Skill assessment of three earth system models with common marine biogeochemistry

We have assessed the ability of a common ocean biogeochemical model, PISCES, to match relevant modern data fields across a range of ocean circulation fields from three distinct Earth system models: IPSL-CM4-LOOP, IPSL-CM5A-LR and CNRM-CM5.1. The first of these Earth system models has contributed to the IPCC 4th assessment report, while the latter two are contributing to the ongoing IPCC 5th assessment report. These models differ with respect to their atmospheric component, ocean subgrid-scale physics and resolution. The simulated vertical distribution of biogeochemical tracers suffer from biases in ocean circulation and a poor representation of the sinking fluxes of matter. Nevertheless, differences between upper and deep ocean model skills significantly point to changes in the underlying model representations of ocean circulation. IPSL-CM5A-LR and CNRM-CM5.1 poorly represent deep-ocean circulation compared to IPSL-CM4-LOOP degrading the vertical distribution of biogeochemical tracers. However, their representations of surface wind, wind stress, mixed-layer depth and geostrophic circulations (e.g., Antarctic Circumpolar Current) have been improved compared to IPSL-CM4-LOOP. These improvements result in a better representation of large-scale structure of biogeochemical fields in the upper ocean. In particular, a deepening of 20–40 m of the summer mixed-layer depth allows to capture the 0–0.5 μgChl L^?1 concentrations class of surface chlorophyll in the Southern Ocean. Further improvements in the representation of the ocean mixed-layer and deep-ocean ventilation are needed for the next generations of models development to better simulate marine biogeochemistry. In order to better constrain ocean dynamics, we suggest that biogeochemical or passive tracer modules should be used routinely for both model development and model intercomparisons.     

Assessing the origin of old apparent ages derived by Pb stepwise leaching of vein-hosted epidote from Mount Isa,northwest Queensland,Australia

Epidote metasomatism affected large areas of tholeiitic metabasalts of the ~1,780 Ma Eastern Creek Volcanics in the Western Fold Belt of the Proterozoic Mount Isa inlier. Hydrothermal epidote generally occurs in quartz veins parallel to or boudinaged within the dominant S₂ fabrics which formed during the regional metamorphic peak at ~1,570 Ma associated with the Isan orogeny. Previously published stable isotopic and halogen data suggest that the fluids responsible for epidote formation are metamorphic in origin (with an evaporitic component). Application of the Pb stepwise leaching technique to the epidote does not separate radiogenic Pb⁴⁺ and common Pb²⁺, generating little spread in ²⁰⁶Pb/²⁰⁴Pb (between 16.0 and 30.5). The causes for this relatively low range are twofold: There is little radiogenic Pb in the epidotes (the most radiogenic steps account for <1 % of Pb released) and both Pb²⁺ and uranogenic Pb⁴⁺ substitute into the same site in the epidote crystal lattice. Consequently, age regressions using the Pb stepwise leaching data give ages between 150 and 1,500 myrs older than the host rocks and over 450 myrs older than the thermal metamorphic peak. These old ages are attributed to chemical inheritance from the host metabasalts, via radiogenic Pb release by breakdown of phases such as zircon, monazite, titanomagnetite, and ilmenite during metamorphism. This idea is supported by trace element data and chrondrite-normalized rare earth element patterns that are similar to both the metabasalts and epidotes (except for a variable Eu anomaly in the latter). Relatively high fO₂ during vein formation (Fe³⁺ dominates in the epidote crystal lattice) would allow the incorporation of Th⁴⁺ and exclusion of U⁶⁺ and would explain elevated Th/U ratios (up to 12) in epidote compared with the host metabasalts. Non-incorporation of U would explain the relatively low U/Pb ratios and non-radiogenic character of the epidote. This process may provide a source of metal for the small U deposits around Mount Isa and may also suggest a relationship between U mineralization and regional Cu mobilization during the Isan orogeny. Our work suggests that non-conventional geochronometers should be used only if additional geological information and geochemical data (e.g., mineral chemistry, trace elements) are available to evaluate any resulting age calculations.     

Interdisciplinary and participatory approaches: the key to effective groundwater management

The challenges of a changing world, which are progressively threatening sustainable use of groundwater resources, can only be rationally and effectively addressed through close collaboration between experts and practitioners from different disciplines. Furthermore, science and management need to build on stakeholder opinions and processes in order to generate useful knowledge and positive outcomes in terms of sustainable and equitable groundwater management. This essay provides a discussion of the status of and vision for participatory and inter-disciplinary approaches to groundwater evaluation and management as well as a conceptual framework and relevant research questions that will facilitate such approaches.     

Middle and Late Holocene Sea-Level Changes in Eastern Maine Reconstructed from Foraminiferal Saltmarsh Stratigraphy and AMS C Dates on Basal Peat

A relative sea-level history is reconstructed for Machiasport, Maine, spanning the past 6000 calendar years and combining two different methods. The first method establishes the long-term (10³ yr) trend of sea-level rise by dating the base of the Holocene saltmarsh peat overlying a Pleistocene substrate. The second method uses detailed analyses of the foraminiferal stratigraphy of two saltmarsh peat cores to quantify fluctuations superimposed on the long-term trend. The indicative meaning of the peat (the height at which the peat was deposited relative to mean tide level) is calculated by a transfer function based on vertical distributions of modern foraminiferal assemblages. The chronology is determined from AMS ¹⁴C dates on saltmarsh plant fragments embedded in the peat. The combination of the two different approaches produces a high-resolution, replicable sea-level record, which takes into account the autocompaction of the peat sequence. Long-term mean rates of sea-level rise, corrected for changes in tidal range, are 0.75 mm/yr between 6000 and 1500 cal yr B.P. and 0.43 mm/yr during the past 1500 years. The foraminiferal stratigraphy reveals several low-amplitude fluctuations during a relatively stable period between 1100 and 400 cal yr B.P., and a sea-level rise of 0.5 m during the past 300 years.     

Simulating compound flooding events in a hurricane

Ocean Dynamics - Compound flooding is usually induced by the concurrence of coastal storm surge and heavy precipitation induced river flooding, with the former involving oceanic processes and the...     

Density function evaluation from borehole gravity meter data – regularized spectral domain deconvolution approach

We present a new method of transforming borehole gravity meter data into vertical density logs. This new method is based on the regularized spectral domain deconvolution of density functions. It is a novel alternative to the “classical” approach, which is very sensitive to noise, especially for high‐definition surveys with relatively small sampling steps. The proposed approach responds well to vertical changes of density described by linear and polynomial functions. The model used is a vertical cylinder with large outer radius (flat circular plate) crossed by a synthetic vertical borehole profile. The task is formulated as a minimization problem, and the result is a low‐pass filter (controlled by a regularization parameter) in the spectral domain. This regularized approach is tested on synthetic datasets with noise and gives much more stable solutions than the classical approach based on the infinite Bouguer slab approximation. Next, the tests on real‐world datasets are presented. The properties and presented results make our proposed approach a viable alternative to the other processing methods of borehole gravity meter data based on horizontally layered formations.