Revised runoff curve number for runoff prediction in the Loess Plateau of China

The soil conservation service (now Natural Resources Conservation Service) Curve Number (SCS-CN), one of the most commonly used methods for surface runoff prediction. The runoff calculated by this method was very sensitive to CN values. In this study, CN values were calculated by both arithmetic mean (CN_C) and least square fit method (CN_F) using observed rainfall-runoff data from 43 sites in the Loess Plateau region, which are considerably different from the CN₂ values obtained from the USDA-SCS handbook table (CN_T). The results showed that using CN_C instead of CN_T for each watershed produce little improvement, while replacing CN_T with CN_F improves the performance of the original SCS-CN method, but still performs poorly in most study sites. This is mainly due to the SCS-CN method using a constant CN value and discounting of the temporal variation in rainfall-runoff process. Therefore, three factors—soil moisture, rainfall depth and intensity—affecting the surface runoff variability are considered to reflect the variation of CN in each watershed, and a new CN value was developed. The reliability of the proposed method was tested with data from 38 watersheds, and then applied to the remaining five typical watersheds using the optimized parameters. The results indicated that the proposed method, which boosted the model efficiencies to 81.83% and 74.23% during calibration and validation cases, respectively, performed better than the original SCS-CN and the Shi and Wang (2020b) method, a modified SCS-CN method based on tabulated CN value. Thus, the proposed method incorporating the influence of the temporal variability of soil moisture, rainfall depth, and intensity factors suggests an accurate runoff prediction for general applications under different hydrological and climatic conditions on the Loess Plateau region.     

X射线衍射技术应用于宝石鉴定-合成及晶体结构研究进展

因宝石检测常附带无损要求、宝石评价具科学性和不确定性等特点,X射线衍射(XRD)在宝石学这门矿物学的分支学科中的应用具有特殊性,其应用领域主要集中在三个方面。①宝石鉴定领域:对单晶宝石和多晶宝石进行物相鉴定、宝石产地特征研究以及宝石矿物多型的种类划分等。例如根据XRD图谱,可将品种繁多的微晶石英隐晶质变种玉髓中不同的SiO₂质矿物相精确区分;通过黏土矿物成分及其含量可将鸡血石中"地"的种类进行划分。②宝石矿物的晶体结构研究:对成分复杂的单晶宝石进行晶体化学分析、获取矿物类质同象替代情况、利用结晶度划分宝石品质。例如晶格参数中的c/a比值可将绿柱石的Al八面体类质同象替代和Be四面体类质同象替代进行区分;软玉中通过XRD数据计算出的结晶度与软玉的品质关系密切。③宝石学研究技术的开发:对宝石的优化处理过程进行监测,在宝石合成过程中检验矿物晶形大小、结晶质量及内应力等,以有机宝石的晶体结构为基础的人工养殖技术研究。例如尖晶石在热处理过程中,Mg离子由四面体中的T位迁移至八面体中的M位,导致M-O和T-O键长随温度变化,并反映在尖晶石的色调中;在托帕石合成过程中,XRD数据显示770~800℃时形成含氟托帕石(与天然托帕石结构相同),而在950℃和1000℃出现含氟托帕石离解成刚玉和莫来石。目前,我国在宝石学的XRD应用方面起步较晚,国外在宝石鉴定、优化与合成方面的应用相对成熟。本文认为,该技术与扫描电镜、质子探针等分析技术的联用仍有很大发展空间。     

准噶尔盆地油气源、油气分布与油气系统

准噶尔盆地是中国西部典型的多旋回叠合盆地,发育有石炭系、二叠系、三叠系、侏罗系、白垩系和古近系6套烃源岩,同时存在6大类原油和3大类天然气,广泛分布于盆地不同地区。西北缘原油总体相似,碳同位素组成轻(δ~(13)C-29‰),胡萝卜烷、类异戊二烯烷烃、三环萜烷、伽马蜡烷丰富,甾烷以C_(28)、C_(29)为主,基本没有重排甾烷,为第二类原油,来源于二叠系湖相烃源岩。腹部绝大多数原油与西北缘原油相似,但胡萝卜烷、类异戊二烯烷烃、伽马蜡烷等有差异,来源于不同凹陷的二叠系湖相烃源岩;少量原油碳同位素组成重(δ~(13)C-28‰~-26‰),Pr/Ph大于2.5,三环萜烷以C_(19)、C_(20)为主,藿烷丰富而伽马蜡烷极低,以C_(29)规则甾烷及重排甾烷为主,为第四类原油,来源于侏罗系煤系烃源岩。东部存在5种类型原油,第一类原油碳同位素组成特别重(δ~(13)C-26‰),来源于石炭系烃源岩;第二类原油与腹部地区绝大多数原油十分相似,来源于二叠系湖相烃源岩;第三类原油碳同位索组成轻,重排甾烷、Ts、C_(29)Ts及C_(30)重排藿烷异常丰富,来源于中上三叠统湖相烃源岩;第四类原油源于侏罗系煤系烃源岩;混合类原油为二叠系、三叠系、侏罗系原油的混合,各自贡献平均分别为20%、15%和65%。南缘存在4类典型原油,为第二、第四、第五和第六类原油,其中第二、第四类分别源于二叠系和侏罗系;第五类原油碳同位素组成轻(δ~(13)C-29‰)、Pr/Ph1.0、伽马蜡烷丰富且有两个异构体、Ts、C_(29)Ts、C_(30)重排藿烷、C_(27)~C_(29)异胆甾烷及C_(30)甲基甾烷丰富,来源于白垩系湖相烃源岩;第六类原油主要为中低成熟原油,碳同位素组成δ~(13)C~28‰~-26‰,C_(27)、C_(28)、C_(29)甾烷呈"V"型分布,甲藻甾烷异常丰富,来源于古近系湖相烃源岩。准噶尔盆地天然气有油型气、混合气和煤型气,前两类主要来源于二叠系湖相烃源岩和石炭系海相烃源岩,煤型气主要来源于石炭系和侏罗系煤系烃源岩。不同类型油气分布与不同时代烃源灶具有良好对应关系:石炭系油气主要分布于陆东-五彩湾;二叠系油气主要分布于西北缘、腹部与东部;三叠系原油仅分布于东部;侏罗系原油主要分布于东部与南部;白垩系原油仅分布于南缘中部;古近系原油仅分布于南缘西部。按照盆地构造特征及不同时代烃源灶与油气关系,将准噶尔盆地划分为西部、中部、东部、南部及乌伦古5个油气系统及15个子油气系统。     

天津蓟县东水厂锰方硼石矿床成因新认识

天津蓟县东水厂锰方硼石矿床是世界上唯一一个具有经济开发价值的锰方硼石矿床,锰方硼石赋存与中元古代高于庄组二段泥晶白云岩中。本文通过微量元素分析探讨了锰方硼石的成矿环境,测定结果显示Sr/Ba=0.125~0.128;V/(Ni+V)=0.230~0.320;Th/U=4.356~4.898;V/Cr=0.018~0.026,各微量元素对比值范围变化不大;LREE总量为66.12×10~(-6)~67.90×10~(-6),HREE总量(包含Y)为18.88×10~(-6)~19.56×10~(-6),LREE/HREE值为3.38~3.60,Y/Ho值介于28.25~29.14之间,δCe介于0.829~0.854之间,显示为弱的负Ce异常,δEu值介于0.831~0.846之间,显示为弱的负Eu异常。地球化学数据指示其成矿环境属海相沉积环境,海水环境为相对氧化的状态,成矿过程中有陆源物质的加入。Sm/Nd-Eu/Sm图解表明研究区与柴达木盆地第三系蒸发岩较为相似,反应锰方硼石成矿时具有类似的蒸发成因。通过对硼同位素(δ~(11)B的数值范围为1.4‰~10.7‰)的解译进一步探讨了锰方硼石在原生成矿阶段的具体成因(海相蒸发沉积)。结合前人所做的锰方硼石地球化学数据,对东水厂锰方硼石矿床的成因做出了新的解释,即锰方硼石成矿时应属海相蒸发成因,而热液活动的过程则可能是发生于锰方硼石成矿之后,属后期热液改造作用,从而形成了锰方硼石复杂的地球化学特征。     

Curve matching approaches to waveform classification: a case study using ICESat data

Light Detection and Ranging (LiDAR) waveforms are being increasingly used in many forest and urban applications, especially for ground feature classification. However, most studies relied on either discretizing waveforms to multiple returns or extracting shape metrics from waveforms. The direct use of the full waveform, which contains the most comprehensive and accurate information has been scarcely explored. We proposed to utilize the complete waveform to test its ability to differentiate between objects having distinct vertical structures using curve matching approaches. Two groups of curve matching approaches were developed by extending methods originally designed for pixel-based hyperspectral image classification and object-based high spatial image classification. The first group is based on measuring the curve similarity between an unknown waveform and a reference waveform, including curve root sum squared differential area (CRSSDA), curve angle mapper (CAM), and Kullback–Leibler (KL) divergence. The second group assesses the curve similarity between an unknown and reference cumulative distribution functions (CDFs) of their waveforms, including cumulative curve root sum squared differential area (CCRSSDA), cumulative curve angle mapper (CCAM), and Kolmogorov–Smirnov (KS) distance. When employed to classify open space, trees, and buildings using ICESat waveform data, KL provided the highest average classification accuracy (87%), closely followed by CCRSSDA and CCAM, and they all significantly outperformed KS, CRSSDA, and CAM based on 15 randomized sample sets.     

Fluid Inclusion and Stable Isotope Geochemistry of the Shangxu Gold Deposit, Northern Tibet

正Objective The Shangxu gold deposit is located in the south of the middle Bangong-Nujiang suture zone in northern Tibet.The origin of this deposit as an orogenic gold deposit is debatable.The study of the Shangxu deposit has a profound implication on gold exploration in the BangongNujiang metallogenic belt and can also improve our understanding of gold mineralization in northern Tibet.     

矿床成矿系列——五论矿床的成矿系列问题

矿床的成矿系列(简称成矿系列)是矿床学领域的一个理论性概念,由五级序次组成。矿床成矿系列是成矿系列的第二序次,是成矿系列的核心部分。矿床成矿系列的划分,以岩浆、沉积、变质、表生和流体(非岩浆-非变质成因流体)5种成矿作用为基本原则,以成矿地质环境为基础,结合成矿的时段与形成的矿床组合进行划分。本文对矿床成矿系列时空范围、时空组成结构、矿化强度与演化、成矿区带内不同矿床成矿系列之间的演化、叠加和复合作用及对指导找矿的意义进行了论述。     

橄榄石微量元素原位分析的现状及其应用

随着高精度EMPA和LA-ICP-MS分析技术的发展和矿物微量元素测试精度的提高,利用橄榄石中的微量元素示踪地幔部分熔融、地幔交代作用、岩浆早期结晶过程等地质问题成为近年来一个新兴的研究方向。一系列开拓性的研究发现也被陆续的发表,主要涉及橄榄石中Ni、Co、Al、Cr、Zn、Ti、Li、V、Sc、Mn、Ca和P等元素的示踪使用。一些卓有成效的示踪方法为:Ca、Al、Ti、Ni及Mn能够很好的用于区分橄榄石捕掳晶和斑晶;橄榄石-尖晶石地幔演化趋势线(OSMA:olivine-spinel mantle array)图解可以用于表征岩浆源区的亏损程度;玄武岩中橄榄石斑晶的Li同位素及Li含量可以很有效地指示岩浆源区是否存在地壳物质再循环及地幔交代作用;橄榄石斑晶中Ni、Ca、Mn、Cr和Al协变关系图解可以识别岩浆的辉石岩源区;利用橄榄石捕掳晶中Zr和Sc的含量差异特征可将橄榄岩中三种最主要的类型(尖晶石橄榄岩、石榴石橄榄岩以及尖晶石-石榴石橄榄岩)区分开来;一些元素的比值或组合(例如Ni/Co、Fe/Mn、V/Sc、Zr和Sc、Ca和Ti)可以指示源区交代作用、岩浆作用过程及氧化状态;基于橄榄石中Al、Cr及Ca的地质温度计可以为推算地幔热状态提供新方法;基于橄榄石分离结晶Fo-NiO演化线的原始岩浆计算模型可以较好的推算原始岩浆成分;利用橄榄石的环带及微量元素的扩散机制可以判别更多岩石成因信息,如识别交代介质、熔体类型以及地质构造背景等。基于上述最新研究的相关资料和已有成果,本文对橄榄石微量元素的地球化学示踪方法做系统性的归纳整理,并对橄榄石微量元素赋存状况、橄榄石微量元素测试方法、橄榄石微量元素的使用条件及需注意的问题等进行讨论,为读者在做相关研究时提供参考。     

汶川地震断裂带多次地震活动新证据

虹口乡八角庙出露完整的映秀—北川断裂带剖面断层岩,高分辨率磁化率测试揭示出多个具有高磁化率特征的断层岩带。系统的岩石磁学分析证明一层褐色断层岩相对围岩具有最大的磁化率值,存在新生成的磁铁矿和拥有相似的天然剩磁(NRM)和非磁滞剩磁(ARM)强度衰减过程。高磁化率特征是含铁顺磁性矿物受到断层滑移过程产生摩擦生热作用生成磁铁矿所致。同时断层岩还获得了热剩磁,记录了地震活动磁学信息。结合汶川地震科学钻探项目1号孔(WFSD-1)磁化率和岩石磁学研究结果,说明映秀—北川断裂带包含多层具有高磁化率特征的断层岩,暗示了多次强震的发生。具有高磁化率特征的断层岩可以作为判定地震活动的标志之一。