The Grombalia aquifer (NE Tunisia) is an example of an important source of water supply for regional and national development, where the weak controls over abstraction, fertilizer application and waste disposal, coupled with limited knowledge of aquifer dynamics, is causing aquifer over-exploitation and water quality degradation. Assessing the key role of groundwater in water-resources security is therefore of paramount importance to support new actions to preserve water quality and quantity in the long-run. This study presents one of the first investigations targeted at a complete assessment of aquifer dynamics in the Grombalia aquifer. A multi-tracer hydrogeochemical and isotopic (δ2H, δ18O and 3H) approach was used to study the influence of seasonal variation on piezometric levels, chemical and isotopic compositions, and groundwater recharge. A total of 116 samples were collected from private wells and boreholes during three periods in a 1 year monitoring campaign (February–March 2014, September 2014 and February 2015). Results revealed the overall unsuitability of groundwater for drinking and irrigation purposes (NO3?>?50 mg/L in 51% of the wells; EC >1,000 μS/cm in 99% of the wells). Isotopic balance coupled to piezometric investigation indicated the contribution of the shallow aquifer to deep groundwater recharge. The study also revealed the weakness of ‘business as usual’ management practices, highlighting possible solutions to tackle water-related challenges in the Grombalia region, where climate change, population growth and intensive agricultural activities have generated a large gap between demand and available water reserves, hence becoming a possible driver for social insecurity. 相似文献
We report on 10 yr of monitoring of the 8.7-s Anomalous X-ray Pulsar 4U 0142+61 using the Rossi X-Ray Timing Explorer (RXTE). This pulsar exhibited stable rotation from 2000 until February 2006: the RMS phase residual for a spin-down model which
includes ν,
, and
is 2.3%. We report a possible phase-coherent timing solution valid over a 10-yr span extending back to March 1996. A glitch
may have occurred between 1998 and 2000, but it is not required by the existing data. We also report that the source’s pulse
profile has been evolving in the past 6 years, such that the dip of emission between its two peaks has been getting shallower
since 2000, almost as if the profile is recovering to its pre-2000 morphology, in which there was no clear distinction between
the peaks. These profile variations are seen in the 2–4 keV band but not in 6–8 keV. Finally, we present the pulsed flux time
series of the source in 2–10 keV. There is evidence of a slow but steady increase in the source’s pulsed flux since 2000.
The pulsed flux variability and the narrow-band pulse profile changes present interesting challenges to aspects of the magnetar
model.
This work was supported by the Natural Sciences and Engineering Research Council (NSERC) PGSD scholarship to R.D. F.P.G. holds
a National Research Council Research Associateship Award at NASA Goddard Space Flight Center. Additional support was provided
by NSERC Discovery Grant Pgpin 228738-03 NSERC Steacie Supplement Smfsu 268264-03, FQRNT, CIAR, and CFI. V.M.K. is a Canada
Research Chair. 相似文献
Toxic organic compounds in wastewater are serious threats for both human and environment healthy states. This study investigates the potential sources of surface water, sediment and groundwater pollution by polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyl (PCBs) as discharged by wastewater into the River of Oued El bey in northeastern Tunisia. Analysis indicates that the concentration of PAHs and PCBs are high in wastewater and vary from 0.37 to 0.83 mg/L and from 0.28 and 1.18 mg/L, respectively. The spatial distribution of PAHs and PCB in surface water showed a variation between 0.37 to 9.91 mg/L and between 0.1 to 0.47 mg/L, respectively. However, the quality of surface water is changed after wastewater evacuation at Oued Tahouna. The determination of PAH and PCB pollutants in groundwater shows a great interest in the development of water resources. The Concentration of these pollutants varying from 0.0204 to 1.93 mg/L and from 0.0052 to 0.196 mg/L, respectively. For PAH, analysis reveals also that naphtelene, fluorene, anthracene and chrysene are the most detected PAHs compounds in water and sediment samples while benzo[b]fluoranthene and benzo[a]pyrene are less present and in trace level. Higher concentrations of PAHs and PCBs are found in samples taken close to industrial areas of Bouargoub and Soliman, and wastewater discharge locations in Soliman. Analysis of the spatial distribution of PAHs and PCBs clearly link their higher concentration in water and sediments to wastewater and manufacturing discharges in the study area. In surface sediment, the organic pollutants are present. The cluster analysis for organic pollutants in different state and different matrix highlight a relationship between the wastewater evacuation and the water qualities which confirmed the direct response of the pollution sources on the surface water and groundwater organic pollution quality. 相似文献
Major element concentrations and stable (δ18O and δ2H) and radiogenic (3H and 14C) isotopes in groundwater have proved useful tracers for understanding the geochemical processes that control groundwater mineralization and for identifying recharge sources in the semi-arid region of Sfax (southeastern Tunisia). Major-ion chemical data indicate that the origins of the salinity in the groundwater are the water–rock interactions, mainly the dissolution of evaporitic minerals, as well as the cation exchange with clay minerals. The δ18O and δ2H relationships suggest variations in groundwater recharge mechanisms. Strong evaporation during recharge with limited rapid water infiltration is evident in the groundwater of the intermediate aquifer. The mixing with old groundwater in some areas explains the low stable isotope values of some groundwater samples. Groundwaters from the intermediate aquifer are classified into two main water types: Ca-Na-SO4 and Ca-Na-Cl-SO4. The high nitrate concentrations suggest an anthropogenic source of nitrogen contamination caused by intensive agricultural activities in the area. The stable isotopic signatures reveal three water groups: non-evaporated waters that indicate recharge by recent infiltrated water; evaporated waters that are characterized by relatively enriched δ18O and δ2H contents; and mixed groundwater (old/recent) or ancient groundwater, characterized by their depleted isotopic composition. Tritium data support the existence of recent limited recharge; however, other low tritium values are indicative of pre-nuclear recharge and/or mixing between pre-nuclear and contemporaneous recharge. The carbon-14 activities indicate that the groundwaters were mostly recharged under different climatic conditions during the cooler periods of the late Pleistocene and Holocene.
Climate aridity and intensive exploitation due to uncontrolled pumping for irrigation have caused a drastic decrease in the piezometric level of the shallow aquifer of Chougafiya plain, central Tunisia, and have seriously degraded groundwater quality. According to the hydrochemical data (Cl?, SO42?, NO3?, HCO3?, Br?, Na+, Mg2+, K+, Ca2+, Sr2+) and the stable isotopes (18O and 2H content), groundwater salinization in the investigated aquifer is caused by four main processes: (1) evaporite dissolution (2) cation exchange reactions (3) evaporation processes and (4) mixing with Sabkhas salt water causing salinity to increase in the central and southern parts of the basin. The radiogenic (3H) isotope data provided insight into the presence of significant contemporaneous recharge waters in the western part of the shallow aquifer. The movement of the tritiated water may have occurred according to the general flow path (NW–SE). When tritium was used in conjunction with the stable isotopes and chloride, the mixing process could be clearly identified, especially in the central part of the study area. 相似文献
The variations of the upper atmosphere air density during geomagnetic disturbances have been investigated by many authors. According to the analysis of satellite orbits, in most cases an increase in the air density may be observed when the indexAphas a maximum. Having ionospheric data from stations in Europe, Asia and Australia we might be able to study the global behaviour of the electron density in theF2 region during such geomagnetic disturbances when an increase of the air density had been observed. In these cases we found, that at the peak of the ionospheric layer, the electron density decreased 0–3 days later than theApmaximum. 相似文献
Micas from magmatic and metamorphic rocks differ from one another in chemical composition and in trace element content. The
chemical composition of micas is discussed in relation to their occurrence, paragenesis and sequence of crystallization. On
the basis of previous studies of the relationship between the physical properties and the chemical composition of 34 chemically
analysed micas, reliable physical methods have been established which permit identification of different mica varieties in
the same rock. Structural formulae and trace element content of micas from basic and granitic rocks, as well as from skarns,
schists, ortho- and paragneisses are discussed. The relationship between the components of the tetrahedral and octahedral
layers and of the interlayer are illustrated as ratios.
Poorly differentiated, hybrid and metasomatic rocks often contain more than one variety of mica. Some prophyritic basalts
and lamprophyres contain an early phlogopite which is paragenetically related to pyroxene phenocrysts and late biotite which
occurs in the groundmass and in the fractures as a result of the crystallization of residual magma. The biotitemuscovite assemblage
was observed in granodiorites, quartz-monzonites, schists and gneisses. In the albite-K-feldspar granites, muscovite predominates
and the biotite is usually altered.
The chemical composition of micas from metamorphic rocks depends on the grade of metamorphism and on the nature of associated
minerals. The biotite from paragneisses contains considerable quantities of octahedral alumina. Pre-metamorphic micas show
variable deficiencies of the (OH, F) group. The micas are useful minerals in determining the degree of differentiation and
subsequent alteration of igneous rocks.
The present study was carried out on the basis of 34 recent complete chemical analyses andca 100 X-ray fluorescence analyses.
Dedicated to Professor Dr.Carl W. Correns on the occasion of his 70th birthday. 相似文献
Stable isotopes (??2H, ??18O and ??13C) and radiocarbon (14C) have been used in conjunction with chemical data to evaluate recharge mechanisms and groundwater residence time, and to identify inter-aquifer mixing in the Djeffara multi-aquifer in semi-arid southeastern Tunisia. The southern part of this basin, the Djeffara of Medenine aquifer system, is comprised of two main aquifers of Triassic and Miocene sandstone. The Triassic aquifer presents two compartments; the first one (west of the Medenine fault system) is unconfined with a well-defined isotope fingerprint; the second compartment is deeper and confined. Multi-tracer results show groundwater of different origins, ages and salinities, and that tectonic features control groundwater flows. Fresh and brackish groundwater from the unconfined part of the Triassic aquifer was mostly recharged during the Holocene. The recharge rates of this aquifer, inferred by 14C ages, are variable and could reach 3.5?mm/year. Brackish water of the deep confined part of the Triassic aquifer has stable isotope composition and 14C content that indicates earlier recharge during late Pleistocene cold periods. Brackish to saline water of the Miocene aquifer presents variable isotope composition. Groundwater flowing through the Medenine fault system is mainly feeding the Miocene aquifer rather than the deep confined part of the Triassic aquifer. 相似文献
Detailed hydrogeochemical investigation has provided new information concerning the major factors and mechanisms controlling the groundwater chemistry of Chougafiya basin. The hydrogeochemical characteristics of groundwaters comprise three main types: Cl–SO4–Ca, Cl–SO4–Na and Cl–Na. Hydrochemical characteristics based on the bivariate diagrams of major (Cl?, SO42?, NO3?, HCO3?, Na+, Mg2+, K+ and Ca2+) and some trace (Br? and Sr2+) ions, mineral saturation indices and hierarchical cluster analysis indicate different origins of groundwater mineralization. The water–rock interaction (dissolution of evaporitic minerals), followed by cation exchange reactions with clay minerals, constitute the main processes that control groundwater salinization. However, the chemical composition of brackish groundwater in the central and southern parts of the study area is influenced by a mixing process with Sabkhas salt groundwater. The mixing proportions inferred from chloride mass balance prove that the contribution of Sabkhas groundwater to Quaternary aquifer ranges between 2.7 and 9.1 %. These intrusion rates reflect the progress of the saltwater–freshwater interface, which is mainly controlled by the piezometric level variation and the distance to the Sabkhas. 相似文献