旋转流地转适应过程与能量转换规律

利用一维线性浅水模式从一个比较普遍的角度对地转适应过程中能量转换的特点进行分析。中首先考虑了两类不同的初始不平衡流的适应问题。一个是Gill所采用的质量不平衡模型，即初始场是静止的，只有水面扰动；另一个是Rossby中所考虑的动量不平衡模型，其初始不平衡流中只有风场的扰动，对这两个模型的适应过程而言，一个显的 特点就是能量转换率始终不会大于1／2或小于0，即适应过程中有位（动）能的释放和向动（位）能的转换，但释放出的能量最多只有其中的一半可以保留在最后的平衡场中。另外，本对任意初始不平衡流适应过程中的能量学特征也进行了分析，指出对于偏差场（相对于一定基本态）的动能和位能而言，上述能量转换关系依然成立。     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

Impact of the North Atlantic Oscillation on Middle Eastern Climate and Streamflow

Interannual to decadal variations in Middle Eastern temperature, precipitationand streamflow reflect the far-field influence of the North Atlantic Oscillation (NAO), a dominant mode of Atlantic sector climate variability. Using a new sea surface temperature (SST) based index of the NAO and availablestreamflow data from five Middle Eastern rivers, we show that the first principal component of December through March streamflow variability reflects changes in the NAO. However, Middle East rivers have two primary flooding periods.The first is rainfall-driven runoff from December through March, regulated on interannual to decadal timescales by the NAO as reflected in local precipitation and temperature.The second period, from April through June, reflects spring snowmelt and contributes in excess of 50% of annual runoff.This period, known locally as the khamsin, displays no significantNAO connections and a less direct relationship with local climatic factors, suggesting that streamflow variability during this period reflects land-cover change, possibly related to agriculture and hydropower generation, and snowmelt.     

Effect of KCl on melting in the Mg<Subscript>2</Subscript>SiO<Subscript>4</Subscript>–MgSiO<Subscript>3</Subscript>–H<Subscript>2</Subscript>O system at 5 GPa

To examine the effect of KCl-bearing fluids on the melting behavior of the Earth’s mantle, we conducted experiments in the Mg₂SiO₄–MgSiO₃–H₂O and Mg₂SiO₄–MgSiO₃–KCl–H₂O systems at 5 GPa. In the Mg₂SiO₄–MgSiO₃–H₂O system, the temperature of the fluid-saturated solidus is bracketed between 1,200–1,250°C, and both forsterite and enstatite coexist with the liquid under supersolidus conditions. In the Mg₂SiO₄–MgSiO₃–KCl–H₂O systems with molar Cl/(Cl + H₂O) ratios of 0.2, 0.4, and 0.6, the temperatures of the fluid-saturated solidus are bracketed between 1,400–1,450°C, 1,550–1,600°C, and 1,600–1,650°C, respectively, and only forsterite coexists with liquid under supersolidus conditions. This increase in the temperature of the solidus demonstrates the significant effect of KCl on reducing the activity of H₂O in the fluid in the Mg₂SiO₄–MgSiO₃–H₂O system. The change in the melting residues indicates that the incongruent melting of enstatite (enstatite = forsterite + silica-rich melt) could extend to pressures above 5 GPa in KCl-bearing systems, in contrast to the behavior in the KCl-free system.     

Paragenesis of unusual Fe-cordierite (sekaninaite)-bearing paralava and clinker from the Kuznetsk coal basin,Siberia, Russia

Sekaninaite (X_Fe > 0.5)-bearing paralava and clinker are the products of ancient combustion metamorphism in the western part of the Kuznetsk coal basin, Siberia. The combustion metamorphic rocks typically occur as clinker beds and breccias consisting of vitrified sandstone–siltstone clinker fragments cemented by paralava, resulting from hanging-wall collapse above burning coal seams and quenching. Sekaninaite–Fe-cordierite (X_Fe = 95–45) is associated with tridymite, fayalite, magnetite, ± clinoferrosilite and ±mullite in paralava and with tridymite and mullite in clinker. Unmelted grains of detrital quartz occur in both rocks (<3 vol% in paralavas and up to 30 vol% in some clinkers). Compositionally variable siliceous, K-rich peraluminous glass is <30% in paralavas and up to 85% in clinkers. The paralavas resulted from extensive fusion of sandstone–siltstone (clinker), and sideritic/Fe-hydroxide material contained within them, with the proportion of clastic sediments ≫ ferruginous component. Calculated dry liquidus temperatures of the paralavas are 1,120–1,050°C and 920–1,050°C for clinkers, with calculated viscosities at liquidus temperatures of 10^1.6–7.0 and 10^7.0–9.8 Pa s, respectively. Dry liquidus temperatures of glass compositions range between 920 and 1,120°C (paralava) and 920–960°C (clinker), and viscosities at these temperatures are 10^9.7–5.5 and 10^8.8–9.7 Pa s, respectively. Compared with worldwide occurrences of cordierite–sekaninaite in pyrometamorphic rocks, sekaninaite occurs in rocks with X_Fe (mol% FeO/(FeO + MgO)) > 0.8; sekaninaite and Fe-cordierite occur in rocks with X_Fe 0.6–0.8, and cordierite (X_Fe < 0.5) is restricted to rocks with X_Fe < 0.6. The crystal-chemical formula of an anhydrous sekaninaite based on the refined structure is | \textK_0.02 |(\textFe_1.54^{2 +} \textMg_0.40 \textMn_0.06 )_{\Upsigma 2.00}^M [(\textAl_1.98 \textFe_0.02^{2 +} \textSi_1.00 )_{\Upsigma 3.00}^T1 (\textSi_3.94 \textAl_2.04 \textFe_0.02^{2 +} )_{\Upsigma 6.00}^T2 \textO₁₈ ]. \left| {{\text{K}}_{0.02} } \right|({\text{Fe}}_{1.54}^{2 + } {\text{Mg}}_{0.40} {\text{Mn}}_{0.06} )_{\Upsigma 2.00}^{M} [({\text{Al}}_{1.98} {\text{Fe}}_{0.02}^{2 + } {\text{Si}}_{1.00} )_{\Upsigma 3.00}^{T1} ({\text{Si}}_{3.94} {\text{Al}}_{2.04} {\text{Fe}}_{0.02}^{2 + } )_{\Upsigma 6.00}^{T2} {\text{O}}_{18} ].     

Response of xenotime to prograde metamorphism

Xenotime is a widespread accessory mineral in lower greenschist to upper amphibolite facies metasedimentary rocks from the Palaeoproterozoic Mount Barren Group, southwestern Australia. Xenotime is closely associated with detrital zircon, commonly forming syntaxial outgrowths, in samples of sandstone, micaceous quartzite, slate, phyllite, garnet-bearing semi-pelites, and in kyanite-, garnet-, and staurolite-bearing mica schists. In situ geochronology of xenotime from lower greenschist sandstones has previously yielded multiple U–Pb ages with peaks at ~2.0, ~1.7, and ~1.65 Ga, interpreted to represent the age of detritus, early diagenesis, and a later thermal event, respectively. New U–Pb dating of xenotime in slate yields a major population at ~1.7 Ga with a minor population at ~1.2 Ga, reflecting diagenetic and metamorphic growth, respectively, whereas xenotime in phyllite forms a minor age population at ~1.7 Ga and a main peak at ~1.2 Ga. Mid-greenschist facies semi-pelitic schists (quartz-muscovite-garnet) contain xenotime that formed before 1.8 Ga and at 1.2 Ga, representing detrital and peak metamorphic ages, respectively. Xenotime in samples of amphibolite facies schist (650°C and ~8 kbars) yields U–Pb ages of ~1.2 Ga, coinciding with the time of peak metamorphism. A single analysis of a xenotime core from an amphibolite facies schist gave an age of ~1.8 Ga, consistent with the presence of detrital xenotime. Our results suggest that detrital xenotime may be preserved under greenschist facies conditions, but is largely replaced during upper amphibolite facies conditions. Detrital xenotime is replaced through dissolution–reprecipitation reactions forming compositionally distinct rims during greenschist and amphibolite facies metamorphism at 1.2 Ga. Diagenetic xenotime is present in lower greenschist facies samples, but was not observed in metasedimentary rocks that had experienced temperatures above mid-greenschist facies metamorphism (450°C). The apparent disappearance of detrital and diagenetic xenotime and appearance of metamorphic xenotime during prograde metamorphism indicates that some of the yttrium, heavy rare earth elements, and phosphorus needed for metamorphic xenotime growth are probably derived from the replacement of detrital and diagenetic xenotime.     

Barium-rich fluids and melts in a subduction environment (La Corea and Sierra del Convento mélanges,eastern Cuba)

Whole-rock compositions of muscovite-bearing amphibolite, trondhjemite, pegmatite and quartz-muscovite rocks from Sierra del Convento and La Corea mélanges (eastern Cuba), as well as mineralogy, record complex circulation of Ba-rich fluids and melts in the subduction environment. Partial melting of fluid-fluxed, MORB-derived amphibolite produced trondhjemite magmas that crystallized at depth, in some cases evolving into pegmatites. Qtz-Ms rocks probably crystallized from primary fluids derived from subducted sediments. All these rocks have elevated concentrations of large-ion lithophile elements, especially Ba (up to 11,810 ppm), presumably released from slab sediments by fluids and/or melts. Fluid–rock interaction produced crystallization of phengite in parental amphibolites. The phengite crystallized in all types of rocks is rich in Ba, with concentric zoning, characterized by Ba-rich cores and Ba-poor rims, indicating a compatible behaviour of Ba in the studied systems. Zoning in phengite is governed primarily by the celadonite (tschermak) exchange vector ((Mg,Fe)Si-(Al)_-2), with more moderate contributions of the celsian (BaAl-(KSi)_-1) and paragonite (NaK_-1) exchange vectors. Late remobilization of Ba at relatively low temperature formed retrograde celsian. The compatible behaviour of Ba in the studied rocks strengthens the importance of the stability of phengite for the transfer of LIL elements from the subduction to the volcanic arc environments.     

Evolution of a Carboniferous carbonate-hosted sphalerite breccia deposit,Isle of Man

A newly discovered, extensive sphalerite-bearing breccia (~7.5 wt.% Zn) is hosted in dolomitised Carboniferous limestones overlying Ordovician–Silurian metasedimentary rocks on the Isle of Man. Although base metal sulphide deposits have been mined historically on the island, they are nearly all quartz vein deposits in the metamorphic basement. This study investigates the origin of the unusual sphalerite breccia and its relationship to basement-hosted deposits, through a combination of petrographic, cathodoluminescence, fluid inclusion, stable isotope and hydrogeologic modelling techniques. Breccia mineralisation comprises four stages, marked by episodes of structural deformation and abrupt changes in fluid temperature and chemistry. In stage I, high-temperature (T _h > 300°C), high-salinity (20–45 wt.% equiv. NaCl) fluid of likely basement origin deposited a discontinuous quartz vein. This vein was subsequently dismembered during a major brecciation event. Stages II–IV are dominated by open-space filling sphalerite, quartz and dolomite, respectively. Fluid inclusions in these minerals record temperatures of ~105–180°C and salinities of ~15–20 wt.% equiv. NaCl. The δ³⁴S values of sphalerite (6.5–6.9‰ Vienna-Canyon Diablo troilite) are nearly identical to those of ore sulphides from mines in the Lower Palaeozoic metamorphic rocks. The δ¹⁸O values for quartz and dolomite indicate two main fluid sources in the breccia’s hydrothermal system, local Carboniferous-hosted brines (~0.5–6.0‰ Vienna standard mean ocean water) and basement-involved fluids (~5.5–11.5‰). Ore sulphide deposition in the breccia is compatible with the introduction and cooling of a hot, basement-derived fluid that interacted with local sedimentary brines.     

The ice sheet dynamics around Dakshin Gangotri glacier,Schirmacher Oasis,East Antarctica vis-à-vis topography and meteorological parameters

Recession of the snout of Dakshin Gangotri glacier in the western part of Schirmacher Oasis, East Antarctica has been recorded over two decades. However, the rate of retreat is not uniform and varies at different locations. The ice wall forming the western flank of the glacier has shown an average retreat of 17.07 m between 2001 and 2009 while the snout had gone back by 6.94 m (average) during the same period. Before 2001, the snout had shown a complete recession of 3.13 m (average). The snout occupies valley area receiving less amount of solar radiation as compared to the western wall, which is a vertical cliff receiving maximum amount of solar radiation. The notable difference in the rate of recession in different parts of the Dakshin Gangotri glacier overriding Schirmacher Oasis can be attributed to combined effect of natural factors, including meteorological parameters, ice sheet dynamics and geomorphology of that area.     

Indirect Effects of Salinity and Temperature on Kuwait’s Shrimp Stocks

Discharge of the Shatt Al-Arab is believed to be a dominating component of the northern Arabian Gulf’s ecology and largely responsible for productivity of Kuwait’s fisheries. With major construction of dams on the Tigris and Euphrates Rivers in Turkey, river discharge has been substantially reduced, and flooding essentially eliminated. We attempted to relate river flow and shrimp landings indirectly by correlating 19 years of salinity and temperature data from Kuwait’s waters with corresponding annual shrimp landings. For green tiger prawns (Penaeus semisulcatus), the combination of October salinities and January temperatures provided the best correlation (r = 0.67) with landings in the following shrimping season. For the combined landings of jinga and kiddi shrimps (Metapenaeus affinis and Parapenaeopsis stylifera, respectively), December salinity during season and May temperature prior to season resulted in the best correlation (r = 0.87). Landings of these two species also correlated well with spring and summer temperatures. Under normal conditions, late winter or early spring temperatures prior to fishing season influence recruitment of the green tiger prawn, whereas December salinities during harvest season influence the abundance of jinga–kiddi shrimps. With further reductions in the Shatt Al-Arab discharge and the elimination of flood events, Kuwait’s shrimp landings will most likely decrease over time.