Sensitive Ion‐Flotation Separation of Ag(I) Traces Using 2‐(2‐Methoxyphenyl)benzimidazole before Flame Atomic Absorption Spectrometric Determination in Water

A sensitive, reliable, and environmentally friendly method for simple separation and preconcentration of Ag(I) traces in aqueous samples is presented prior to their flame atomic absorption spectrometric determinations. At pH 7.0, Ag(I) was separated with 2‐(2‐methoxyphenyl)benzimidazole (MPBI) as a new complexing agent and floated after adding sodium dodecyl sulfate (SDS) as a foaming reagent. The floated layer was then dissolved in proper amount of concentrated nitric acid in methanol and introduced to the flame atomic absorption spectrometer (FAAS). The effects of pH, concentration of MPBI, type and amount of surfactant as the floating agent, type and amount of eluting agent, and influence of foreign ions on the recovery of the analyte ion were investigated. Also, using a nonlinear curve fitting method, the formation constant of 1.62 × 10⁶ was obtained for Ag(I)–MPBI complex. The analytical curve was linear in the range of 1.8 × 10^?7–1.7 × 10^?6 mol/L for determination of Ag(I). The relative standard deviation (RSD; N = 10) corresponding to 0.7 × 10^?6 mol/L of Ag(I), the limit of detection (10 blanks), and the enrichment factor were obtained as 1.7%, 2.9 × 10^?8 mol/L, and 43.0, respectively. The proposed procedure was then applied successfully for determination of silver ions in different water samples.     

Assessing building vulnerability to tsunami using the PTVA-3 model: A case study of Chabahar Bay,Iran

Chabahar Bay, in southeastern Iran, lies at the north of the Gulf of Oman and close to the Makran Subduction Zone, which makes it a region that is susceptible to tsunamis. This bay has an increasingly important role in Iran’s international trade, and therefore the assessment of the regional vulnerability to the effects of a tsunami is vital. Based on both the details of historical events and the results of numerical modeling of the propagation pattern of a tsunami in this region, this study assessed the vulnerability of buildings within the Chabahar Bay region to a tsunami event. The Papathoma Tsunami Vulnerability Assessment (PTVA) model was used to calculate a relative vulnerability index (RVI) for the affected buildings based on their physical and structural characteristics. The results showed that in a postulated worst-case-scenario tsunami event in the Chabahar Bay area, approximately 60 % of the residential buildings would be affected, a level of damage that is categorized as “Average” in the RVI classification. Overall, the economic losses related to the damage of residential buildings due to a tsunami in the Chabahar Bay area are anticipated to be the equivalent of US$ 16.5 million.     

Psychological sequels of flood on residents of southeast Caspian region

Flood is the most common disaster in the world and has acute or chronic health consequences including psychological sequels. Post-traumatic stress disorder (PTSD) is one of the main consequences. This study aimed to explore the psychological impacts (PTSD) in two flooded cities of Mazandaran Province, Neka and Behshahr, in the southeastern Caspian region that experienced flooding in 2012. A cross-sectional community-based study was performed on randomly selected samples of 400 individuals using GIS-based sampling from 139931 residents of the two flooded cities. The PTSS-10 questionnaire was used for data collection. The results showed that the overall stress disorder mean score among the participants was 2.59 out of 6. PTSD prevalence in the affected population was 64%. It was also found that stress scores significantly increased in younger people, male gender, the divorced, the widows or the widowers, and those who lost their properties (p < 0.05). Study findings showed that flood is a considerable stressor which develops PTSD. This finding should be taken into account in all four phases of disaster management cycle, and subsequently, specialized post-disaster mental health services must be provided for the afflicted population.     

Earthquake relocation in the Central Alborz region of Iran using a non-linear probabilistic method

In this study, we calculate accurate absolute locations for nearly 3,000 shallow earthquakes (≤20 km depth) that occurred from 1996 to 2010 in the Central Alborz region of northern Iran using a non-linear probabilistic relocation algorithm on a local scale. We aim to produce a consistent dataset with a realistic assessment of location errors using probabilistic hypocenter probability density functions. Our results indicate significant improvement in hypocenter locations and far less scattering than in the routine earthquake catalog. According to our results, 816 earthquakes have horizontal uncertainties in the 0.5–3.0 km range, and 981 earthquakes are relocated with focal-depth errors less than 3.0 km, even with a suboptimal network geometry. Earthquake relocated are tightly clustered in the eastern Tehran region and are mainly associated with active faults in the study area (the Mosha and Garmsar faults). Strong historical earthquakes have occurred along the Mosha and Garmsar faults, and the relocated earthquakes along these faults show clear north-dipping structures and align along east–west lineations, consistent with the predominant trend of faults within the study region. After event relocation, all seismicity lies in the upper 20 km of the crust, and no deep seismicity (>20 km depth) has been observed. In many circumstances, the seismicity at depth does not correlate with surface faulting, suggesting that the faulting at depth does not directly offset overlying sediments.     

A COMPARISON OF HYDROLOGY AND VEGETATION BETWEEN A CHANNELIZED STREAM AND A NONCHANNELIZED STREAM IN WESTERN TENNESSEE

The purpose of this study was to provide baseline data on floodplain forest structure, composition, and function that would be needed to predict and monitor the consequences of a proposed stream restoration project. This project would involve the “dechannelization” of Stokes Creek, a stream in western Tennessee that was channelized and leveed in the first half of the 1900s. To this end, we collected data on surface hydrology, soil redox potential (Eh), and the structure and composition of the floodplain vegetation of Stokes Creek. To place our findings into a regional context, we also collected comparable vegetation data from plots located along a nonchannelized stream reach of the Wolf River near Moscow, Tennessee. While hydrologic fluctuations of floodplain sites were synchronous with river dynamics for the Wolf River, the hydrology of floodplain sites at Stokes Creek was constrained by the influence of beaver dams, backflooding, and ponding of overland flow behind levees. Consequently, composition of the forest overstory, understory, and herbaceous strata was significantly different between the two sites. For example, Stokes Creek had a noticeable lack of cypress and tupelo sites, and a greater abundance of red maple. Analyses of size-class structure and woody debris quantity reinforced the existing differences between the more natural and human-impacted systems. While the current hydrology apparently has a negative affect on bottomland hardwoods, scattered regeneration stems and soil redox measurements indicate that a dechannelization effort that yielded lower water tables in the Stokes Creek floodplain potentially could increase bottomland hardwood establishment. [Key words: channelization, western Tennessee, bottomland hardwoods, hydrology.]     

Probabilistic Analysis of Ground Surface Vibration Due to Train Movement, a Case Study on Tehran Metro Line 4

Ground surface vibration produced by moving train is one of the most important aspects in urban areas. The purpose of this study is the probabilistic analysis of ground surface vibration, which is generated by metro transportations. For this reason, Tehran metro line 4 is considered as a case study. In this paper, at first, a new procedure is used to simulate train dynamic load. In the second step, based on the variation of geomechanical properties and train characteristics in Tehran metro line 4, more than 60 numerical models are simulated. The results of numerical simulations are analyzed by multivariate statistical technique and an equation for prediction of peak particle velocity (PPV) in the ground surface is presented. In the next step, probabilistic analysis is done using Monte Carlo Simulation (MCS). Finally, sensitivity of input data on ground surface vibration is discussed and the impact of geomechanical properties and train characteristics on the surface vibration is considered. Based on the probabilistic analysis, PPV in the surface region of Tehran metro line 4 is <2.76?mm/s with 95?% probability.     

Application of multivariate statistical methods to indicate the origin and geochemical behavior of potentially hazardous elements in sediment around the Sarcheshmeh copper mine,SE Iran

Multivariate statistical techniques, i.e., correlation coefficient analysis, principal components analysis (PCA), and hierarchical cluster analysis (CA), were applied to the total and water-soluble concentrations of potentially hazardous metals in sediments associated with the Sarcheshmeh mine, one of the largest Oligo-Miocene porphyry copper deposits in the world. The samples were analyzed for hazardous metal concentration levels by inductively coupled plasma mass spectrometry method. Results indicate that the contaminant metals As, Cd, Cu, Mo, S, Sb, Sn, Se, Pb, and Zn were positively correlated with the total concentrations. These hazardous metals also have strong association in the PCA and CA results. Different anthropic versus natural sources of contaminant metals were distinguished by using CA method. Water-soluble fraction of hazardous metals showed that the hydro-geochemical behavior of these metals in sediments is different considerably. Elements such as Cd, Co, Cr, Cu, Fe, Mn, Ni, S, and Zn are readily water soluble from contaminated samples, especially from evaporative mineral phases, while the release of As, Mo, Sb, and Pb into the water is limited by adsorption processes. Results obtained from the application of multivariate techniques on the water-soluble fraction data set show that the hazardous metals are categorized into three groups including (1) Ni, S, Co, Cu, Cr, and Fe; (2) Se, Mn, Cd, and Zn; and (3) Sb, As, Mo, and Sn. This classification describes the hydro-geochemical behavior of hazardous metals in water–sediment environments of the Sarcheshmeh porphyry copper mine and can be used as a basis in remedial and treatment strategies.     

The assessment of rock slope instability along the Khosh-Yeylagh Main Road (Iran) using a systems approach

The slope instability is connected to a large diversity of causative and triggering factors, ranging from inherent geological structure to the environmental conditions. Thus, assessment and prediction of slope failure hazard is a difficult and complex multi-parametric problem. In contrast to the analytic approaches, the systems approaches are able to consider infinite number of affecting parameters and assess the interactions of each couple of the parameters in the system. This paper presents a complete application of the rock engineering systems approach in prediction of the instability potential of rock slopes in 15 stations along a 20?km section of the Khosh-Yeylagh Main Road, Iran as the case study of the research. In this research, the main objective has been defining the principal causative and triggering factors responsible for the manifestation of slope instability phenomena, quantify their interactions, obtain their weighted coefficients, and calculate the slope instability index, which refers to the inherent potential instability of each slope of the examined region. The final results have been mapped to highlight the rock slopes susceptible to instability. Finally, as a preliminary validation on the utilization of systems approach in the study region, the stability of investigated rock slopes were analyzed using an empirical method and the results were compared. The comparisons showed a rather good coincidence between the given classes of two methods.     

Surfactant Enhance DLLME/FO‐LADS: Assay of Malachite Green Level in Aquatic Environment of Trout Fish

Malachite green (MG), a traditional agent used in aquaculture although is not approved; its low cost and high efficacy make illicit use likely. We developed a small‐scale, simple, and sensitive dispersive liquid–liquid microextraction procedure for the assay of trace amounts of MG in aquatic environment of Trout fish. Fiber optic‐linear array detection spectrophotometry with charge‐coupled device detector benefiting from a microcell was used for this purpose. The method is based on enhancement effect of an anionic surfactant on the extraction of MG in to very fine multidroplets of microextraction solvent which made assisted by disperser solvent. Under the optimum conditions, the enrichment factor 77.5 was obtained from a 5‐mL water sample. The calibration graph was linear up to 5 × 10^?7 mol L^?1 with detection limit of 1 × 10^?8 mol L^?1. The relative standard deviation for seven replicate measurements of 4 × 10^?7 and 5 × 10^?8 mol L^?1 of MG were 3.3 and 4.5%, respectively.     

Probabilistic rainfall thresholds for flood forecasting: evaluating different methodologies for modelling rainfall spatial correlation (or dependence)

Rainfall threshold (RT) method is one of the evolving flood forecasting approaches. When the cumulative rainfall depth for a given initial soil moisture condition intersects the threshold rainfall curve, the peak discharge is expected to be equal or greater than the threshold discharge for flooding at the target site. Besides the total rainfall depth, spatial and temporal distribution of rainfall impacts the flood peak discharge and the time to peak. To revisit a previous study conducted by the authors, in which spatially independent rainfall pattern was assumed, the spatial distribution of rainfall was simulated following a Monte Carlo approach. The structure of the spatial dependence among sub‐watersheds' rainfalls was taken into account under three different scenarios, namely independent, bivariate copula (2copula) and multivariate Gaussian copula (MGC). For each set of generated random dimensionless rainfalls, the probabilistic RT curves were derived for dry moisture condition. Results were evaluated with both historical and simulated events. For the simulated events, threshold curves were assessed by means of categorical statistics, such as hit rate, false rate and critical success index (CSI). Results revealed that the best performance based on the CSI criterion corresponded to 50% curve in 2copula and MGC scenarios as well as 90% curve in the independent scenario. The recognition of 50% curve in 2copula and MGC scenarios is in agreement with our expectations that the mean probable curve should have the best performance. Moreover, the proposed inclusion of spatially dependent rainfall scenario improved the performance of RT curves by about 25% in comparison with the presumed spatially uniform rainfall scenario. Copyright © 2011 John Wiley & Sons, Ltd.