In-situ Measurements of Tropospheric Hydroxyl Radicals by Folded Long-Path Laser Absorption During the Field Campaign POPCORN

Absolutely calibrated in-situ measurements of tropospheric hydroxyl radicals, formaldehyde, sulfur dioxide, and naphthalene (C10H8) were performed by long-path laser absorption spectroscopy during the field campaign POPCORN. The absorption light path was folded into an open optical multiple reflection cell with a mirror separation of 38.5 m. Using a light path length of 1848 m and an integration time of 200 s, the average 1-detection limits of OH, HCHO, SO2 and C10H8 during POPCORN were 8.7 · 105 cm–3, 8.3 · 109 cm–3, 2.4 · 109 cm–3, 1.5 · 108 cm–3, respectively. In total, 392 identifications of OH in air spectra were made in a rural environment between August 5 and August 23, 1994. We present and discuss OH absorption spectra and diurnal OH concentration profiles of three days which are representative for measurements under different pollution conditions during POPCORN. The observed maximum and median OH radical concentrations are 1.3 · 107 OH/cm3 and 4.0 · 106 OH/cm3, respectively. The measured diurnal variation of the OH concentration shows a good correlation with the primary formation reaction of OH radicals which is the photolysis of ambient ozone. Deviations from this correlation in the morning and evening hours, when the OH concentration is higher than expected from the ozone photolysis, demonstrate the importance of other photochemical HOx production pathways during POPCORN.     

Meteorological Aspects, Ozone, and Solar Radiation Measurements During POPCORN 1994

Meteorological data, ozone mixing ratios, and photolysis frequencies for the period August 2 to August 24, 1994, are presented and discussed in support of the field campaign POPCORN (Photochemistry of Plant Emitted Compounds and OH Radicals in Northeastern Germany). Measurements of temperature, ozone, and wind speed at different heights are used to evaluate micro-meteorological parameters. The observations provide information about local influences on the air mass composition. The analysis of radio sonde data of nearby stations provides the height of the planetary boundary layer.     

Deformation and stress regimes in the Hellenic subduction zone from focal Mechanisms

Fault plane solutions for earthquakes in the central Hellenic arc are analysed to determine the deformation and stress regimes in the Hellenic subduction zone in the vicinity of Crete. Fault mechanisms for earthquakes recorded by various networks or contained in global catalogues are collected. In addition, 34 fault plane solutions are determined for events recorded by our own local temporary network on central Crete in 2000–2001. The entire data set of 264 source mechanisms is examined for types of faulting and spatial clustering of mechanisms. Eight regions with significantly varying characteristic types of faulting are identified of which the upper (Aegean) plate includes four. Three regions contain interplate seismicity along the Hellenic arc from west to east and all events below are identified to occur within the subducting African lithosphere. We perform stress tensor inversion to each of the subsets in order to determine the stress field. Results indicate a uniform N-NNE direction of relative plate motion between the Ionian Sea and Rhodes resulting in orthogonal convergence in the western forearc and oblique (40–50^∘) subduction in the eastern forearc. There, the plate boundary migrates towards the SE resulting in left-lateral strike-slip faulting that extends to onshore Eastern Crete. N110^∘E trending normal faulting in the Aegean plate at this part is in accordance with this model. Along-arc extension is observed on Western Crete. Fault plane solutions for earthquakes within the dipping African lithosphere indicate that slab pull is the dominant force within the subduction process and responsible for the roll-back of the Hellenic subduction zone.     

Imaging crustal discontinuities and the downgoing slab beneath western Crete

The migration of teleseismic receiver functions yields high-resolution images of the crustal structure of western Crete. Data were collected during two field campaigns in 1996 and 1997 by networks of six and 47 short-period three-component seismic stations, respectively. A total of 1288 seismograms from 97 teleseismic events were restituted to true ground displacement within a period range from 0.5 to 7 s. The application of a noise-adaptive deconvolution filter and a new polarization analysis technique helped to overcome problems with local coda and noise conditions. The computation and migration of receiver functions results in images of local crustal structures with unprecedented spatial resolution for this region. The crust under Crete consists of a continental top layer of 15–20 km thickness above a 20–30 km thick subducted fossil accretionary wedge with a characteristic en echelon fault sequence. The downgoing oceanic Moho lies at a depth of 40–60 km and shows a topography or undulation with an amplitude of several kilometres. As a consequence of slab depth and distribution of local seismicity, the Mediterranean Ridge is interpreted as the recent accretionary wedge.     

Pink manganian phengite in a high P/T meta-conglomerate from northern Syros (Cyclades, Greece)

A new occurrence of Mn-rich rocks was discovered within the high-pressure/low-temperature metamorphic rocks on the Palos peninsula of Syros (Greece). Near the summit of Mount Príonas, a meta-conglomerate consists of calcite (~63 wt%), pink manganian phengite, blue–purple manganian aegirine–jadeite, microcline, albite and quartz. In addition, it contains abundant braunite-rich aggregates (up to ~1.5 cm in diameter) that include hollandite [(Ba_0.98–1.02K_<0.01Na_<0.02Ca_<0.03) (Mn _1.02–1.52 ³⁺ Fe _0.38–0.88 ³⁺ Ti_0.29–0.92Mn _5.11–5.76 ⁴⁺ )O₁₆], barite and manganian hematite. Due to metamorphic recrystallization and deformation, the contacts between clasts and matrix are blurred and most clasts have lost their identity. In back-scattered electron images, many aegirine–jadeite grains appear patchy and show variable jadeite contents (Jd_10–67). These pyroxenes occur in contact with either quartz or albite. Manganian phengite (3.41–3.49 Si per 11 oxygen anions) is of the 3T type and contains 1.4–2.2 wt% of Mn₂O₃. At the known P–T conditions of high-pressure metamorphism on Syros (~1.4 GPa/ 470 °C), the mineral sub-assemblage braunite + quartz + calcite (former aragonite) suggests high oxygen fugacities relative to the HM buffer (+7 ≤ ?f_O2 ≤ + 17) and relatively high CO₂ fugacities. The exact origin of the conglomerate is not known, but it is assumed that the Fe–Mn-rich and the calcite-rich particles originated from different sources. Braunite has rather low contents of Cu (~0.19 wt%) and the concentrations of Co, Ni and Zn are less than 0.09 wt%. Hollandite shows even lower concentrations of these elements. Furthermore, the bulk-rock compositions of two samples are characterized by low contents of Cu, Co and Ni, suggesting a hydrothermal origin of the manganese ore. Most likely, these Fe–Mn–Si oxyhydroxide deposits consisted of ferrihydrite, todorokite, birnessite, amorphous silica (opal-A) and nontronite. Al/(Al + Fe + Mn) ratios of 0.355 and 0.600 suggest the presence of an aluminosilicate detrital component.     

UV irradiation of natural organic matter (NOM): impact on organic carbon and bacteria

UV-induced transformation of dissolved organic matter (DOC) is often accompanied by reduction of molecular weight and aromaticity and an increase of low-molecular weight (LMW) matter that can be utilized as a substrate by heterotrophic bacteria. Moreover, the generation of reactive transients and mineralization of DOC occurs. For a better understanding of the modification that starts after irradiation and to distinguish between possible chemical and biological modifications, we selected different natural organic matter (NOM) from Norway and Germany. The aqueous solutions were treated by UV irradiation and divided into two aliquot samples. NaN₃ anti-bacterial treatment was applied to one sample, and high-pressure size-exclusion chromatography (HPSEC) analysis was used for both. In all samples, we found typical modifications of NOM after UV irradiation. Incubation (>7?days) of UV-irradiated NOM samples resulted in lower levels of LMW matter and increased aromaticity. Parallel to these changes of carbon fractions, an increase in bacterial cell numbers was observed. Addition of NaN₃ to NOM, however, inhibited the reduction of LMW matter, indicating that microbial activity accounted for the observed changes in NOM. Analysis of the bacterial community composition by denaturing gradient gel electrophoresis (DGGE) of the amplified 16S rRNA genes revealed that bacterial communities of non-irradiated and UV-irradiated NOM were different and that UV selected for specific members of ??-proteobacteria, ??-proteobacteria, and Bacteriodetes. Our results imply that after UV-irradiation of NOM, specific bacterial members are well adapted to low pH, high LMW DOC concentrations, and oxidative stress, and therefore thrive well on UV-irradiated humic matter.     

Deep Time Reconstructions of Internal Earth Structure with the Adjoint Method

正The adjoint method is a powerful tool to obtain gradient information in a computational model relative to unknown model parameters,allowing one to solve inverse problems where analytical solutions are not available or the cost to determine prohibitive.In geodynamics its most prominent application relates to the restoration problem of mantle convection(i.e.,to reconstruct past mantle flow states with dynamic earth models back in time by finding optimal flow histories relative to