Geological setting and SHRIMP U–Pb geochronological evidence for ca. 2680–2660 Ma lode-gold mineralization at Jundee–Nimary in the Yilgarn Craton, Western Australia

The 7 million oz. Jundee–Nimary lode-gold deposit occurs in the northern portion of the Yandal greenstone belt in the northeastern part of the Archean Yilgarn Craton of Western Australia. Gold mineralization at Jundee–Nimary is similar in structural style, mineralogy, geochemistry and relative timing with respect to deformation and metamorphism, to other Western Australian Archean greenstone-hosted gold deposits, but is unusual in the fact that mineralized structures are crosscut by structurally late intermediate to felsic dykes. Within the Deakin South open cut, gold mineralization is hosted in brittle–ductile shear zones primarily developed within the dacitic Mitchell Porphyry. The Moore Porphyry, a broad dyke of porphyritic granodiorite, intrudes the Mitchell Porphyry, crosscutting and post-dating gold mineralization. Analytically indistinguishable SHRIMP U–Pb zircon ages of 2678 ± 5 Ma for the Mitchell Porphyry and 2669 ± 7 Ma for the Moore Porphyry require that gold mineralization at Jundee–Nimary occurred at ca. 2680–2660 Ma, approximately 40 million years earlier than the majority of published robust ages for gold mineralization in the Yilgarn Craton, which mostly overlap at ca. 2640–2630 Ma. The close spatial and temporal relationship between gold mineralization and felsic to intermediate magmatism at Jundee–Nimary also raises the possibility of a genetic link between hydrothermal and igneous activity. However, additional work is required to establish a firm connection. Current research on lode-gold mineralization in Archean, Paleozoic and Phanerozoic terranes suggests a model which postulates that these deposits formed during transpressional to compressional deformation in accretionary and collisional orogens and that their formation is intimately related to orogenic processes. Consequently, mineralization and regional metamorphism are expected to be diachronous, as terranes are accreted and the front of orogenesis migrates. Consideration of the new data presented in this paper in conjunction with previously published dates supports the hypothesis that gold mineralization, along with regional metamorphism, was generally diachronous from northeast to southwest across the Yilgarn Craton, over a period of approximately 40 million years from ca. 2680–2660 Ma to ca. 2640–2630 Ma. This is directly analogous to the accepted model for the timing of orogenic lode-gold mineralization in other provinces and therefore provides further support for a unified model for this style of deposit through geological time. Received: 17 March 2000 / Accepted: 8 September 2000     

Internal structure of a trough blowout, determined from migrated ground-penetrating radar profiles

Ground‐penetrating radar (GPR) was used to investigate the relationship between the geomorphological development of a large aeolian trough blowout and the stratigraphy and internal sedimentary structure of its associated deposits. Although analogous, many of the data‐processing techniques routinely applied in seismic reflection are very rarely applied in GPR studies. In this study, a simple migration program was used that significantly enhanced the quality of GPR images from a large trough blowout at Raven Meols on the Sefton coast, northwest England. These improvements aided subsequent data interpretation, which was achieved through application of the principles of radar stratigraphy. GPR shows the pre‐blowout dunes to have a complex internal structure that suggests they were formed in the presence of at least a partial vegetation cover. Subsequent to stabilization of these dunes a thin soil developed. This dune soil forms an important radar sequence boundary and delineates a complex topography beneath the depositional lobe of the blowout. The internal structure of the depositional lobe of the blowout does not conform to a model of simple radial foreset deposition, as derived from contemporary process studies reported in the literature. Instead, the pattern of deposition has been extensively modified by the antecedent dune topography and by varying spatial and temporal exposure to important sand‐transporting winds that is partly controlled by interactions between the regional wind pattern and local dune morphology. Trough blowout deposits in coastal aeolian sedimentary sequences are likely to be recognized by the presence of laterally continuous packets of relatively high‐angle cross‐strata, which often display a spatially‐variable radial dip pattern that is only very poorly or partially developed. In addition, a soil, or other surface representing a significant hiatus in dune deposition, is likely to underlie the blowout deposits, the topography of which will show a clear relationship to the dip and orientation of the overlying cross‐strata.     

Chemical studies of L-chondrites—I. A study of possible chemical sub-groups

Radiochemical neutron activation analysis of Ag, As, Au, Bi, Co, Cs, Ga, In, Rb, Sb, Te, Tl and Zn and major element data in 14 L4-6 and 3 LL5 chondrites indicates that the L-group is unusually variable and may represent at least 2 sub-groups differing in formation history. Chemical trends in the S/Fe-rich sub-group support textural evidence indicating late loss of a shock-formed Fe-Ni-S melt; the S/Fe-poor sub-group seemingly reflects nebular fractionation only. Highly mobile In and Zn apparently reflect shock-induced loss from L-chondrites. Data for L5 chondrites suggest higher formation temperatures and/or degrees of shock than for LL5 chondrites.     

Microtextures, geochemistry and geochronology of authigenic xenotime: constraining the cementation history of a Palaeoproterozoic metasedimentary sequence

An ≈ 26 m thick unit of phosphatic sandstone and black shale (the Phosphatic Unit) in the Palaeoproterozoic Mount Barren Group of south-western Australia contains abundant authigenic xenotime crystals showing well-preserved diagenetic textures. Despite extensive regional deformation and thermal metamorphism, the peak of which occurred at ≈ 1205 Ma, the Phosphatic Unit was preserved as a low-strain envelope because of its pre-compaction carbonate and phosphate cementation. In situ U–Pb geochronology of xenotime reveals four discrete age populations at 1693 ± 4, 1645 ± 3, 1578 ± 10 and 1481 ± 21 Ma. When integrated with petrography, the age data place a timeframe on: (i) sediment deposition; (ii) phosphogenesis; (iii) diagenetic cement infilling; (iv) diagenetic pyrite formation; (v) secondary porosity generation; (vi) hydrocarbon migration; (vii) burial compaction; and (viii) hydrothermal alteration, up until peak thermal metamorphism. Xenotime growth at ≈ 1693 Ma occurred prior to compaction, whereas xenotime growth at ≈ 1645 Ma occurred during burial. Xenotime growth at ≈ 1580 Ma and at ≈ 1480 Ma appears to be the far-field record of thermotectonic events associated with intracontinental extension and magmatism recorded elsewhere in Australia. Geochemical analysis, integrated with geochronology, shows a systematic increase in MREE/HREE in xenotime crystals with decreasing age and with increasing stratigraphic depth. Coupled with a decrease in xenotime abundance and age with depth, it suggests that: (i) the main focus of porosity infilling was at the top of the Phosphatic Unit and progressed downwards over the > 200 Myr period of porosity infilling, and (ii) the changes in xenotime REE chemistry may be due to an influx of MREE from increasing amounts of dissolved apatite or changes, with respect to REE solubility, in the physiochemical nature of the fluids with burial depth.     

Experimental calibration of lake-sediment spectral reflectance to chlorophyll a concentrations: methodology and paleolimnological validation

Chlorophyll a preserved in lake sediments reflects, in part, past primary production. This study assesses the spectral properties of sedimentary chlorophyll a using visible-near infrared reflectance (VNIR) spectroscopy, with the objective of establishing a new, non-destructive paleolimnological proxy. Reflectance spectra were determined from a dilution series (n = 10) involving incremental additions of pulverized modern algae to a lake sediment matrix of low organic content. This enabled an assessment of the development of sediment reflectance spectra in relation to different sediment chlorophyll a concentrations, and subsequent regression of spectral features against measured concentrations of chlorophyll a and derivatives obtained by high performance liquid chromatography (HPLC). The experiment demonstrates that ubiquitous troughs in sediment reflectance near 675 nm are attributable to chlorophyll a and derivative compounds. A significant correlation (r ² = 0.98, P < 0.01) was obtained between the area of the reflectance trough in the 650–700 nm interval and summed concentrations of chlorophyll a, all derivative isomers, and degradational pheopigments. A simple linear inference model derived from this experiment was applied to a down-core sequence of VNIR spectra from a productive prairie lake (Alberta, Canada), where it produced inferred sediment chlorophyll a concentrations in concordance with HPLC measurements. Although a larger training set is desirable to further refine the inference model, the analyses reported here demonstrate that reflectance spectroscopy provides a rapid, semi-quantitative method for assessing the chlorophyll a content of lake sediments.     

Tsunami generation by pyroclastic flow during the 3500-year B.P. caldera-forming eruption of Aniakchak Volcano, Alaska

 A discontinuous pumiceous sand, a few centimeters to tens of centimeters thick, is located up to 15 m above mean high tide within Holocene peat along the northern Bristol Bay coastline of Alaska. The bed consists of fine-to-coarse, poorly to moderately well-sorted, pumice-bearing sand near the top of a 2-m-thick peat sequence. The sand bed contains rip-up clasts of peat and tephra and is unique in the peat sequence. Major element compositions of juvenile glass from the deposit and radiocarbon dating of enclosing peat support correlation of the pumiceous sand with the caldera-forming eruption of Aniakchak Volcano. The distribution of the sand and its sedimentary characteristics are consistent with emplacement by tsunami. The pumiceous sand most likely represents redeposition by tsunami of climactic fallout tephra and beach sand during the approximately 3.5 ka Aniakchak caldera-forming eruption on the Alaska Peninsula. We propose that a tsunami was generated by the sudden entrance of a rapidly moving, voluminous pyroclastic flow from Aniakchak into Bristol Bay. A seismic trigger for the tsunami is unlikely, because tectonic structures suitable for tsunami generation are present only south of the Alaska Peninsula. The pumiceous sand in coastal peat of northern Bristol Bay is the first documented geologic evidence of a tsunami initiated by a volcanic eruption in Alaska. Received: 3 December 1997 / Accepted: 11 April 1998     

Aluminium solubility controls in acid waters: the need for a reappraisal

Stability diagrams have been frequently used to demonstrate aluminium solubility controls in acidic stream and soil waters. This paper shows that it is possible by this method to generate apparent controls using random numbers in place of stream chemistry data. Thermodynamic arguments demonstrate that a wide variety of reactions can produce relationships similar to Al(OH)₃ solubility controls. It is proposed that stability diagrams alone should be used with great caution in identifying aluminium solubility controls, taking care that their axes are independent. Thermodynamic solubility calculations should be used with due scepticism. Supplementary investigations should be used where possible to identify phases precipitating or dissolving.     

Identification of a collapsing protostar

The globular molecular cloud B335 contains a single, deeply embedded, far-infrared source. Our recent observations of H₂CO and CS lines toward this source provide direct kinematic evidence for collapse. Both the intensity and detailed shape of the line profiles match those expected from inside-out collapse inside a radius of 0.036 pc. The collapse began about 1.5 × 10⁵ years ago, similar to the onset of the outflow. The mass accretion rate is about 10 times the outflow rate, and about 0.4M should have now accumulated in the star and disk. Because B335 rotates only very slowly, any disk would still be very small (about 3 AU). The accretion luminosity should be adequate to power the observed luminosity. Consequently, we believe that B335 is indeed a collapsing protostar.Paper presented at the Conference onPlanetary Systems: Formation, Evolution, and Detection held 7–10 December, 1992 at CalTech, Pasadena, California, U.S.A.