Spatio-temporal dynamics of suspended matter properties and bacterial communities in the back-barrier tidal flat system of Spiekeroog Island

Back-barrier tidal flat systems are characterized by basins and inlets through which water is exchanged with the coastal sea by tidal water movements. The hydrographic and morphometric properties at the inlets and in the basins vary considerably, but there is little information available how biogeochemical properties in the water column at these different sites respond to these differences. Therefore, we investigated tidal dynamics of suspended particulate matter (SPM), particulate and dissolved organic carbon (DOC), chlorophyll a, phaeopigments, numbers of particle-associated (PA) and free-living bacteria (FL), bacterial biomass production, and concentrations of dissolved manganese (Mn). Samples were taken at the surface, a mid-depth and 1 m above the bottom at a fixed station at the inlet and in the basin of the Spiekeroog back-barrier tidal flat system in the German Wadden Sea. Five tidal cycles representative for typical seasonal situations, January (winter), April and May (late spring bloom), July (summer), and November (late fall) were studied in 2005 and 2006. In July, processes related to phytoplankton dynamics and bacterial decomposition were much more enhanced in the basin, whereas in April, these processes were enhanced at the inlet but were particularly low within the basin itself. The low values within the basin were a result of the settled phytoplankton spring bloom and represent a rather short period at the decline of this bloom. In November and January, differences were much less pronounced than during the growing season and restricted mainly to SPM and PA bacteria, exhibiting higher values in the basin. FL bacteria, DOC, and dissolved Mn exhibited different patterns and much less differences between the two stations, indicating that biogeochemical processes in the dissolved phase were controlled by different factors than PA biogeochemical processes. These differences reflect the retentive properties of the basin for particles and PA biogeochemical processes, particularly during the growing season, and in general emphasize the high productivity of back-barrier tidal flat systems.     

Radiocarbon wiggle-match dating of proglacial lake sediments – Implications for the 8.2 ka event

The problem of insufficient age-control limits the utilisation of the 8.2 ka BP event for modelling freshwater forcing in climate change studies. High-resolution radiocarbon dates, magnetic susceptibility and lithostratigraphic evidence from a lake sediment core from Nedre Hervavatnet located at Sygnefjell in western Norway provide a record of the early Holocene. We use the method of radiocarbon wiggle-match dating of the lake sediments using the non-linear relationship between the ¹⁴C calibration curve and the consecutive accumulation order of the sample series in order to build a high-resolution age-model. The timing and duration of Holocene environmental changes is estimated using 38 AMS radiocarbon dates on terrestrial macrofossils, insects and chironomids covering the time period from 9750 to 1180 cal BP. Chironomids, Salix and Betula leaves produce the most consistent results. Sedimentological and physical properties of the core suggest that three meltwater events with high sedimentation rates are superimposed on a long-term trend with glacier retreat between 9750 and 8000 cal BP. The lake sediment sequence of Nedre Hervavatnet demonstrates the following: only a reliable high-resolution geochronology based on carefully selected terrestrial macrofossils allows the reconstruction of a more refined and complex environmental change history before and during the 8.2 ka event.     

Surface chlorophyll-a dynamics in the upper Gulf of Thailand revealed by a coupled hydrodynamic-ecosystem model

Although plankton bloom incidents in the upper Gulf of Thailand (UGoT) have been reported, no dynamic investigation of the phenomenon has been conducted. To address this need, a simple pelagic ecosystem model coupled with the Princeton Ocean Model (POM) was employed to investigate seasonal variations in surface chlorophyll-a (chl-a) distributions to clarify phytoplankton dynamics in this area. The results revealed patterns of seasonal chl-a distribution that correspond to local wind, water movement and river discharge. High chl-a patchiness was found to be concentrated near the western coast following westward circulation near the northern coast developed during the northeast monsoon. During the southwest monsoon high concentrations were observed around the northeastern coast due to eastward flow. The simulated results could explain the seasonal shifting of phytoplankton blooms, which typically arise along the western and eastern coasts during the northeast and the southwest monsoons, respectively. Sensitivity analyses of simulated chl-a distributions demonstrate that water stability, including wind-induced vertical currents and mixing, plays significant roles in controlling phytoplankton growth. Nutrients in the water column will not stimulate strong plankton blooms unless upwelling develops or vertical diffusivity is low. This finding suggests an alternative aspect of the mechanism of phytoplankton bloom in this region.     

Interpolation of Steady-State Concentration Data by Inverse Modeling

In most groundwater applications, measurements of concentration are limited in number and sparsely distributed within the domain of interest. Therefore, interpolation techniques are needed to obtain most likely values of concentration at locations where no measurements are available. For further processing, for example, in environmental risk analysis, interpolated values should be given with uncertainty bounds, so that a geostatistical framework is preferable. Linear interpolation of steady-state concentration measurements is problematic because the dependence of concentration on the primary uncertain material property, the hydraulic conductivity field, is highly nonlinear, suggesting that the statistical interrelationship between concentration values at different points is also nonlinear. We suggest interpolating steady-state concentration measurements by conditioning an ensemble of the underlying log-conductivity field on the available hydrological data in a conditional Monte Carlo approach. Flow and transport simulations for each conditional conductivity field must meet the measurements within their given uncertainty. The ensemble of transport simulations based on the conditional log-conductivity fields yields conditional statistical distributions of concentration at points between observation points. This method implicitly meets physical bounds of concentration values and non-Gaussianity of their statistical distributions and obeys the nonlinearity of the underlying processes. We validate our method by artificial test cases and compare the results to kriging estimates assuming different conditional statistical distributions of concentration. Assuming a beta distribution in kriging leads to estimates of concentration with zero probability of concentrations below zero or above the maximal possible value; however, the concentrations are not forced to meet the advection-dispersion equation.     

Spatial and seasonal variations of sulphate,dissolved organic carbon,and nutrients in deep pore waters of intertidal flat sediments

Spatial and seasonal variations of sulphate, dissolved organic carbon (DOC), nutrients and metabolic products were determined down to 5 m sediment depth in pore waters of intertidal flats located in NW Germany. The impact of sediment permeability, pore water flow, and organic matter supply on deep pore water biogeochemistry was evaluated. Low sediment permeability leads to an enrichment of remineralisation products in pore waters of clay-rich sediments. In permeable sandy sediments pore water biogeochemistry differs depending on whether tidal flat margins or central parts of the tidal flat are studied. Pore water flow in tidal flat margins increases organic matter input. Substrate availability and enhanced temperatures in summer stimulate sulphate reducers down to 3.5 m sediment depth. Sulphate, DOC, and nutrient concentrations exhibit seasonal variations in deep permeable sediments of the tidal flat margin. In contrast, seasonal variations are small in deep pore waters of central parts of the sand flat. This study shows for the first time that seasonal variations in pore water chemistry are not limited to surface sediments, but may be observed down to some metres depth in permeable tidal flat margin sediments. In such systems more organic matter seems to be remineralised than deduced from surface sediment studies.     

Varied pathways of river-borne clay minerals in a near-shore marine region: A case study of sediments from the Elbe- and Weser rivers,and the SE North Sea

The <2 μm fraction of 45 sediment samples from the Elbe and Weser rivers and from the southeastern North Sea (German Bight) was analyzed for its contents of clay minerals and selected chemical elements. This was done to provide new information to the controversial question about the origin and distribution of clays in this near-shore marine region. The proportions of smectite, chlorite, illite and kaolinite were determined from intensities of the (001) basal reflection of the XRD pattern using weighted integrated factors and IR-mineral spectra, which were fitted to the values of the chemical analyses. Illite – the major clay mineral – was characterized by its K/Rb ratios and K-Ar ages. Anthropogenic metal contamination was demonstrated by the Cu, Pb and Zn contents.     

Preserved landscapes underneath the Antarctic Ice Sheet reveal the geomorphological history of Jutulstraumen Basin

The landscape of Antarctica, hidden beneath kilometre-thick ice in most places, has been shaped by the interactions between tectonic and erosional processes. The flow dynamics of the thick ice cover deepened pre-formed topographic depressions by glacial erosion, but also preserved the subglacial landscapes in regions with moderate to slow ice flow. Mapping the spatial variability of these structures provides the basis for reconstruction of the evolution of subglacial morphology. This study focuses on the Jutulstraumen Glacier drainage system in Dronning Maud Land, East Antarctica. The Jutulstraumen Glacier reaches the ocean via the Jutulstraumen Graben, which is the only significant passage for draining the East Antarctic Ice Sheet through the western part of the Dronning Maud Land mountain chain. We acquired new bed topography data during an airborne radar campaign in the region upstream of the Jutulstraumen Graben to characterise the source area of the glacier. The new data show a deep relief to be generally under-represented in available bed topography compilations. Our analysis of the bed topography, valley characteristics and bed roughness leads to the conclusion that much more of the alpine landscape that would have formed prior to the Antarctic Ice Sheet is preserved than previously anticipated. We identify an active and deeply eroded U-shaped valley network next to largely preserved passive fluvial and glacial modified landscapes. Based on the landscape classification, we reconstruct the temporal sequence by which ice flow modified the topography since the beginning of the glaciation of Antarctica.     

Microfacies and depositional environment of Late Cretaceous to Early Paleocene oil shales from Jordan

The purpose of this study is to better understand the depositional setting of Late Cretaceous to Early Paleocene oil shales from southeast and central-east Jordan. One core from both the Jafr and the Azraq-Hamza Basins was logged, and their lithology, texture, and ichnofabrics were recorded. A total of 79 thin sections were analyzed petrographically, and eight microfacies types recognized. Both cores show lithologic and petrographic similarities. The oil shales are Maastrichtian to Danian in age and can be described as organic matter and calcite-rich mudrocks. The most abundant granular components are foraminifera and various types of phosphatic bio- and lithoclasts. Macrofossils (bivalves, ostracods, echinoderms) were recorded in some intervals. The current results were compared with data from a previous publication on Maastrichtian oil shales from the Jafr Basin. A new model explaining the deposition of the oil shales of the Jafr and Azraq-Hamza Basins is proposed. The onset of the Maastrichtian oil shale deposition in both basins coincides with the early Maastrichtian transgression in this region. The organic matter-rich sediments were deposited in a mid to outer ramp setting below the storm wave base. Younger oil shales of Late Maastrichtian to Danian age were deposited in a shallower environment, below the fair weather wave base. The Cretaceous/Paleogene boundary is marked by a hiatus in both cores. The Danian oil shales show relatively lower “total organic carbon” content than the Maastrichtian ones. The former are believed to have been deposited in more oxygenated bottom waters of a mid-ramp zone.     

Extreme events,trends, and variability in Northern Hemisphere lake-ice phenology (1855–2005)

Often extreme events, more than changes in mean conditions, have the greatest impact on the environment and human well-being. Here we examine changes in the occurrence of extremes in the timing of the annual formation and disappearance of lake ice in the Northern Hemisphere. Both changes in the mean condition and in variability around the mean condition can alter the probability of extreme events. Using long-term ice phenology data covering two periods 1855–6 to 2004–5 and 1905–6 to 2004–5 for a total of 75 lakes, we examined patterns in long-term trends and variability in the context of understanding the occurrence of extreme events. We also examined patterns in trends for a 30-year subset (1975–6 to 2004–5) of the 100-year data set. Trends for ice variables in the recent 30-year period were steeper than those in the 100- and 150-year periods, and trends in the 150-year period were steeper than in the 100-year period. Ranges of rates of change (days per decade) among time periods based on linear regression were 0.3−1.6 later for freeze, 0.5−1.9 earlier for breakup, and 0.7−4.3 shorter for duration. Mostly, standard deviation did not change, or it decreased in the 150-year and 100-year periods. During the recent 50-year period, standard deviation calculated in 10-year windows increased for all ice measures. For the 150-year and 100-year periods changes in the mean ice dates rather than changes in variability most strongly influenced the significant increases in the frequency of extreme lake ice events associated with warmer conditions and decreases in the frequency of extreme events associated with cooler conditions.     

Available energy and energy balance closure at four coniferous forest sites across Europe

The available energy (AE), driving the turbulent fluxes of sensible heat and latent heat at the earth surface, was estimated at four partly complex coniferous forest sites across Europe (Tharandt, Germany; Ritten/Renon, Italy; Wetzstein, Germany; Norunda, Sweden). Existing data of net radiation were used as well as storage change rates calculated from temperature and humidity measurements to finally calculate the AE of all forest sites with uncertainty bounds. Data of the advection experiments MORE II (Tharandt) and ADVEX (Renon, Wetzstein, Norunda) served as the main basis. On-site data for referencing and cross-checking of the available energy were limited. Applied cross checks for net radiation (modelling, referencing to nearby stations and ratio of net radiation to global radiation) did not reveal relevant uncertainties. Heat storage of sensible heat J _H, latent heat J _E, heat storage of biomass J _veg and heat storage due to photosynthesis J _C were of minor importance during day but of some importance during night, where J _veg turned out to be the most important one. Comparisons of calculated storage terms (J _E, J _H) at different towers of one site showed good agreement indicating that storage change calculated at a single point is representative for the whole canopy at sites with moderate heterogeneity. The uncertainty in AE was assessed on the basis of literature values and the results of the applied cross checks for net radiation. The absolute mean uncertainty of AE was estimated to be between 41 and 52 W m^?2 (10–11 W m^?2 for the sum of the storage terms J and soil heat flux G) during mid-day (approximately 12% of AE). At night, the absolute mean uncertainty of AE varied from 20 to about 30 W m^?2 (approximately 6 W m^?2 for J plus G) resulting in large relative uncertainties as AE itself is small. An inspection of the energy balance showed an improvement of closure when storage terms were included and that the imbalance cannot be attributed to the uncertainties in AE alone.