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261.
Trace elements and cathodoluminescence of quartz in stockwork veins of Mongolian porphyry-style deposits 总被引:1,自引:0,他引:1
Axel Müller Richard Herrington Robin Armstrong Reimar Seltmann Douglas J. Kirwin Nina G. Stenina Andreas Kronz 《Mineralium Deposita》2010,45(7):707-727
The combination of scanning electron microscope–cathodoluminescence (CL), fluid inclusion analysis and high-resolution electron
probe microanalysis of Al, Ti, K and Fe in vein quartz has yielded results permitting a greater understanding of the complex
mineralisation of the Central Oyu Tolgoi and Zesen Uul porphyry-style deposits, southern Mongolia. These data demonstrate
the relationship between quartz precipitation, dissolution and ore deposition as the mineralising fluid chemistry changed
through time. Four major quartz generations are identified in the A-type veins from the stockworks of both the Central Oyu
Tolgoi (OTi to OTiv) and Zesen Uul deposits (ZUi to ZUiv). Despite differences in the associated alteration and mineralisation
style, the observed CL textures and trace element signatures of the quartz generations are comparable between deposits. The
OTi and ZUi stage formed both the primary network of A-type veins and pervasive silicification of the host rock. Using the
Ti-in-quartz geothermometer, crystallisation temperatures for OTi and ZUi of between 598°C and 880°C are indicated. The main
stage of sulphide mineralisation was accompanied by the dissolution of pre-existing quartz (OTi and ZUi) and precipitation
of a weakly luminescent generation of quartz (OTii and ZUii) with a low Ti content, reflected in a calculated temperature
drop from approximately 700°C to 340°C in Central Oyu Tolgoi and 445°C in Zesen Uul. OTii and ZUii stage quartzes show high
and variable Al concentrations. The next stage of quartz in both deposits (OTiii and ZUiii) forms a fine network of veins
in cracks formed in pre-existing quartz. OTiii and ZUiii quartz contain measurable fluid inclusions of moderate salinity (3–17.1 wt.%
NaCl eq.), entrapped in the temperature range 256°C to 385°C. OTiii and ZUiii are not related to any sulphide mineralisation.
The final OTiv and ZUiv stages are characterised by quartz–calcite micro-breccias that penetrate the A-type veins. Based on
the calculated entrapment temperatures, the OTiv/ZUiv stage crystallised between 212°C and 335°C, and the quartz is characterised
by elevated but variable Al and Fe contents. The CL and trace element signatures of the OTi to OTiii and ZUi to ZUiii stages
of the two Mongolian porphyries show similar features to those observed in porphyry-style deposits from other regions. This
suggests that a common sequence of quartz crystallisation occurs during the formation of early veins in many porphyry copper
systems. 相似文献
262.
Terrace pediments occupy approximately 30 per cent of the bottom of the Makhtesh Ramon erosional cirque in the central Negev Desert, Israel. River terraces and terrace pediments are genetically connected landforms, where each terrace pediment corresponds with a fluvial terrace of the same relative height. A pediment and river terrace constitute a geomorphic pair and should be regarded as chronometrically synchronous morphological elements. The formation of the terrace pediment staircases is controlled mainly by local base level changes. The present‐day configuration and overall morphology of Makhtesh Ramon formed in the early stages of its development by both stream erosion and subsequent pedimentation. Less significantly, modification by intermittent erosion alternating with periods of stability, resulted in deepening of the Makhtesh Ramon bottom. The present‐day stepped relief throughout the Makhtesh valley is, thus, a composite feature. The overall rate of terrace pediment formation in Makhtesh Ramon ranges from 0·05 to 0·10 mm a−1. Copyright © 2000 John Wiley & Sons, Ltd. 相似文献
263.
Forest canopies alter the amount and isotopic composition of precipitation reaching the forest floor. Thus retention, evaporation and transport processes in forest canopies, and their effects on water isotopes, are key to understanding forest water cycling. Using a two-year isotope dataset from a mixed beech/spruce forest in Zurich, Switzerland, we assessed the isotopic offsets between precipitation, throughfall and stemflow. We also analysed how these offsets affect estimates of the fraction of soil water that is derived from winter precipitation. Throughfall was typically enriched in heavy isotopes compared to precipitation, but isotopically lighter than stemflow, with average δ2H of −64.3 ‰, −59.9 ‰ and − 56.3 ‰ in precipitation, throughfall and stemflow, respectively. The differences between beech and spruce were rather small compared to the seasonal differences in precipitation isotopes. Isotopic offsets between precipitation and throughfall/stemflow were smaller during the spring and summer months (March through August) than during fall and winter (September through February). Bulk and mobile soil waters at 10 and 40 cm showed smaller seasonal variations than those in precipitation, throughfall and stemflow, and were isotopically lighter than recent precipitation, with the largest offsets occurring during the summer months (June through August) for bulk soil waters. Thus, bulk soil waters at both depths contain a mixture of precipitation from previous events and seasons, with over-representation of isotopically lighter winter precipitation. Mobile soil waters were more similar to recent precipitation than bulk soil waters were. Throughfall isotopes were slightly heavier than precipitation isotopes, resulting in different sinusoidal fits for seasonal isotopic cycles in precipitation and throughfall. These differences lead to small underestimates in the fraction of soil water originating from winter precipitation, when open-field precipitation rather than throughfall is used as the input data. Together our results highlight the importance of isotope measurements in throughfall and stemflow for the assessment of precipitation seasonality and water cycling across forested landscapes. 相似文献