钨、锡流-熔分配实验结果及其矿床成因意义

本文用实验确定了钨、锡在成分不同的花岗质熔体相与共存水热流体相的流-熔分配系数(D_(Me)~(V/L))及其与介质溶液(NaF,KF,HF,NaCl等水溶液)摩尔浓度间的函数关系。实验结果表明,钨、锡的分配行为明显不同。在相同条件下,随体系的不同,D_W~(V/L)比D_(Sn)~(V/L)大几倍至二十倍。钠和钾对钨、锡的流-熔分配行为的影响基本相同,而氟和氯对钨、锡的分配行为的影响相差甚远,花岗质熔体的主成分对D_W~(V/L)和D_(Sn)~(V/L)有复杂的影响。利用这些结果探讨与花岗岩有关的钨、锡矿床的成矿机理,得出了一些与前人不同的新认识。     

煎茶岭镍矿床成矿作用特征

煎岭镍矿与同类矿床相比,具有特殊的地质、地球化学物征，是一种特殊类型镍矿。本矿床流体包裹体同位素特征，表现出成矿体为岩浆与地层两端元混合趋势，成矿流体分属于Mg2+-Ca2+-Na+-F-(Cl-)型。根据 Pb、Sr、O、H、C 同位素及 REE资料，作者认为该镍矿的形成与后期酸性岩浆活动有密切关系，后期岩浆活动为成矿提供热力与热液，使成矿元素活化迁移、富集。本文最后提出了初步的成矿模式。     

漳州热田地下热水的循环深度

漳州热田是我国东南沿海地区目前所见温度(121.5℃)最高的一个。热田地热地质、地球化学以及地温场的研究结果表明,漳州热田属于深循环对流型热田。为了计算热田的热水循环深度,本文采用管道模型的方法,利用热田中心钻孔的测温资料计算地下热水上涌的流速,利用热田内水化学资料计算热储温度,然后用图解法求出漳州热田热水的循环深度为3.4—4.0 km,为漳州热田的成因分析和热水资源的评价提供了依据。     

Chemistry of alkali extraction of brown coals—I. Kinetics, characterisation and implications to coalification

Three Australian brown coals have been separated into humin and humic acid fractions and studied by high resolution solid state ¹³C NMR spectroscopy and Fourier transform IR spectroscopy. The aromatic rings of the humic acids are highly substituted showing that extensive cross linking must have occurred during formation from wood lignin and tannin. However, the humins contain more aliphatic carbon and hydrogen than the corresponding humic acids. This shows that little cross linking has occurred with other components of the brown coal such as resins, waxes cutin and algal detritus, and cross linking has not rendered the aromatics alkali insoluble. The kinetics of extraction are complex and not simple first order. This is reflected in the chemical composition of the humic acid which is extraction temperature dependent. We also observed that there is a conversion of aromatic carbon to aliphatic carbon and gas during extraction, probably by alkaline oxidation, resulting in ring opening. A range of suitable model compounds have been studied to confirm this finding. Such a mechanism may account for the modification of lignin in oxidising environments such as those occurring in the initial stages of coalification (lignite or brown coal formation) and in soils.     

乾安县浅层高氟地下水的分布规律及成因的初步探讨

本文主要阐述了乾安县浅层高氟地下水的分布规律;探讨了浅层高氟地下水的成因与构造、地貌、古气候、地层岩性和水文地质条件的关系,从而闸明了广泛分布的湖沼相松散沉积物的组成和水文地质条件是本区浅层高氟地下水的主要原因。     

S,Pb, C and O isotopic compositions and ore genesis of the strata-bound polymetallic sulfide deposits in central Inner Mongolia,China

The strata-bound Cu−Pb−Zn polymetallic sulfide deposits occur in metamorphic rocks of greenschist phase of the middle-upper Proterozoic Langshan Group in central Inner Mongolia. δ³⁴S values for sulfides range from −3.1‰ to +37.3‰, and an apparent difference is noticed between vein sulfides and those in bedded rocks. For example, δ³⁴S values for bedded pyrite range from +10.6‰ to +20.0‰, while those for vein pyrite vary from −3.1‰ to +14.1‰. δ³⁴S of bedded pyrrhotite is in the range +7.9‰–+23.5‰ in comparison with +6.5‰–+17.1‰ for vein pyrrhotite. The wide scatter of δ³⁴S and the enrichment of heavier sulfur indicate that sulfur may have been derived from H₂S as a result of bacterial reduction of sulfates in the sea water. Sulfur isotopic composition also differs from deposit to deposit in this area because of the difference in environment in which they were formed. The mobilization of bedded sulfides in response to regional metamorphism and magmatic intrusion led to the formation of vein sulfides. δ¹⁸O and δ¹³C of ore-bearing rocks and wall rocks are within the range typical of ordinary marine facies, with the exception of lower values for ore-bearing marble at Huogeqi probably due to diopsidization and tremalitization of carbonate rocks. Pb isotopic composition is relatively stable and characterized by lower radio-genetic lead. The age of basement rocks was calculated to be about 23.9 Ma and ore-forming age 7.8 Ma.²⁰⁷Pb/²⁰⁴Pb−²⁰⁶Pb/²⁰⁴Pb and²⁰⁸Pb/²⁰⁴Pb−²⁰⁶Pb/²⁰⁴Pb plots indicate that Pb may probably be derived from the lower crust or upper mantle. It is believed that the deposits in this region are related to submarine volcanic exhalation superimposed by later regional metamorphism and magmatic intrusion.     

辽宁五龙金矿地质特征及矿床成因

五龙金矿是产在辽河群地层中的含金石英脉型金矿床.通过矿床产出地质特征、矿物组合、微量元素地球化学、稳定同位素及矿物包体学研究,探讨了金矿与燕山期岩浆活动的成因联系.     

Effect of Free Ferric Oxide on Engineering Properties of Laterite

In southern China, there are a great amount of red clay(laterite) which contains some free ferric oxide. Owing to its composition and microstructure developed under hot, wet soil-forming conditions, the clay has several special characteristics. Although the water content and void ratio of laterite are greater than similar clay soils, its strength is still higher than the others. There seems to be a contradiction between its physical parameters and mechanical properties. In this paper, the effect of free ferric oxide in laterite on its engineering properties, such as strength, swelling properties and others is discussed. The research result shows that special properties of laterite are the result of various conditions of formation, loss and crystallization degree of free ferric oxide, and its physical and mechanical properties will change with variation of physicochemical circumstance.     

The stability of Foundation Rock in Gezhouba Project

The results of the stability study of dam foundation , including the effects of ground stresses on the stability of base masses and long-term stability and strength of weak intercalations , especially of clayey ones, are presented. It is proved that the considerable tectonic stresses exist even in red rock layers with slight folds and a gentle terrain and that the stability of masses are directly affected by local stress relief. It is found that sedimentary rock behaves like rheology. A method of deter-mining long-term strength of rheological rock is suggested.     

江西修水二叠系-三叠系界线地层树枝状微生物岩状岩石成因初解

江西修水二叠系-三叠系界线地层有一段特殊构造的地层，下部为灰色部分和红色部分组成的斑状构造，上部为灰色部分和黄色部分组成的树枝状构造。这种树枝状构造的岩石与前人报道自重庆老龙洞剖面的微生物岩非常相似。岩石薄片观察表明，树枝状构造的暗色部分为残留的灰泥岩；浅色部分为灰岩经过重结晶、白云石化去白云石化作用改造而成。在暗色的残留灰岩里有保存很好的丰富的球状微生物化石。研究认为，岩石中暗色部分和浅色部分的原始组分是同时沉积的；是成岩作用控制了浅色部分的形成。这一成果应当对认识老龙洞剖面树枝状微生物岩的成因有借鉴作用。