarbon dates and above all by the glacial chronology developed independently on the basis of the Quaternary geological method. The strongly emerging evidence for a much more extensive LGM glaciation of High Asia is, however, either being ignored or rejected by many authors, solely on the basis of the above-mentioned uncalibrated datings. This self-conceit based on the “dating fallacy”, as we call it, should be avoided since it goes decidedly against the standards of the scientific method established in Quaternary geology and makes a fundamental scientific discussion impossible.     

Using subsurface metazoan fauna to indicate groundwater–surface water interactions in the Nakdong River floodplain, South Korea

Hydrological interactions between surface water and groundwater (GW) can be described using hydrochemical and biological methods. Surface water–groundwater interactions and their effects on groundwater invertebrate communities were studied in the Nakdong River floodplain in South Korea. Furthermore, the GW-Fauna-Index, a promising new index for assessing the strength of surface-water influence on groundwater, was tested. The influence of surface water on groundwater decreased with increasing depth and distance from the river. While hydrochemistry prevailingly reflected the origin of the waters in the study area (i.e. whether alluvial or from adjacent rock), faunal communities seemed to display an affinity to surface-water intrusion. Fauna reacted quickly to changes in hydrology, and temporal changes in faunal community structure were significantly linked to the hydrological situation in the floodplain. The metazoan faunal community and the GW-Fauna-Index allow a distinction between surface and subsurface waters with varying degrees of exchange. The results indicate that hydrological conditions are reflected by faunal assemblages on a high spatiotemporal resolution, and that surface-water intrusion can be estimated using the GW-Fauna-Index.     

Global change and the biogeochemistry of the North Sea: the possible role of phytoplankton and phytoplankton grazing

Phytoplankton plays a dominant role in shelf biogeochemistry by producing the major part of organic matter. Part of the organic matter will reach the sediment where diagenetic processes like denitrification, apatite formation or burial will remove nutrients from the biogeochemical cycle. In this article current knowledge on the decadal plankton variability in the North Sea is summarized and possible implications of these changes for the biogeochemistry of the North Sea are discussed. Most of the observed interdecadal dynamics seem to be linked to large-scale oceanographic and atmospheric processes. Prominent changes in the North Sea ecosystem have taken place around 1979 and 1988. In general, the phytoplankton color (CPRS indicator of phytoplankton biomass) reached minimum values during the end of the 1970s and has increased especially since the mid 1980s. Changes with a similar timing have been identified in many time series from the North Sea through the entire ecosystem and are sometimes referred to as regime shifts. It is suggested that the impact of global change on the local biogeochemistry is largely driven by the phyto- and zooplankton dynamics during spring and early summer. At that time the extent of zooplankton–phytoplankton interaction either allows that a large part of the new production is settling to the sediment, or that a significant part of the new production including the fixed nutrients is kept within the pelagic system. The origin of the extent of the phytoplankton–zooplankton interaction in spring is probably set in the previous autumn and winter. In coastal areas, both large-scale atmospheric and oceanographic changes as well as anthropogenic factors influence the long-term dynamics. Due to eutrophication, local primary production nowadays still is up to five times higher than during pre-industrial conditions, despite a decreasing trend. Recently, introduced species have strengthened the filter feeder component of coastal ecosystems. Especially in shallow coastal seas like the Wadden Sea, this will enhance particle retention, shift organic matter degradation to the benthic compartment and enhance nutrient removal from the biogeochemical cycle by denitrification or apatite formation.     

Intrusion versus inversion—a 3D density model of the southern rim of the Northwest German Basin

An unsolved problem of regional importance for both the evolution and structure of the Northwest German Basin is the existence or non-existence of the so-called Bramsche Massif. Explaining the nature of this massif and the cause of a related strong, positive Bouguer anomaly (Bramsche Anomaly) is critical. In the study described here, we tested an existing “intrusion model” against a newer “inversion model” in the southern Northwest German Basin. In the intrusion model, the strongly-positive Bouguer anomaly represents the gravity effect of an intrusion at depths between 6 and 10 km. More recent interpretations invoke tectonic inversion rather than intrusion to explain increased burial and the low level of hydrocarbon maturity found in boreholes. We tested these different interpretations by constructing 3D forward density models to 15 km depth. The intrusion model was updated and adjusted to incorporate recent data and we also modelled pre-Zechstein structures using different scenarios. The final model has a very good fit between measured and modelled gravity fields. Based on currently available seismic and structural models, as well as borehole density measurements, we show that the positive Bouguer anomaly cannot be modeled without a high-density, intrusive-like body at depth. However, further in-sight into the crustal structures of the Bramsche region requires more detailed investigations. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Integration of multi-source remote sensing data for land cover change detection

The objective of this study is to develop a methodology to integrate multi-source remote sensing data into a homogeneous time series of land cover maps in order to carry out change detection. We developed a method to increase the comparability between land cover maps coming from panchromatic aerial photographs and SPOT XS (multi-spectral) data by equalizing their levels of thematic content and spatial details. The methodology was based on the hypotheses that: (1) map generalization can improve the integration of data for change detection purpose, and (2) the spatial structure of a land cover map, as measured by a set of landscape metrics, is an indicator of the level of generalization of that map. Firstly, the methodology for data integration was developed by using land cover maps generated from near-synchronous data. Results revealed that, by controlling successively the parameters that influence the level of map generalization, the percentage of agreement between the near-synchronous land cover maps can be increased from 42% to 93%. The computation of five landscape metrics for a set of generalized land cover maps and for the target map allowed us to optimize the level of generalization by measuring the similarity in landscape pattern of the maps. The optimum level of generalization of the land cover map obtained from the aerial photographs for comparison with a land cover map derived from SPOT XS data was found at a resolution of 41m for two generalization levels of the thematic content. The spatial structure of a land cover map, as measured by a set of landscape metrics, is thus a good indicator of the level of generalization of this map. Secondly, the method was applied by integrating a land cover map obtained from aerial photographs of 1954 with a land cover map obtained from a SPOT XS image of 1992.