Tufa and travertines of southern Italy: deep‐seated,fault‐related CO2 as the key control in precipitation

Continental carbonates of Quaternary age in southern Italy commonly exhibit the facies of calcareous tufa, often reported as related to shallow aquifers fed by meteoric waters and to organic processes. A close spatial relationship exists between the mappable tufa deposits and major Quaternary extensional faults. With respect to the Ca‐Mg‐HCO₃ composition of limestone aquifers’ springs, tufa‐depositing springs exhibit higher salinity and alkalinity, are slightly warmer, have lower pH and are enriched in SO₄ and CO₂. Their δ¹³C values are systematically positive and compatible with a deep‐seated carbon source. A clear input of soil‐derived organic carbon is indicated only for small, non‐mappable tufas deposited by perched springs. The dataset indicates that the large tufa deposits owe their origin to a supplementary source of CO₂ advected by degassing through active faults, as a necessary prerequisite for inducing a rise of total dissolved salts and alkalinity. Meteoric waters that have come from a shallow aquifer are able to precipitate only limited amount of carbonates.     

Biological Assessment of Eastern Oysters (Crassostrea virginica) Inhabiting Reef,Mangrove, Seawall,and Restoration Substrates

The eastern oyster, Crassostrea virginica, plays an essential functional role in many estuarine ecosystems on the east and Gulf coasts of the USA. Oysters form biogenic reefs but also live on alternative intertidal substrates such as artificial surfaces and mangrove prop roots. The hypothesis tested in this study was that non-reef-dwelling oysters (i.e., those inhabiting mangrove, seawall, or restoration substrates) were similar to their reef-dwelling counterparts based upon a suite of biological parameters. The study was carried out at six sites in three zones in Tampa Bay on the west coast of Florida using monthly samples collected from October 2008–September 2009. The timing of gametogenesis and spawning, fecundity, and juvenile recruitment were the same for oysters in all four habitats. Oyster size (measured as shell height), density, and Perkinsus marinus infection intensity and prevalence varied among habitats. This study indicates that oysters on mangroves, seawalls, and oyster restoration substrates contribute larvae, habitats for other species, and likely other ecosystem benefits similar to those of intertidal oyster reefs in Tampa Bay. Oysters from alternative intertidal substrates should be included in any system wide studies of oyster abundance, clearance rates, and the provision of alternate habitats, especially in highly developed estuaries.     

The future that may (or may not) come: How framing changes responses to uncertainty in climate change communications

Communicating possible effects of climate change inevitably involves uncertainty. Because people are generally averse to uncertainty, this activity has the potential to undermine effective action more than stimulate it. The present research considered how framing climate change predictions differently might moderate the tendency for uncertainty to undermine individual action. Two studies (Ns = 88 and 120) show that higher uncertainty combined with a negative frame (highlighting possible losses) decreased individual intentions to behave environmentally. However when higher uncertainty was combined with a positive frame (highlighting the possibility of losses not materializing) this produced stronger intentions to act. Study 2 revealed that these effects of uncertainty were mediated through feelings of efficacy. These results suggest that uncertainty is not an inevitable barrier to action, provided communicators frame climate change messages in ways that trigger caution in the face of uncertainty.     

Flow modelling in gravel‐bed rivers: rethinking the bottom boundary condition

A key problem in computational fluid dynamics (CFD) modelling of gravel‐bed rivers is the representation of multi‐scale roughness, which spans the range from grain size, through bedforms, to channel topography. These different elements of roughness do not clearly map onto a model mesh and use of simple grain‐scale roughness parameters may create numerical problems. This paper presents CFD simulations for three cases: a plane bed of fine gravel, a plane bed of fine gravel including large, widely‐spaced pebble clusters, and a plane gravel bed with smaller, more frequent, protruding elements. The plane bed of fine gravel is modelled using the conventional wall function approach. The plane bed of fine gravel including large, widely‐spaced pebble clusters is modelled using the wall function coupled with an explicit high‐resolution topographic representation of the pebble clusters. In these cases, the three‐dimensional Reynolds‐averaged continuity and Navier–Stokes equations are solved using the standard k ? ε turbulence model, and model performance is assessed by comparing predicted results with experimental data. For gravel‐bed rivers in the field, it is generally impractical to map the bed topography in sufficient detail to enable the use of an explicit high‐resolution topography. Accordingly, an alternative model based on double‐averaging is developed. Here, the flow calculations are performed by solving the three‐dimensional double‐averaged continuity and Navier‐Stokes equations with the spatially‐averaged 〈k ? ε〉 turbulence model. For the plane bed of fine gravel including large, widely‐spaced pebble clusters, the model performance is assessed by comparing the spatially‐averaged velocity with the experimental data. The case of a plane gravel bed with smaller, more frequent, protruding elements is represented by a series of idealized hypothetical cases. Here, the spatially‐averaged velocity and eddy viscosity are used to investigate the applicability of the model, compared with using the explicit high‐resolution topography. The results show the ability of the model to capture the spatially‐averaged flow field and, thus, illustrate its potential for representing flow processes in natural gravel‐bed rivers. Finally, practical data requirements for implementing such a model for a field example are given. Copyright © 2011 John Wiley & Sons, Ltd.     

The impacts of fine sediment on riverine fish

Elevated fine sediment input from terrestrial and aquatic sources as a result of anthropogenic activity is widely recognized to impact negatively on aquatic ecosystems. In rivers, freshwater fish are exposed to a range of impacts resulting from fine sediment pressures. To date, research on the effects of fine sediments on fish has been concentrated within relatively few families, notably the salmonidae. This paper reviews the literature describing indirect and direct impacts of fine sediment on freshwater fish as a contribution towards enhancing the understanding of the impacts of anthropogenic activities on freshwater ecosystems. We identify the causal mechanisms that underpin the observed negative response exhibited by fish populations to enhanced fine sediment loads, and the variability across different fish species. Copyright © 2011 John Wiley & Sons, Ltd.     

Elevated stream trace and minor element concentrations in the foreland of receding tropical glaciers

Globally, the ongoing retreat of mountain glaciers will ultimately diminish fresh water supplies. This has already begun in watersheds with greatly reduced glacial coverage. Still unknown are the affects of glacial retreat on downstream water quality, including the threats to human and ecosystem health. In the Cordillera Blanca, retreating glaciers have exposed sulfide-rich rock outcrops, negatively affecting the quality of the glacial meltwater. This study has evaluated glacial melt stream hydrogeochemistry in the sulfide-bearing Rio Quilcay watershed (∼9°27′S, ∼77°22′W) during the 2008 dry season. Surface water samples were collected from the upper 12 km of the watershed during the 2008 dry season. Dissolved (0.4 μm) and unfiltered acidified (pH < 2) Al, Co, Cu, Fe, Ni, Mn, Pb, Zn and dissolved major ions and organic C (DOC) concentrations were quantified and pH and temperature were measured in the field. Twenty of 22 stream samples had pH values below 4, generating significantly (p < 0.01, α = 0.05) greater cation denudation normalized to discharge than other worldwide glacier-fed streams. Additionally, dissolved trace and minor element concentrations were comparable to acid mine drainage. Non-conservative dissolved element behaviors resulted from adsorption/desorption reactions in tributary mixing zones. At low pH values, hydrous Fe oxides acted as the dominant sorption surfaces. The poor water quality observed in Cordillera Blanca headwaters coupled with the likely exposure of additional sulfide-rich outcrops from ongoing glacial retreat may pose water quality challenges.     

Vegetation Index Methods for Estimating Evapotranspiration by Remote Sensing

Evapotranspiration (ET) is the largest term after precipitation in terrestrial water budgets. Accurate estimates of ET are needed for numerous agricultural and natural resource management tasks and to project changes in hydrological cycles due to potential climate change. We explore recent methods that combine vegetation indices (VI) from satellites with ground measurements of actual ET (ET_a) and meteorological data to project ET_a over a wide range of biome types and scales of measurement, from local to global estimates. The majority of these use time-series imagery from the Moderate Resolution Imaging Spectrometer on the Terra satellite to project ET over seasons and years. The review explores the theoretical basis for the methods, the types of ancillary data needed, and their accuracy and limitations. Coefficients of determination between modeled ET_a and measured ET_a are in the range of 0.45–0.95, and root mean square errors are in the range of 10–30% of mean ET_a values across biomes, similar to methods that use thermal infrared bands to estimate ET_a and within the range of accuracy of the ground measurements by which they are calibrated or validated. The advent of frequent-return satellites such as Terra and planed replacement platforms, and the increasing number of moisture and carbon flux tower sites over the globe, have made these methods feasible. Examples of operational algorithms for ET in agricultural and natural ecosystems are presented. The goal of the review is to enable potential end-users from different disciplines to adapt these methods to new applications that require spatially-distributed ET estimates.     

An inventory of trees in Dublin city centre

While urban areas are often considered to be comprised chiefly of artificial surfaces, they can contain a substantial portion of green space and a great diversity of natural habitats. These spaces include public parks, private gardens and street trees, all of which can provide valuable environmental services, such as improved air quality. Trees play a particular role in cities as they are often placed along roadsides and in the median strip of busy streets. As such they regulate access to sunshine, restrict airflow, provide shelter, scavenge air pollutants and manage noise at the street level. A tree planting policy can be an important part of a broader environmental strategy aimed at improving the quality of life in urban areas but this requires up-to-date knowledge of the current tree stock, which does not exist for Dublin. This article presents an inventory of trees in Dublin's city centre, defined as the area between the Grand and Royal canals. The results show that there are over 10,000 trees in the study area representing a density of 684 trees km-2 or one tree to approximately every 50 residents of the city centre. The tree canopy extent when in full foliage was nearly 1 km2 in extent or 6% of the study area. A more detailed analysis of those trees planted along streets shows little species variation but clear distinction in the sizes of trees, which is indicative of the age of planting. These data are used to estimate the carbon stored in Dublin's trees.     

Processes of carbonate precipitation in modern microbial mats

Microbial mats are ecosystems that arguably greatly affected the conditions of the biosphere on Earth through geological time. These laminated organosedimentary systems, which date back to > 3.4 Ga bp, are characterized by high metabolic rates, and coupled to this, rapid cycling of major elements on very small (mm-µm) scales. The activity of the mat communities has changed Earth's redox conditions (i.e. oxidation state) through oxygen and hydrogen production. Interpretation of fossil microbial mats and their potential role in alteration of the Earth's geochemical environment is challenging because these mats are generally not well preserved.Preservation of microbial mats in the fossil record can be enhanced through carbonate precipitation, resulting in the formation of lithified mats, or microbialites. Several types of microbially-mediated mineralization can be distinguished, including biologically-induced and biologically influenced mineralization. Biologically-induced mineralization results from the interaction between biological activity and the environment. Biologically-influenced mineralization is defined as passive mineralization of organic matter (biogenic or abiogenic in origin), whose properties influence crystal morphology and composition. We propose to use the term organomineralization sensu lato as an umbrella term encompassing biologically influenced and biologically induced mineralization. Key components of organomineralization sensu lato are the “alkalinity” engine (microbial metabolism and environmental conditions impacting the calcium carbonate saturation index) and an organic matrix comprised of extracellular polymeric substances (EPS), which may provide a template for carbonate nucleation. Here we review the specific role of microbes and the EPS matrix in various mineralization processes and discuss examples of modern aquatic (freshwater, marine and hypersaline) and terrestrial microbialites.