Groundwater age,mixing and flow rates in the vicinity of large open pit mines,Pilbara region,northwestern Australia

Determining groundwater ages from environmental tracer concentrations measured on samples obtained from open bores or long-screened intervals is fraught with difficulty because the sampled water represents a variety of ages. A multi-tracer technique (Cl, ¹⁴C, ³H, CFC-11, CFC-12, CFC-113 and SF₆) was used to decipher the groundwater ages sampled from long-screened production bores in a regional aquifer around an open pit mine in the Pilbara region of northwest Australia. The changes in tracer concentrations due to continuous dewatering over 7 years (2008–2014) were examined, and the tracer methods were compared. Tracer concentrations suggest that groundwater samples are a mixture of young and old water; the former is inferred to represent localised recharge from an adjacent creek, and the latter to be diffuse recharge. An increase in ¹⁴C activity with time in wells closest to the creek suggests that dewatering of the open pit to achieve dry mining conditions has resulted in change in flow direction, so that localised recharge from the creek now forms a larger proportion of the pumped groundwater. The recharge rate prior to development, calculated from a steady-state Cl mass balance, is 6 mm/y, and is consistent with calculations based on the ¹⁴C activity. Changes in CFC-12 concentrations with time may be related to the change in water-table position relative to the depth of the well screen.     

From nappe stacking to exhumation: Cretaceous tectonics in the Apuseni Mountains (Romania)

International Journal of Earth Sciences - New Ar–Ar muscovite and Rb–Sr biotite age data in combination with structural analyses from the Apuseni Mountains provide new constraints on...     

Decadal Changes in Water Quality and Net Productivity of a Shallow Danish Estuary Following Significant Nutrient Reductions

We utilized an extensive data set (1977–2013) from a water quality monitoring program to investigate the recovery of a Danish estuary following large reductions in total phosphorus (TP) and total nitrogen (TN) loading. Monthly rates of net transport and biogeochemical transformation of dissolved inorganic nitrogen (DIN) and phosphorus (DIP) were computed in two basins of the estuary using a box model approach, and oxygen-based rates of net ecosystem production (NEP) were determined. Since 1990, nutrient loading was reduced by 58 % for nitrogen and 80 % for phosphorus, causing significant decreases in DIN (60 %) and DIP (85 %) concentrations. Reductions in nutrient loadings and concentrations reduced annual chlorophyll levels by 50 % in the inner estuary and improved Secchi depth by approximately 1 m during the same period, particularly in the summer period. In the outer, deeper region of the estuary trends in water quality was less evident. Improvements in the inner estuary were strongly coupled to declines in DIN. Thresholds of DIN and DIP concentrations limiting phytoplankton growth indicated that both regions of the estuary were nitrogen limited. NEP rates indicated the development of more net autotrophic conditions over time that were likely associated with higher benthic primary production stimulated by improved light conditions. Box model computations revealed a modest reduction in summer net production of DIP over time, despite the persistence of elevated fluxes for several years after external loads were reduced. Since the mid-1990s, nutrient loading and transformation were stable while nutrient concentrations continued to decline and water quality improved in the inner estuary. The oligotrophication trajectory involved an initial fast transformation and modest retention of nutrients followed by a gradual decline in the rate of improvement towards a new stable condition.     

Chronology of Quaternary terrace deposits at the locality Hohle Gasse (Pratteln,NW Switzerland)

The Quaternary stratigraphy of the Alpine Foreland consists of distinct terrace levels, which have been assigned to four morphostratigraphic units: Höhere (Higher) Deckenschotter, Tiefere (Lower) Deckenschotter, Hochterrasse (High Terrace) and Niederterrasse (Lower Terrace). Here, we focus on the terrace gravels at Hohle Gasse, SSE of Pratteln near Basel, which are mapped as Tiefere Deckenschotter. Petrographic and morphometric data established from clasts allowed to infer the transport mechanisms and sources of the gravels. Sedimentological analyses indicate that the gravels were transported by a braided river and deposited in a distal glaciofluvial setting. In addition, it can be shown that the majority of the clasts display multiple reworking and only a minority maintained a distinct glaciofluvial shape. Cosmogenic multi-isotope dating using ¹⁰Be and ³⁶Cl allowed direct dating of the sediments at the study site. A depth-profile age of \(2 70_{ - 1 90}^{ + 8 30}\) ka for ¹⁰Be was achieved for the deposits at Hohle Gasse. Unfortunately, no age could be modelled from the ³⁶Cl concentrations as the blank correction was too high. Furthermore, this age proves that the studied terrace level should be assigned to the morphostratigraphic unit Hochterrasse.     

GGR Biennial Critical Review: Analytical Developments Since 2014

This GGR biennial critical review covers developments and innovations in key analytical methods published since January 2014, relevant to the chemical, isotopic and crystallographic characterisation of geological and environmental materials. In nine selected analytical fields, publications considered to be of wide significance are summarised, background information is provided and their importance evaluated. In addition to instrumental technologies, this review also presents a summary of new developments in the preparation and characterisation of rock, microanalytical and isotopic reference materials, including a précis of recent changes and revisions to ISO guidelines for reference material characterisation and reporting. Selected reports are provided of isotope ratio determinations by both solution nebulisation MC‐ICP‐MS and laser ablation‐ICP‐MS, as well as of radioactive isotope geochronology by LA‐ICP‐MS. Most of the analytical techniques elaborated continue to provide new applications for geochemical analysis; however, it is noted that instrumental neutron activation analysis has become less popular in recent years, mostly due to the reduced availability of nuclear reactors to act as a neutron source. Many of the newer applications reported here provide analysis at increasingly finer resolution. Examples include atom probe tomography, a very sensitive method providing atomic scale information, nanoscale SIMS, for isotopic imaging of geological and biological samples, and micro‐XRF, which has a spatial resolution many orders of magnitude smaller than conventional XRF.     

Influence of Groundwater Hydraulic Gradient on Bank Storage Metrics

The hydraulic gradient between aquifers and rivers is one of the most variable properties in a river/aquifer system. Detailed process understanding of bank storage under hydraulic gradients is obtained from a two‐dimensional numerical model of a variably saturated aquifer slice perpendicular to a river. Exchange between the river and the aquifer occurs first at the interface with the unsaturated zone. The proportion of total water exchanged through the river bank compared to the river bed is a function of aquifer hydraulic conductivity, partial penetration, and hydraulic gradient. Total exchange may be estimated to within 50% using existing analytical solutions provided that unsaturated zone processes do not strongly influence exchange. Model‐calculated bank storage is at a maximum when no hydraulic gradient is present and increases as the hydraulic conductivity increases. However, in the presence of a hydraulic gradient, the largest exchange flux or distance of penetration does not necessarily correspond to the highest hydraulic conductivity, as high hydraulic conductivity increases the components of exchange both into and out of an aquifer. Flood wave characteristics do not influence ambient groundwater discharge, and so in large floods, hydraulic gradients must be high to reduce the volume of bank storage. Practical measurement of bank storage metrics is problematic due to the limitations of available measurement technologies and the nested processes of exchange that occur at the river‐aquifer interface. Proxies, such as time series concentration data in rivers and groundwater, require further development to be representative and quantitative.     

Recent shifts in coastline change and shoreline stabilization linked to storm climate change

Since cuspate coastlines are especially sensitive to changes in wave climate, they serve as potential indicators of initial responses to changing wave conditions. Previous work demonstrates that Cape Hatteras and Cape Lookout, North Carolina, which are largely unaffected by shoreline stabilization efforts, have become increasingly asymmetric over the past 30 years, consistent with model predictions for coastline response to increases in Atlantic Ocean summer wave heights and resulting changes in the distribution of wave‐approach angles. Historic and recent shoreline change observations for Cape Fear, North Carolina, and model simulations of coastline response to an increasingly asymmetric wave climate in the presence of beach nourishment, produce comparable differences in shoreline change rates in response to changes in wave climate. Results suggest that the effect of beach nourishment is to compensate for – and therefore to mask – natural responses to wave climate change that might otherwise be discernible in patterns of shoreline change alone. Therefore, this case study suggests that the effects of wave climate change on human‐modified coastlines may be detectable in the spatial and temporal patterns of shoreline stabilization activities. Similar analyses of cuspate features in areas where the change in wave climate is less pronounced (i.e. Fishing Point, Maryland/Virginia) and where local geology appears to exert control on coastline shape (i.e. Cape Canaveral, Florida), suggest that changes in shoreline configuration that may be arising from shifting wave climate are currently limited to sandy wave‐dominated coastlines where the change in wave climate has been most pronounced. However, if hurricane‐generated wave heights continue to increase, large‐scale shifts in patterns of erosion and accretion will likely extend beyond sensitive cuspate features as the larger‐scale coastline shape comes into equilibrium with changing wave conditions. Copyright © 2014 John Wiley & Sons, Ltd.     

Prograded foredunes of Western Australia's macro‐tidal coast – implications for Holocene sea‐level change and high‐energy wave impacts

The Holocene evolution of the Canning Coast of Western Australia has largely been overlooked so far mainly due to its remoteness and low population density. We report on new data from a sequence of foredunes inside the macro‐tidal Admiral Bay, 110 km southwest of Broome. Based on sediment cores, differential global positioning system (dGPS)‐based elevation transects, and stratigraphical analyses on outcrops of the relict foredunes, we aim at reconstructing Holocene coastal changes and relative sea levels (RSLs), as well as identifying and dating imprints of extreme‐wave events. Sedimentary analyses comprise the documentation of bedding structures, foraminiferal content and macrofaunal remains, grain size distribution, and organic matter. The chronological framework is based on 26 carbon‐14 accelerator mass spectrometry (¹⁴C‐AMS) datings. Marine flooding of the pre‐Holocene surface landward of the 2.5 km‐wide foredune barriers occurred 7400–7200 cal bp , when mangroves colonized the area. After only 200–400 years, a high‐energy inter‐tidal environment established and prevailed until c. 4000 cal bp , before turning into the present supralittoral mudflat. During that time, coastal regression led to beach progradation and the formation of aligned foredunes. Drivers of progradation were a stable RSL or gradual RSL fall after the mid‐Holocene and a positive sand budget. The foredunes overlie upper beach deposits located up to >2 m above the present upper beach level and provide evidence for a higher mid‐Holocene RSL. Discontinuous layers of coarse shells and sand are intercalated in the foredunes, indicating massive coastal flooding events. One such layer was traced over three dune ridges and dated to c. 1700–1550 cal bp . However, it seems that most tropical cyclones induce net erosion rather than deposition at aligned foredunes and thus, they are only suitable for reconstructing temporal variability if erosional features or sedimentation reliably tied to these events can be identified and dated accurately. Copyright © 2014 John Wiley & Sons, Ltd.     

Induced Temperature Gradients to Examine Groundwater Flowpaths in Open Boreholes

Techniques for characterizing the hydraulic properties and groundwater flow processes of aquifers are essential to design hydrogeologic conceptual models. In this study, rapid time series temperature profiles within open‐groundwater wells in fractured rock were measured using fiber optic distributed temperature sensing (FO‐DTS). To identify zones of active groundwater flow, two continuous electrical heating cables were installed alongside a FO‐DTS cable to heat the column of water within the well and to create a temperature difference between the ambient temperature of the groundwater in the aquifer and that within the well. Additional tests were performed to examine the effects of pumping on hydraulic fracture interconnectivity around the well and to identify zones of increased groundwater flow. High‐ and low‐resolution FO‐DTS cable configurations were examined to test the sensitivities of the technique and compared with downhole video footage and geophysical logging to confirm the zones of active groundwater flow. Two examples are presented to demonstrate the usefulness of this new technique for rapid characterization of fracture zones in open boreholes. The combination of the FO‐DTS and heating cable has excellent scope as a rapid appraisal tool for borehole construction design and improving hydrogeologic conceptual models.