Anisotropic Closure in Squeezing Rocks: The Example of Saint-Martin-la-Porte Access Gallery

In this paper, we analyse the convergence measurements recorded in a gallery excavated in severely squeezing ground. The procedure consists in a preliminary geometrical treatment of the raw data to evaluate the principal axes of deformation by assuming an elliptic deformation of the walls of the gallery. Then the convergence law proposed by Sulem et al. (Int J Rock Mech Min Sci Geomech Abstr 24(3):145–154, 1987a), which is extended to account for anisotropic closure, is fitted on the displacements along the two axes of the obtained ellipse. This procedure is more robust and relevant than fitting the convergence recorded on the most deforming segment or fitting the average value of the convergence along the various segments. An attempt is made to correlate the amount and the direction of anisotropic deformation with the lithology and some geological features described by the dominant discontinuity families.     

Spatial and Temporal Variability of the CO2 Fluxes in a Tropical, Highly Urbanized Estuary

The spatial and temporal variations of the flux of CO₂ were determined during 2007 in the Recife estuarine system (RES), a tropical estuary that receives anthropogenic loads from one of the most populated and industrialized areas of the Brazilian coast. The RES acts as a source of nutrients (N and P) for coastal waters. The calculated CO₂ fluxes indicate that the upstream inputs of CO₂ from the rivers are largely responsible for the net annual CO₂ emission to the atmosphere of +30 to +48 mmol m^?2 day^?1, depending on the CO₂ exchange calculation used, which mainly occurs during the late austral winter and early summer. The observed inverse relationship between the CO₂ flux and the net ecosystem production (NEP) indicates the high heterotrophy of the system (except for the months of November and December). The NEP varies between ?33 mmol m^?2 day^?1 in summer and ?246 mmol m^?2 day^?1 in winter. The pCO₂ values were permanently high during the study period (average ~4,700 μatm) showing a gradient between the inner (12,900 μatm) and lower (389 μatm) sections on a path of approximately 30 km. This reflects a state of permanent pollution in the basin due to the upstream loading of untreated domestic effluents (N/P?=?1,367:6 μmol kg^?1 and pH?=?6.9 in the inner section), resulting in the continuous mineralization of organic material by heterotrophic organisms and thereby increasing the dissolved CO₂ in estuarine waters.     

The November 2002 eruption of Piton de la Fournaise,Réunion: tracking the pre-eruptive thermal evolution of magma using melt inclusions

The November 2002 eruption of Piton de la Fournaise in the Indian Ocean was typical of the activity of the volcano from 1999 to 2006 in terms of duration and volume of magma ejected. The first magma erupted was a basaltic liquid with a small proportion of olivine phenocrysts (Fo₈₁) that contain small numbers of melt inclusions. In subsequent flows, olivine crystals were more abundant and richer in Mg (Fo_83–84). These crystals contain numerous melt and fluid inclusions, healed fractures, and dislocation features such as kink bands. The major element composition of melt inclusions in this later olivine (Fo_83–84) is out of equilibrium with that of its host as a result of extensive post-entrapment crystallization and Fe²⁺ loss by diffusion during cooling. Melt inclusions in Fo₈₁ olivine are also chemically out of equilibrium with their hosts but to a lesser degree. Using olivine–melt geothermometry, we determined that melt inclusions in Fo₈₁ olivine were trapped at lower temperature (1,182 ± 1°C) than inclusions in Fo_83–84 olivine (1,199–1,227°C). This methodology was also used to estimate eruption temperatures. The November 2002 melt inclusion compositions suggest that they were at temperatures between 1,070°C and 1,133°C immediately before eruption and quenching. This relatively wide temperature range may reflect the fact that most of the melt inclusions were from olivine in lava samples and therefore likely underwent minor but variable amounts of post-eruptive crystallization and Fe²⁺ loss by diffusion due to their relatively slow cooling on the surface. In contrast, melt inclusions in tephra samples from past major eruptions yielded a narrower range of higher eruption temperatures (1,163–1,181°C). The melt inclusion data presented here and in earlier publications are consistent with a model of magma recharge from depth during major eruptions, followed by storage, cooling, and crystallization at shallow levels prior to expulsion during events similar in magnitude to the relatively small November 2002 eruption.     

Chlorine isotopic composition in seafloor serpentinites and high-pressure metaperidotites. Insights into oceanic serpentinization and subduction processes

Bulk-rock chlorine content and isotopic composition (δ³⁷Cl) were determined in oceanic serpentinites, high-pressure metaperidotites and metasediments in order to gain constraints on the global chlorine cycle associated with hydrothermal alteration and subduction of oceanic lithosphere. The distribution of insoluble chlorine in oceanic serpentinites was also investigated by electron microprobe. The hydrothermally-altered ultramafic samples were dredged along the South West Indian Ridge and the Mid-Atlantic Ridge. The high-pressure metamorphic samples were collected in the Western Alps: metaperidotites in the Erro-Tobbio unit and metasediments in the Schistes Lustrés nappe.Oceanic serpentinites show relatively large variations of bulk-rock Cl contents and δ³⁷Cl values with mean values of 1105 ± 596 ppm and −0.7 ± 0.4‰, respectively (n = 8; 1σ). Serpentines formed after olivine (meshes) show lower Cl content than those formed after orthopyroxene (bastites). In bastites of two different samples, Cl is positively correlated with Al₂O₃ and negatively correlated with SiO₂. These relationships are interpreted as reflecting preferential Cl-incorporation into the bastite structure distorted by Al (substituted for Si) rather than different alteration conditions between olivine and orthopyroxene minerals. High-pressure metaperidotites display relatively homogeneous Cl contents and δ³⁷Cl values with mean values of 467 ± 88 ppm and −1.4 ± 0.1‰, respectively (n = 7; 1σ). A macroscopic high-pressure olivine-bearing vein, formed from partial devolatilization of serpentinites at ∼2.5 GPa and 500-600 °C, shows a Cl content and a δ³⁷Cl value of 603 ppm and −1.6‰, respectively. Metasediments (n = 2) show low whole-rock Cl contents (<15 ppm Cl) that did not allow Cl isotope analyses to be obtained.The range of negative δ³⁷Cl values observed in oceanic serpentinites is likely to result from water-rock interaction with fluids that have negative δ³⁷Cl values. The homogeneity of δ³⁷Cl values from the high-pressure olivine-bearing vein and the metaperidotite samples implies that progressive loss of Cl inherited from oceanic alteration throughout subduction did not significantly fractionate Cl isotopes. Chlorine recycled in subduction zones via metaperidotites should thus show a range of δ³⁷Cl values similar to the range found in oceanic serpentinized peridotites.     

36.5万年以来西边界底流冰期-间冰期不稳定性与ODP 646站位(拉布拉多海)黏土级沉积碎屑Sm/Nd比率的关系

1区域概况随着气候—海洋系统模拟工作力度的加大,相关古气候改变北大西洋深层水(NADW)生产力速率的论著十分亟需。大多数作者认为整体的NADW生产力在冰期降低,他们的推断范围不完全一致。冰期更大量的南大洋水体涌入北大西洋,而且北大西洋深部对流现在已被更浅的和更南部的对流所取代。有关更新世末次冰期—间冰期旋回NADW演变,主要研究成果如下:(1)沿冰岛—苏格兰溢流水团路径从冰岛盆地采集柱状样,对其进行磁各向异性测试。变化结果同过去20万a水体可变强度相关联。冰期氧同位素2期、4期、6期较之间冰期1期、3期、5期有30%的强度衰…     

Seasonal and Interannual Variability in the Distribution of Surface Nutrients and Dissolved Inorganic Carbon in the Northern North Pacific: Influence of El Niño

The seasonal and interannual changes in surface nutrients, dissolved inorganic carbon (DIC) and total alkalinity (TA) were recorded in the North Pacific (30–54°N) from 1995 to 2001. This study focuses on the region north of the subarctic boundary (∼40°N) where there was extensive monthly coverage of surface properties. The nutrient cycles showed large interannual variations in the eastern and western subarctic gyres. In the Alaska Gyre the seasonal depletion of nitrate (ΔNO₃) increased from 8–14 μmol kg⁻¹ in 1995–1999 to 21.5 μmol kg⁻¹ in 2000. In the western subarctic the shifts were similar in amplitude but more frequent. The large ΔNO₃ levels were associated with high silicate depletions, indicating enhanced diatom production. The seasonal DIC:NO₃ drawdown ratios were elevated in the eastern and central subarctic due to calcification. In the western subarctic and the central Bering Sea calcification was significant only during 1997 and/or 1998, two El Ni?o years. Regional C/N stoichiometric molar ratios of 5.7 to 7.0 (>40°N) were determined based on the years with negligible or no calcification. The annual new production (NP_a) based on ΔNO₃ and these C/N ratios showed large interannual variations. NP_a was usually higher in the western than in the eastern subarctic. However, values of 84 gC m⁻²yr⁻¹ were found in the Alaska Gyre in 2000 which is similar to that in the most productive provinces of the northern North Pacific. There were also large increases in NP_a around the Alaska Peninsula in 1997 and 1998. Finally, the net removal of carbon by the biological pump was estimated as 0.72 Gt C yr⁻¹ in the North Pacific (>30°N). This revised version was published online in August 2006 with corrections to the Cover Date.     

Predicting river water temperatures using stochastic models: case study of the Moisie River (Québec,Canada)

Successful applications of stochastic models for simulating and predicting daily stream temperature have been reported in the literature. These stochastic models have been generally tested on small rivers and have used only air temperature as an exogenous variable. This study investigates the stochastic modelling of daily mean stream water temperatures on the Moisie River, a relatively large unregulated river located in Québec, Canada. The objective of the study is to compare different stochastic approaches previously used on small streams to relate mean daily water temperatures to air temperatures and streamflow indices. Various stochastic approaches are used to model the water temperature residuals, representing short‐term variations, which were obtained by subtracting the seasonal components from water temperature time‐series. The first three models, a multiple regression, a second‐order autoregressive model, and a Box and Jenkins model, used only lagged air temperature residuals as exogenous variables. The root‐mean‐square error (RMSE) for these models varied between 0·53 and 1·70 °C and the second‐order autoregressive model provided the best results. A statistical methodology using best subsets regression is proposed to model the combined effect of discharge and air temperature on stream temperatures. Various streamflow indices were considered as additional independent variables, and models with different number of variables were tested. The results indicated that the best model included relative change in flow as the most important streamflow index. The RMSE for this model was of the order of 0·51 °C, which shows a small improvement over the first three models that did not include streamflow indices. The ridge regression was applied to this model to alleviate the potential statistical inadequacies associated with multicollinearity. The amplitude and sign of the ridge regression coefficients seem to be more in agreement with prior expectations (e.g. positive correlation between water temperature residuals of different lags) and make more physical sense. Copyright © 2006 John Wiley & Sons, Ltd.     

The SARAL/AltiKa Altimetry Satellite Mission

The India-France SARAL/AltiKa mission is the first Ka-band altimetric mission dedi-cated to oceanography. The mission objectives are primarily the observation of the oceanic mesoscales but also include coastal oceanography, global and regional sea level monitoring, data assimilation, and operational oceanography. Secondary objectives include ice sheet and inland waters monitoring. One year after launch, the results widely confirm the nominal expectations in terms of accuracy, data quality and data availability in general.

Today's performances are compliant with specifications with an overall observed performance for the Sea Surface Height RMS of 3.4 cm to be compared to a 4 cm requirement. Some scientific examples are provided that illustrate some salient features of today's SARAL/AltiKa data with regard to standard altimetry: data availability, data accuracy at the mesoscales, data usefulness in costal area, over ice sheet, and for inland waters.     

Nutrient dynamics at the sediment-water interface in a Mediterranean lagoon (Thau, France): influence of biodeposition by shellfish farming activities

The Thau Lagoon, a French Mediterranean shallow lagoon, is a site where extensive shellfish farming occurs. The aim of the present work is to evaluate the role of this activity on nutrient exchange at the sediment-water interface in relation to organic matter (OM) sedimentation and degradation. Two stations inside (C5) and outside (C4) of the shellfish farming areas were sampled at three seasons. Porewater chemistry surveys and calculated diffusive fluxes were used to evaluate the trophic status of the Thau lagoon. Quantitative (Particulate Organic Carbon) as well as qualitative OM (Hydrogen Index, Carbohydrates) analyses were performed on sediments to assess OM characteristics. Results emphasized that surficial sediments at C5 are always more enriched in OM. Porewater nutrient concentrations are 10-20 times higher at C5 than at C4. In June 2003, the porewater profiles exhibit a sharp gradient at the bottom waters, indicating a hypereutrophic status, leading to an anoxic crisis.