Laboratory kinetics of C2H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.     

Symplectic Mappings of Co-orbital Motion in the Restricted Problem of Three Bodies

The dynamics of co-orbital motion in the restricted three-body problem are investigated by symplectic mappings. Analytical and semi-numerical mappings have been developed and studied in detail. The mappings have been tested by numerical integration of the equations of motion. These mappings have been proved to be useful for a quick determination of the phase space structure reflecting the main characteristics of the dynamics of the co-orbital problem.     

Isolation of resonance in acoustic backscatter from elastic targetsusing adaptive estimation schemes

It has been shown that at certain frequencies the acoustic backscatter from elastic targets exhibits certain resonance behavior which closely relates to the physical properties of the target such as dimension, thickness, and composition. The purpose of this paper is to develop an automated approach for identifying the presence of resonance in the acoustic backscatter from an unknown underwater target by isolating the resonance part from the specular contribution. An adaptive transversal filter structure is used to estimate the specular part of the backscatter and consequently the error signal would provide an estimate of the resonance part. An important aspect of this scheme lies in the fact that it does not require an underlying model for the elastic return. The adaptation rule is based upon fast recursive least squares (RLS) learning. The approach taken in this paper is general in the sense that it can be applied to targets of unknown geometry and thickness and, further, does not require any a priori information about the target and/or the environment. Test results on acoustic data are presented which indicate the effectiveness of the proposed approach     

The MPE X-ray test facility PANTER: Calibration of hard X-ray (15–50 kev) optics

The Max-Planck-Institut für extraterrestrische Physik (MPE) in Garching, Germany, uses its large X-ray beam line facility PANTER for testing X-ray astronomical instrumentation. A number of telescopes, gratings, filters, and detectors, e.g. for astronomical satellite missions like Exosat, ROSAT, Chandra (LETG), BeppoSAX, SOHO (CDS), XMM-Newton, ABRIXAS, Swift (XRT), have been successfully calibrated in the soft X-ray energy range (< 15keV). Moreover, measurements with mirror test samples for new missions like ROSITA and XEUS have been carried out at PANTER. Here we report on an extension of the energy range, enabling calibrations of hard X-ray optics over the energy range 15–50 keV. Several future X-ray astronomy missions (e.g., Simbol-X, Constellation-X, XEUS) have been proposed, which make use of hard X-ray optics based on multilayer coatings. Such optics are currently being developed by the Osservatorio Astronomico di Brera (OAB), Milano, Italy, and the Harvard-Smithsonian Center for Astrophysics (CfA), Cambridge, MA, USA. These optics have been tested at the PANTER facility with a broad energy band beam (up to 50 keV) using the XMM-Newton EPIC-pn flight spare CCD camera with its good intrinsic energy resolution, and also with monochromatic X-rays between C-K (0.277 keV) and Cu-Kα (8.04 keV). PACS: 95.55.Ka, 95.55.Aq, 41 50.+h, 07.85.Fv     

Spatial measurements of stream baseflow,a relevant method for aquifer characterization and permeability evaluation. Application to a hard‐rock aquifer,the Oman ophiolite

The structure, functioning and hydrodynamic properties of aquifers can be determined from an analysis of the spatial variability of baseflow in the streams with which they are associated. Such analyses are based on simple low‐cost measurements. Through interpreting the hydrological profiles (Q = f(A)) it is possible to locate the aquifer(s) linked to the stream network and to determine the type of interrelated flow, i.e. whether the stream drains or feeds the aquifer. Using an analytical solution developed for situations with a positive linear relationship, i.e. where the baseflow increases linearly with increasing catchment size, it is also possible to estimate the permeability of the aquifer(s) concerned at catchment scale. Applied to the hard‐rock aquifers of the Oman ophiolite, this method shows that the ‘gabbro’ aquifer is more permeable than the ‘peridotite’ aquifer. As a consequence the streams drain the peridotites and ‘leak’ into the gabbro. The hydrological profiles within the peridotite are linear and positive, and indicate homogeneity in the hydrodynamic properties of these formations at the kilometre scale. The permeability of the peridotite is estimated at 5 · 10^?7 to 5 · 10^?8 m/s. Copyright © 2004 John Wiley & Sons, Ltd.