Description of an aerodynamic levitation apparatus with applications in Earth sciences

Background  

In aerodynamic levitation, solids and liquids are floated in a vertical gas stream. In combination with CO₂-laser heating, containerless melting at high temperature of oxides and silicates is possible. We apply aerodynamic levitation to bulk rocks in preparation for microchemical analyses, and for evaporation and reduction experiments.     

The improvement of greenhouse gas inventory as a tool for reduction emission uncertainties for operations with oil in the Russian Federation

The high quality inventory is an important step to greenhouse gas emission mitigation. The inventory quality is estimated by means of the uncertainty analysis. The level of uncertainty depends upon the reliability of activity data and the parameters used. An attempt has been made to improve the accuracy of the estimates through a shift from production-based method (IPCC Tier 1) (IPCC 2000) to enhanced combination of production-based and mass balance methods (IPCC Tier 2) (IPCC 2006) in the estimation of emissions from operations with oil that are key in the national greenhouse gas inventory of the Russian Federation. The IPCC Tier 2 (IPCC 2006) was adapted for the national conditions. The greenhouse gas emissions were calculated for 1990 to 2009 with the use of both methods. The quantitative uncertainty assessment of the calculations was performed, and the outcomes were compared. The comparison showed that the estimates made with the use of higher tier method resulted in higher accuracy and lower uncertainties (26 % respectively compared to previously derived 54 %).     

A six hundred-year annual minimum temperature history for the central Tibetan Plateau derived from tree-ring width series

The recent unprecedented warming found in different regions has aroused much attention in the past years. How temperature has really changed on the Tibetan Plateau (TP) remains unknown since very limited high-resolution temperature series can be found over this region, where large areas of snow and ice exist. Herein, we develop two Juniperus tibetica Kom. tree-ring width chronologies from different elevations. We found that the two tree-ring series only share high-frequency variability. Correlation, response function and partial correlation analysis indicate that prior year annual (January–December) minimum temperature is most responsible for the higher belt juniper radial growth, while more or less precipitation signal is contained by the tree-ring width chronology at the lower belt and is thus excluded from further analysis. The tree growth-climate model accounted for 40 % of the total variance in actual temperature during the common period 1957–2010. The detected temperature signal is further robustly verified by other results. Consequently, a six century long annual minimum temperature history was firstly recovered for the Yushu region, central TP. Interestingly, the rapid warming trend during the past five decades is identified as a significant cold phase in the context of the past 600 years. The recovered temperature series reflects low-frequency variability consistent with other temperature reconstructions over the whole TP region. Furthermore, the present recovered temperature series is associated with the Asian monsoon strength on decadal to multidecadal scales over the past 600 years.     

Enrichments of the mantle sources beneath the Southern Volcanic Zone (Andes) by fluids and melts derived from abraded upper continental crust

Mafic basaltic-andesitic volcanic rocks from the Andean Southern Volcanic Zone (SVZ) exhibit a northward increase in crustal components in primitive arc magmas from the Central through the Transitional and Northern SVZ segments. New elemental and Sr–Nd-high-precision Pb isotope data from the Quaternary arc volcanic centres of Maipo (NSVZ) and Infernillo and Laguna del Maule (TSVZ) are argued to reflect mainly their mantle source and its melting. For the C-T-NSVZ, we identify two types of source enrichment: one, represented by Antuco in CSVZ, but also present northward along the arc, was dominated by fluids which enriched a pre-metasomatic South Atlantic depleted MORB mantle type asthenosphere. The second enrichment was by melts having the characteristics of upper continental crust (UCC), distinctly different from Chile trench sediments. We suggest that granitic rocks entered the source mantle by means of subduction erosion in response to the northward increasingly strong coupling of the converging plates. Both types of enrichment had the same Pb isotope composition in the TSVZ with no significant component derived from the subducting oceanic crust. Pb–Sr–Nd isotopes indicate a major crustal compositional change at the southern end of the NSVZ. Modelling suggests addition of around 2 % UCC for Infernillo and 5 % for Maipo.     

Fe and O isotope composition of meteorite fusion crusts: Possible natural analogues to chondrule formation?

Meteorite fusion crust formation is a brief event in a high‐temperature (2000–12,000 K) and high‐pressure (2–5 MPa) regime. We studied fusion crusts and bulk samples of 10 ordinary chondrite falls and 10 ordinary chondrite finds. The fusion crusts show a typical layering and most contain vesicles. All fusion crusts are enriched in heavy Fe isotopes, with δ⁵⁶Fe values up to +0.35‰ relative to the solar system mean. On average, the δ⁵⁶Fe of fusion crusts from finds is +0.23‰, which is 0.08‰ higher than the average from falls (+0.15‰). Higher δ⁵⁶Fe in fusion crusts of finds correlate with bulk chondrite enrichments in mobile elements such as Ba and Sr. The δ⁵⁶Fe signature of meteorite fusion crusts was produced by two processes (1) evaporation during atmospheric entry and (2) terrestrial weathering. Fusion crusts have either the same or higher δ¹⁸O (0.9–1.5‰) than their host chondrites, and the same is true for Δ¹⁷O. The differences in bulk chondrite and fusion crust oxygen isotope composition are explained by exchange of oxygen between the molten surface of the meteorites with the atmosphere and weathering. Meteorite fusion crust formation is qualitatively similar to conditions of chondrule formation. Therefore, fusion crusts may, at least to some extent, serve as a natural analogue to chondrule formation processes. Meteorite fusion crust and chondrules exhibit a similar extent of Fe isotope fractionation, supporting the idea that the Fe isotope signature of chondrules was established in a high‐pressure environment that prevented large isotope fractionations. The exchange of O between a chondrule melt and an ¹⁶O‐poor nebula as the cause for the observed nonmass dependent O isotope compositions in chondrules is supported by the same process, although to a much lower extent, in meteorite fusion crusts.     

Experimental study of gold-hydrosulphide complexing in aqueous solutions at 350-500°C, 500 and 1000 bars using mineral buffers

The solubility of gold was measured in KCl solutions (0.001-0.1 m) at near-neutral to weakly acidic pH in the presence of the K-feldspar-muscovite-quartz, andalusite-muscovite-quartz, and pyrite-pyrrhotite-magnetite buffers at temperatures 350 to 500°C and pressures 0.5 and 1 kbar. These mineral buffers were used to simultaneously constrain pH, f(S₂), and f(H₂). The experiments were performed using a CORETEST flexible Ti-cell rocking hydrothermal reactor enabling solution sampling at experimental conditions. Measured log m(Au) (mol/kg H₂O) ranges from −7.5 at weakly acid pH to −5.9 in near-neutral solutions, and increases slightly with temperature. Gold solubility in weakly basic and near-neutral solutions decreases with decreasing pH at all temperatures, which implies that Au(HS)₂ is the dominant Au species in solution. In more acidic solutions, solubility is independent of pH. Comparison of the experimentally measured solubilities with literature values for Au hydrolysis constants demonstrates that at 350°C dominates Au aqueous speciation at the weakly acidic pH and f(S₂)/f(H₂) conditions imposed by the pyrite-pyrrhotite-magnetite buffer. In contrast, at temperatures >400°C becomes less important and predominates in weakly acid solutions. Solubility data collected in this study were used to calculate the following equilibrium reaction constants:

     

基于GWR模型的中国中东部降水与海拔高度关系特征分析

利用中国国家级地面气象站逐时降水资料,采用地理加权回归(Geographically Weighted Regression,GWR)模型系统分析了中国中东部暖季降水与海拔高度的关系,并将二者关系作为一种客观标准,评估了ECMWF-IFS模式对2017年暖季降水的预报能力。主要结论如下:(1)总体来看,中国中东部降水频率(强度)随海拔高度升高而增加(减小),二者在不同地区的贡献程度不同导致降水量与海拔高度关系的区域差异显著。(2)通过对比午后短时和夜间长时降水事件与海拔高度关系的差异,发现午后短时降水事件的降水量主要随海拔高度升高而增加,且以降水频率与海拔高度关系的贡献为主。而夜间长时降水事件的降水量与海拔高度关系的区域一致性较差。相较于午后短时降水事件,夜间长时降水事件中有更多站点表现出降水量随海拔高度升高而减小的特征,在大地形周边陡峭地形处的站点所表现出的此种差异较东部孤立地形处更加显著。(3)根据ECMWF-IFS模式的评估结果,模式能够较好地刻画出中国中东部2017年暖季降水气候态的空间分布特征,且与观测具有较大的空间相关系数。但从降水与海拔高度关系来看,观测与模式的空间相关性偏弱。此外,模式能够表现出降水强度(频率)主要随海拔高度升高而减小(增加)的特征,但绝大多数站点在模式中的降水强度(频率)与海拔高度的负(正)回归关系要弱(强)于观测结果。